Method for preparing acrylic copolymer, acrylic copolymer and resin composition comprising the copolymer
Provided is a method for preparing an acrylic copolymer, and more specifically, provided are a method for preparing an acrylic copolymer including: i) adding and polymerizing 50 to 80 parts by weight of a methyl (meth)acrylate monomer and 10 to 49 parts by weight of a C2-C12 alkyl (meth)acrylate monomer, based on 100 parts by weight of a total monomer content, in a reactor (S1); and ii) adding and polymerizing 1 to 10 parts by weight of the methyl (meth)acrylate monomer, more than 0.01 part by weight to less than 1 part by weight of an acrylic cross-linking agent, and a surfactant, based on 100 parts by weight of the total monomer content, in which a polymerization conversion ratio of the polymerization in step (S1) is 70% to 90% (S2), an acrylic copolymer prepared therefrom, and a resin composition including the same.
1. A method for preparing an acrylic copolymer comprising:
i) adding and polymerizing 50 to 80 parts by weight of a methyl (meth)acrylate monomer and 10 to 49 parts by weight of a C2-C12 alkyl (meth)acrylate monomer, based on 100 parts by weight of a total monomer content, in a reactor (S1); and
ii) adding and polymerizing 1 to 10 parts by weight of the methyl (meth)acrylate monomer, more than 0.01 part by weight to less than 1 part by weight of an acrylic cross-linking agent, and a surfactant, based on 100 parts by weight of the total monomer content, in which a polymerization conversion ratio of the polymerization in (S1) is 70% to 90%.
2. The method of claim 1 , wherein the acrylic cross-linking agent is at least one selected from the group consisting of pentaerythritol diacrylate, pentaerythritol triacrylate, and pentaerythritol tetraacrylate.
3. The method of claim 1 , wherein the surfactant is represented by Chemical Formula 1 below:
in Chemical Formula 1,
R 1 , R 2 , and R 3 are each independently a C1-C10 alkylene group,
R 4 is a C1-C30 alkyl group, a C5-C30 cycloalkyl group, a C6-C30 aryl group, a C7-C30 alkylaryl group, a C7-C30 arylalkyl group, a C1-C30 alkyloxy group, a C5-C30 cycloalkyloxy group, a C6-C30 aryloxy group, a C7-C30 alkylaryloxy group, or a C7-C30 arylalkyloxy group, and
n is an integer selected from 1 to 30.
4. The method of claim 1 , wherein the acrylic copolymer polymerized in (S1) has a weight average molecular weight of 6,000,000 g/mol to 7,000,000 g/mol.
5. The method of claim 1 , wherein the acrylic copolymer polymerized in (S2) has a weight average molecular weight of 15,000,000 g/mol or more.
6. An acrylic copolymer comprising:
100 parts by weight of a monomer-derived repeating unit including 51 wt % to 90 wt % of a methyl (meth)acrylate monomer-derived repeating unit, 10 wt % to 49 wt % of a C2-C12 alkyl (meth)acrylate monomer-derived repeating unit;
more than 0.01 part by weight to less than 1 part by weight of an acrylic cross-linking agent-derived cross-linking part; and
a surfactant,
wherein a weight average molecular weight is 15,000,000 g/mol or more.
7. A resin composition comprising the acrylic copolymer of claim 6 and a vinyl chloride polymer.
8. The resin composition of claim 7 , wherein a foam molded article having a foaming length of 30 mm, which is obtained by foaming the resin composition using a twin-screw extruder at a cylinder temperature of 180° C., a screw speed of 30 rpm, and a slit die size of 2 mm (thickness)×30 mm (width), has a foaming specific gravity of less than 0.51 g/cm 3 .