Production method of rubber composition
View Patent ↗To provide a method for producing a rubber composition which gives a cross-linked rubber which has a low volume resistivity value, which is low in hardness, and which is kept down in contamination of the photoconductor when used as a conductive member. A production method of a rubber composition comprising a step of mixing a polyether rubber which is dissolved in a solvent at 0.1 to 30 wt % of concentration and a liquid ethylenically unsaturated nitrile-conjugated diene copolymer rubber in a solution is provided.
1. A production method of a rubber composition comprising a rubber component, which comprises a polyether rubber and a liquid ethylenically unsaturated nitrile-conjugated diene copolymer rubber, and a cross-linking agent, the production method comprising
a first step of mixing in a solution:
the polyether rubber dissolved in a solvent at 5 to 30 wt % concentration of the polyether rubber,
wherein the polyether rubber has, as main structural unit, oxyalkylene repeating units which are obtained by polymerizing an oxirane monomer by ring opening polymerization,
wherein the polyether rubber comprises ethylene oxide monomer units in an amount of 40 to 80 mol %; and
the liquid ethylenically unsaturated nitrile-conjugated diene copolymer rubber, wherein the liquid ethylenically unsaturated nitrile-conjugated diene copolymer rubber contains 10 to 60 wt % of ethylenically unsaturated nitrile monomer units and 40 to 90 wt % of conjugated diene monomer units,
a second step of coagulating and drying a composition containing the rubber component, which comprises the polyether rubber and the liquid ethylenically unsaturated nitrile-conjugated diene copolymer rubber, and the solvent so as to remove the solvent and obtain a solid composition, and
a third step of adding the cross-linking agent to the solid composition.
2. The production method of a rubber composition as set forth in claim 1 , wherein the ratio of said polyether rubber in the rubber component is 60 to 99 wt % and the ratio of said liquid ethylenically unsaturated nitrile-conjugated diene copolymer rubber in the rubber component is 40 to 1 wt %.
3. The production method of a rubber composition as set forth in claim 1 , wherein said liquid ethylenically unsaturated nitrile-conjugated diene copolymer rubber is a liquid acrylonitrile-butadiene rubber.
4. The production method of a rubber composition as set forth in claim 2 , wherein the ratio of said polyether rubber in the rubber component is 70 to 99 wt % and the ratio of said liquid ethylenically unsaturated nitrile-conjugated diene copolymer rubber in the rubber component is 30 to 1 wt %.
5. The production method of a rubber composition as set forth in claim 1 ,
wherein the rubber composition further comprises a cross-linking accelerator, and
the third step is a step where the cross-linking accelerator is further added to the solid composition in addition to the cross-linking agent.
6. The production method of a rubber composition as set forth in claim 1 ,
wherein the rubber composition further comprises a cross-linking accelerator and carbon black, and
the third step is a step where the cross-linking accelerator and the carbon black are further added to the solid composition in addition to the cross-linking agent.
7. The production method of a rubber composition as set forth in claim 1 ,
wherein, in the first step, a rubber other than the polyether rubber and the liquid ethylenically unsaturated nitrile-conjugated diene copolymer rubber is not used.
8. The production method of a rubber composition as set forth in claim 1 , the solvent is one or more selected from the group consisting of toluene, tetrahydrofuran, anisole, diethyl ether, ethyl acetate, ethyl benzoate, acetone, 2-butanone, acetophenone, acetonitrile, dimethylformamide, and dimethylsulfoxide.