All-inorganic solvents for electrolytes
An all-inorganic electrolyte formulation for use in a lithium ion battery system comprising at least one of each a phosphoranimine, a phosphazene, a monomeric organophosphate and a supporting lithium salt. The electrolyte preferably has a melting point below 0° C., and a vapor pressure of combustible components at 60.6° C. sufficiently low to not produce a combustible mixture in air, e.g., less than 40 mmHg at 30° C. A solid electrolyte interface layer formed by the electrolyte with an electrode is preferably thermally stable ≥80° C.
1. An electrolyte solvent formulation comprising:
a phosphoranimine;
a phosphazene present in an amount of between 3 and 30% by volume; and
optionally a monomeric phosphorus compound;
wherein a portion of the electrolyte solvent formulation is labile at a voltage of 5V and the portion is effective to scavenge free radicals and suppress free radical propagation;
being a liquid between at least 0° C. and 60.6° C., and having a vapor pressure of combustible components at 60.6° C. sufficiently low to not produce a combustible mixture in air.
2. The electrolyte solvent formulation according to claim 1 , wherein the formulation comprises the monomeric phosphorus compound, selected from the group consisting of a phosphate, phosphonate, phosphinate, phosphine, and a phosphine oxide, having at least two different types of pendent groups, sufficient to achieve a viscosity of the electrolyte solvent formulation of from 1 cp to less than about 30 cp at 35° C.
3. The electrolyte solvent formulation according to claim 1 , wherein the formulation comprises the monomeric phosphorus compound, in an amount of between 10% and 50% by volume, having the structure:
wherein R 10 , R 11 , and R 12 , are independently selected from the group consisting of alkyl, aryl, heteroalkyl, heteroaryl, halogen substituted alkyl, halogen substituted aryl, halogen substituted heteroalkyl, halogen substituted heteroaryl, alkoxy, aryloxy, heteroalkoxy, heteroaryloxy, halogen substituted alkoxy, halogen substituted aryloxy, halogen substituted heteroalkoxy, and halogen substituted heteroaryloxy functional groups, and the monomeric phosphorus compound is stable under an applied electrical potential 4 V.
4. The electrolyte solvent formulation according to claim 1 , wherein the phosphoranimine has the structure:
wherein R 1 , R 2 , and R 3 are independently selected from the group consisting of alkyl, aryl, heteroalkyl, heteroaryl, halogen substituted alkyl, halogen substituted aryl, halogen substituted heteroalkyl, halogen substituted heteroaryl, alkoxy, aryloxy, heteroalkoxy, heteroaryloxy, halogen substituted alkoxy, halogen substituted aryloxy, halogen substituted heteroalkoxy, and halogen substituted heteroaryloxy functional groups, wherein R 1 , R 2 , and R 3 are represented by at least two different substituents and wherein X is selected from the group consisting of an organosilyl group or a tert-butyl group.
5. The electrolyte solvent formulation according to claim 4 , wherein R 1 , R 2 , and R 3 are each independently selected from the group consisting of an alkoxy group, and an aryloxy group.
6. The electrolyte solvent formulation according to claim 1 , wherein the phosphazene is a substituted phosphazine having at least two different substituents selected from the group consisting of alkoxy and fluorinated alkoxy groups, and lacking phosphorus-halogen bonds.
7. The electrolyte solvent formulation according to claim 1 , wherein the formulation comprises the monomeric phosphorus compound, and
the phosphoranimine is present in an amount of between 20-80% by volume,
and
the monomeric phosphorus compound is present in an amount of 10-80% by volume.
8. A battery, comprising the electrolyte solvent formulation according to claim 1 , in combination with an anode, a cathode, a separator, and a supporting salt.
9. The electrolyte solvent formulation according to claim 1 , wherein the formulation is substantially free of compounds having any direct halogen-phosphorus bonds.
10. The electrolyte solvent formulation according to claim 1 , wherein
the phosphoranimine, the phosphazene, and the monomeric phosphorus compound each lacks phosphorus-halogen bonds, having a stability against degradation under an applied electrical potential of 4 V.