Traps for use with chromatography systems
Certain configurations are provided herein of a trap that can be used with chromatography systems. In certain instances, the trap may be designed to remove substantially all oil in a sample comprising the oil and an analyte of interest. Methods using the gravity trap are also described.
1. A gas chromatography system comprising:
an injector comprising an inlet port fluidically coupled to an outlet of the injector which is fluidically coupled to a common fluid line at the outlet of the injector, wherein the common fluid line splits into a first fluid line and a second fluid line, in which the injector is configured to receive a fluid sample comprising an oil and analyte of interest through the inlet port, vaporize the received fluid sample and provide the vaporized fluid sample through the common fluid line and the first and second fluid lines;
a trap fluidically coupled to the first fluid line, the trap configured to receive vaporized oil in the vaporized fluid sample from the first fluid line and trap and condense the vaporized oil in the fluid sample in the trap while permitting continued flow of vaporized analyte of interest to waste;
a gas chromatography column fluidically coupled to the second fluid line and configured to receive the vaporized fluid sample through the second fluid line to separate analytes in the received vaporized fluid sample;
a detector fluidically coupled to the gas chromatography column and configured to receive the separated analytes from the gas chromatography column and detect the separated analytes,
in which the trap is positioned outside of an instrument housing comprising the gas chromatography column, and the common fluid line travels from an internal space of the instrument housing to the outside of the instrument housing where the trap is positioned, and wherein the first fluid line penetrates into the trap to permit dripping of vaporized oil from the first fluid line into the trap as condensed oil.
2. The gas chromatography system of claim 1 , in which the trap is configured as a gravity trap constructed and arranged to receive the vaporized oil in the vaporized fluid sample, condense the vaporized oil and retain the condensed oil in the trap.
3. The gas chromatography system of claim 2 , in which the common fluid line comprises a split fitting fluidically coupled to the first fluid line and the second fluid line.
4. The gas chromatography system of claim 1 , in which a terminal portion of the first fluid line that penetrates into the trap is positioned at a lower height than a height of the inlet port of the injector.
5. The gas chromatography system of claim 1 , in which the trap further comprises a drain valve configured to permit removal of the condensed oil from the trap.
6. The gas chromatography system of claim 1 , further comprising an oven that receives the gas chromatography column.
7. The gas chromatography system of claim 1 , further comprising at least one flow controller fluidically coupled to the injector.
8. The gas chromatography system of claim 7 , further comprising a processor electrically coupled to the at least one flow controller.
9. The gas chromatography system of claim 1 , in which the trap comprises at least one material effective to absorb the condensed oil.
10. The gas chromatography system of claim 1 , in which the trap comprises a larger inner diameter than an outer diameter of the first fluid line.
11. The gas chromatography system of claim 1 , in which the detector is selected from the group consisting of a mass spectrometer, a thermal conductivity detector, a flame ionization detector, a flame photometric detector, a photoionization detector, an infrared detector, a catalytic combustion detector, a discharge ionization detector, an electron capture detector, a thermionic detector and a nitrogen-phosphorous detector.
12. A gas chromatography system comprising:
an injector comprising an inlet port fluidically coupled to an outlet of the injector which is fluidically coupled to a common fluid line at the outlet of the injector, wherein the common fluid line splits into a first fluid line and a second fluid line, in which the injector is configured to receive a fluid sample comprising an oil and analyte of interest through the inlet port, vaporize the received fluid sample and provide the vaporized fluid sample through the common fluid line and the first and second fluid lines;
a trap fluidically coupled to the first fluid line, the trap configured to receive vaporized oil in the vaporized fluid sample from the first fluid line and trap and condense the vaporized oil in the fluid sample in the trap while permitting continued flow of vaporized analyte of interest to waste;
a gas chromatography column fluidically coupled to the second fluid line and configured to receive the vaporized fluid sample through the second fluid line to separate analytes in the received vaporized fluid sample;
a detector fluidically coupled to the gas chromatography column and configured to receive the separated analytes from the gas chromatography column and detect the separated analytes, and
in which a first section of the common fluid line is positioned within an instrument housing comprising the gas chromatography column and a second section of the common fluid line is positioned outside of the instrument housing comprising the gas chromatography column.
13. The gas chromatography system of claim 12 , further comprising a flow controller configured to control the flow of carrier gas in the gas chromatography system.
14. The gas chromatography system of claim 13 , further comprising a processor electrically coupled to the flow controller.
15. The gas chromatography system of claim 14 , in which the trap comprises at least one material effective to absorb the condensed oil.
16. The gas chromatography system of claim 14 , in which the trap comprises a larger inner diameter than an outer diameter of the first fluid line.
17. The gas chromatography system of claim 14 , in which the detector is selected from the group consisting of a mass spectrometer, a thermal conductivity detector, a flame ionization detector, a flame photometric detector, a photoionization detector, an infrared detector, a catalytic combustion detector, a discharge ionization detector, an electron capture detector, a thermionic detector and a nitrogen-phosphorous detector.