Method for producing dielectric ceramic, and dielectric ceramic
A method for producing a dielectric ceramic includes: shaping mixed powdery particles including a cordierite material (2MgO.2Al 2 O 3 .5SiO 2 ) and a low-temperature-sintering material including Al, Si and Sr, the Si being partially vitrified; and firing the resultant shaped body. The method includes the step of wet-pulverizing the low-temperature-sintering material together with at least the cordierite material to prepare mixed powder particles having a median diameter D50 less than 1 μm; and, in a process until a time of the preparation of the mixed powder particles, the low-temperature-sintering material undergoes no step of wet-pulverizing only the low-temperature-sintering material, and drying the resultant pulverized material.
1. A method for producing a dielectric ceramic, comprising: shaping mixed powdery particles comprising a cordierite material (2MgO.2Al 2 O 3 .5SiO 2 ) and a low-temperature-sintering material comprising Al, Si and Sr, the Si being partially vitrified; and firing the resultant shaped body;
wherein the method comprises the step of wet-pulverizing the low-temperature-sintering material together with at least the cordierite material to prepare mixed powder particles having a median diameter D50 less than 1 μm;
wherein, in a process until a time of the preparation of the mixed powder particles, the low-temperature-sintering material undergoes no step of wet-pulverizing only the low-temperature-sintering material and drying the resultant pulverized material; and
wherein the resultant dielectric ceramic comprises, as a main phase thereof, Sr anorthite (SrAl 2 Si 2 O 8 ) and further comprises cordierite and alumina (Al 2 O 3 ); and has a dielectric constant of 6.5 or less at a frequency of 15 GHz and a porosity of 0.8% or less.
2. The method for producing a dielectric ceramic according to claim 1 , comprising the step of calcining raw materials to 850° C. or lower to yield the low-temperature-sintering material.
3. The method for producing a dielectric ceramic according to claim 1 , wherein the firing is performed at 1000° C. or lower.
4. The method for producing a dielectric ceramic according to claim 1 , wherein a slurry of the mixed powder particles yielded by the wet-pulverization, the slurry comprising an organic solvent, is sheet-shaped into ceramic green sheets; and the ceramic green sheets are laminated onto each other to yield the shaped body.
5. The method for producing a dielectric ceramic according to claim 1 , wherein the resultant dielectric ceramic is a ceramic substrate.
6. The method for producing a dielectric ceramic according to claim 1 , wherein before the step of preparing the mixed powder particles, the cordierite material is pulverized to have a particle diameter D95 of 0.5 to 3.0 μm.
7. The method for producing a dielectric ceramic according to claim 1 , wherein in the step of preparing the mixed powder particles, the mixed powder particles comprise Ag.