IP Library Granted Patent US 10,686,040
Granted Patent B2
US 10,686,040 · App. 16/395,084 · Granted Jun 16, 2020

Artificial synapse with hafnium oxide-based ferroelectric layer in CMOS front-end

Inventors: Martin M. Frank (Dobbs Ferry, NY); Takashi Ando (Tuckahoe, NY); Xiao Sun (Pleasantville, NY); Jin Ping Han (Yorktown Heights, NY); Vijay Narayanan (New York, NY)
Assignee: International Business Machines Corporation
H01L29/12H01L21/82345H01L23/52H01L27/085H01L27/088H01L29/0649
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Quick Facts
Patent No.
US 10,686,040
App. No.
16/395,084
Granted
Jun 16, 2020
Kind
B2
Abstract

Artificial synaptic devices with a HfO 2 -based ferroelectric layer that can be implemented in the CMOS front-end are provided. In one aspect, a method of forming a FET device is provided. The method includes: forming a shallow STI region in a substrate separating a first active area of the substrate from a second active area of the substrate; forming at least one FeFET on the substrate in the first active area having a ferroelectric material including a HfO 2 -based material; and forming at least one logic FET alongside the at least one FeFET on the substrate in the second active area, wherein the at least one logic FET has a gate dielectric including the HfO 2 -based material. A FET device formed by the present techniques is also provided.

Claims (40)

1. A field-effect transistor (FET) device, comprising:

a substrate comprising a first active area separated from a second active area by a shallow trench isolation (STI) region;

at least one ferroelectric FET (FeFET) on the substrate in the first active area having a ferroelectric material comprising a hafnium oxide (HfO 2 )-based material; and

at least one logic FET alongside the at least one FeFET on the substrate in the second active area, wherein the at least one logic FET has a gate dielectric comprising the HfO 2 -based material, and wherein the at least one logic FET further comprises:

the gate dielectric disposed on the substrate;

a dielectric capping layer disposed on the gate dielectric;

a gate metal layer disposed on the dielectric capping layer;

a gate capping layer disposed on the gate metal layer; and

an additional gate metal layer disposed on the gate capping layer.

2. The FET device of claim 1 , wherein the HfO 2 -based material is selected from the group consisting of: pure HfO 2 , Hf ˜0.5 Zr ˜0.5 O 2 , doped HfO 2 , and combinations thereof.

3. The FET device of claim 2 , wherein the doped HfO 2 comprises a dopant selected from the group consisting of: nitrogen (N), carbon (C), silicon (Si), aluminum (Al), lanthanum (La), gadolinium (Gd), yttrium (Y), scandium (Sc), strontium (Sr), and combinations thereof.

4. The FET device of claim 1 , wherein the at least one FeFET further comprises:

the ferroelectric material disposed on the substrate;

a dielectric capping layer disposed on the ferroelectric material; and

an electrode disposed on the dielectric capping layer.

5. The FET device of claim 4 , wherein the dielectric capping layer comprises a material selected from the group consisting of: lanthanum oxide (La 2 O 3 ), aluminum oxide (Al 2 O 3 ), and combinations thereof.

6. The FET device of claim 4 , wherein the electrode comprises a metal selected from the group consisting of: titanium nitride (TiN), tantalum nitride (TaN), and combinations thereof.

7. The FET device of claim 1 , wherein the dielectric capping layer comprises a material selected from the group consisting of: La 2 O 3 , Al 2 O 3 and combinations thereof.

8. The FET device of claim 1 , wherein the gate capping layer comprises a material selected from the group consisting of: La 2 O 3 , Al 2 O 3 and combinations thereof.

9. The FET device of claim 1 , wherein the gate metal layer and the additional gate metal each comprises a metal selected from the group consisting of: TiN, TaN, and combinations thereof.

10. The FET device of claim 1 , wherein the gate dielectric is selected from the group consisting of: pure HfO 2 , Hf ˜0.5 Zr ˜0.5 O 2 , doped HfO 2 , and combinations thereof.

11. The FET device of claim 10 , wherein the doped HfO 2 comprises a dopant selected from the group consisting of: N, C, Si, Al, La, Gd, Y, Sc, Sr, and combinations thereof.

12. A FET device, comprising:

a substrate comprising a first active area separated from a second active area by a STI region;

at least one FeFET on the substrate in the first active area having a ferroelectric material comprising a HfO 2 -based material selected from the group consisting of: pure HfO 2 , Hf ˜0.5 Zr ˜0.5 O 2 , doped HfO 2 , and combinations thereof; and

at least one logic FET alongside the at least one FeFET on the substrate in the second active area, wherein the at least one logic FET has a gate dielectric comprising the HfO 2 -based material, and wherein the at least one logic FET further comprises:

the gate dielectric disposed on the substrate;

a dielectric capping layer disposed on the gate dielectric;

a gate metal layer disposed on the dielectric capping layer;

a gate capping layer disposed on the gate metal layer; and

an additional gate metal layer disposed on the gate capping layer.

13. The FET device of claim 12 , wherein the doped HfO 2 comprises a dopant selected from the group consisting of: N, C, Si, Al, La, Gd, Y, Sc, Sr, and combinations thereof.

14. The FET device of claim 12 , wherein the at least one FeFET further comprises:

the ferroelectric material disposed on the substrate;

a dielectric capping layer disposed on the ferroelectric material; and

an electrode disposed on the dielectric capping layer.

15. The FET device of claim 14 , wherein the dielectric capping layer comprises a material selected from the group consisting of: La 2 O 3 , Al 2 O 3 , and combinations thereof.

16. The FET device of claim 14 , wherein the electrode comprises a metal selected from the group consisting of: TiN, TaN, and combinations thereof.

17. The FET device of claim 12 , wherein the dielectric capping layer and the gate capping layer each comprises a material selected from the group consisting of: La 2 O 3 , Al 2 O 3 and combinations thereof.

18. The FET device of claim 12 , wherein the gate metal layer and the additional gate metal each comprises a metal selected from the group consisting of: TiN, TaN, and combinations thereof.

Assignments (2)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 21, 2020
From: INTERNATIONAL BUSINESS MACHINES CORPORATION
To: SAMSUNG ELECTRONICS CO., LTD.
Reel/Frame 054126/0693 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Apr 25, 2019
From: FRANK, MARTIN M.; ANDO, TAKASHI; SUN, XIAO; HAN, JIN PING; NARAYANAN, VIJAY
To: INTERNATIONAL BUSINESS MACHINES CORPORATION
Reel/Frame 049001/0463 →
Continuity (2)
Division 15797774 · Oct 30, 2017
Related Publication 20190252500A1 · Aug 15, 2019
Cited By (1)
US 12,690,195