IP Library › Granted Patent US 10,683,384
Granted Patent B2
US 10,683,384 · App. 15/759,882 · Granted Jun 16, 2020

Two-component composition

Inventors: Takuya Kunitomo (Chigasaki, JP); Shoko Sakata (Chigasaki, JP); Barbara Jucker (Hiratsuka, JP)
Assignee: SIKA TECHNOLOGY AG
C08G18/3893C08G18/10C08G18/227C08G18/341C08G18/4829C08G18/4866C08G18/6666C08G18/6692C08G18/718C08G18/724C08G18/755C08G18/7621C08K3/26C08K5/13C08K5/3475C08K5/57C08K7/16C08L71/02C09D175/04C09J175/04C08F230/08C08G65/336C08K2003/265
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Quick Facts
Patent No.
US 10,683,384
App. No.
15/759,882
Granted
Jun 16, 2020
Kind
B2
Abstract

A two-component composition is based on silane-functional polymers, especially silane-functional polymers with high reactivity. Such a composition shows long shelf life without the requirement of expensive stabilizers and is suitable to be used as a low E-modulus joint sealant offering excellent durability in high movement joints.

Claims (38)

1. Two-component composition comprising

a) a first component A, comprising

between 50% and 100% by weight of at least one silane-functional polymer P selected from formula (II), and/or (III)

wherein

radicals R 1 and R 2 independently represent a linear or branched monovalent hydrocarbon radical having 1 to 10 carbon atoms;

radical R 4 represents a linear or branched divalent hydrocarbon radical having 1 to 6 carbon atoms and optionally containing one or more heteroatoms;

radical R 5 represents a dialkyl succinate radical;

radical R 6 represents a divalent aliphatic hydrocarbon radical having 1 to 15 carbon atoms;

radical R 7 represents a hydroxyl-terminated polyether or polyurethane polymer after removal of p hydroxyl groups;

radical R 8 represents a divalent linear, branched, or cyclic hydrocarbon radical having 1 to 15 carbon atoms and optionally containing heteroatoms;

n represents an integer having a value of 2 or 3;

m represents an integer having a value of 3-n;

p represents an integer having a value of at least 2; and

between 0% and 50% by weight of at least one plasticizer; and between 0% and 10% by weight of at least one organosilane OS; and between 0% and 5% by weight of at least one drying agent;

wherein component A does not contain filler and component A is essentially free of catalyst for catalyzing hydrolysis and/or condensation of organosilanes and wherein the amounts of all individual components comprised in component A are adjusted such that their sum equals 100%;

and

b) a second component B, comprising

between 0.05% and 4% by weight of a catalyst for catalyzing hydrolysis and/or condensation of organosilanes; and

between 25% and 75% by weight of at least one filler; and

between 0% and 60% by weight of at least one plasticizer; and

between 0% and 0.5% of at least one stabilizer;

wherein the amounts of all individual components comprised in component B are adjusted such that their sum equals 100%;

wherein the mixing ratio by weight of component A to component B is between 1:2 and 1:4, and

wherein the two components A and B are produced separately, stored in separated packages, and combined only immediately before application.

2. The two-component composition according to claim 1 , wherein said radical R 6 represents an isophorone diisocyanate radical after removal of two isocyanate groups.

3. The two-component composition according to claim 1 , wherein said radical R 1 represents a methyl or ethyl radical.

4. The two-component composition according to claim 1 , wherein said radical R 5 represents a diethyl succinate radical.

5. The two-component composition according to claim 1 , wherein the cured composition of the two components A and B passes the durability test according to Japanese Industrial Standard JIS A 5758:2010 and reaches classification 9030.

6. The two-component composition according to claim 1 , wherein component A comprises between 50% and 100% by weight, based on the total weight of component A, of at least one polymer P, and between 0% and 50% by weight, based on the total weight of component A, of at least one plasticizer, and between 1% and 5% by weight, based on the total weight of component A, of at least one organosilane OS, wherein the amounts of all individual components comprised in component A are adjusted such that their sum equals 100%.

7. The two-component composition according to claim 1 , wherein component B comprises between 25% and 75% by weight, based on the total weight of component B, of at least one filler, and between 0.05% and 4% by weight, based on the total weight of component B, of at least one catalyst for catalyzing hydrolysis and/or condensation of organosilanes, and between 15% and 50% by weight, based on the total weight of component B, of at least one plasticizer, and between 0% and 0.4% by weight, based on the total weight of component B, of at least one stabilizer, wherein the amounts of all individual components comprised in component B are adjusted such that their sum equals 100%.

8. The two-component composition according to claim 1 , wherein said catalyst for catalyzing hydrolysis and/or condensation of organosilanes comprises a metal salt or complex, and an aliphatic, cycloaliphatic, or aromatic compound comprising at least one amine functional group.

9. The two-component composition according to claim 1 , wherein said organosilane OS comprises at least one vinylsilane and/or at least one aminosilane and/or at least one mercaptosilane and/or at least one glycidoxysilane and/or mixtures thereof and/or oligomeric products thereof.

10. The two-component composition according to claim 1 , wherein component B additionally comprises water.

11. A method comprising sealing, adhering, or coating with a two-component composition according to claim 1 .

12. The method according to claim 11 , wherein a substrate to be sealed, adhesively attached to another substrate, or coated was not pretreated with a primer or adhesion promoter.

13. A cured or curing composition obtained by combining component A and component B of the two-component composition according to claim 1 and mixing them by using a static or dynamic mixing system and applying the mixture to a substrate.

14. The two-component composition according to claim 1 , wherein at least one silane-functional polymer P of formula (II) is present.

15. The two-component composition according to claim 1 , wherein at least one silane-functional polymer P of formula (III) is present.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 14, 2018
From: KUNITOMO, TAKUYA; SAKATA, SHOKO; JUCKER, BARBARA
To: SIKA TECHNOLOGY AG
Reel/Frame 045586/0354 →
Priority Claims (1)
EP 15186453 · Sep 23, 2015 · regional
Continuity (1)
Related Publication 20180251590A1 · Sep 6, 2018