Delayed fluorescence material and organic light emitting device having the delayed fluorescence material

1. A delayed fluorescence material having a molecular structure, wherein the molecular structure includes an electron donor unit and an electron acceptor unit coupled to the electron donor unit, wherein the electron acceptor unit includes an indolocarbazole group having at least one acceptor functional-group bound to the indolocarbazole group,

wherein the molecular structure has one of following structures 1-3 and 1-6:

where each of D 1 , D 2 , and D 31 individually represents the electron donor unit,

wherein each of A 2 , A 31 and A 41 individually represents the acceptor functional-group, and

wherein each of R 1 to R 9 individually represents one selected from a group consisting of hydrogen, deuterium, an alkyl group having 1 to 60 carbon atoms, an alkylthio group having 1 to 10 carbon atoms, an alkyl-substituted amino group having 1 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, a diarylamino group having 12 to 24 carbon atoms, an alkoxycarbonyl group having 2 to 10 carbon atoms, an alkylsulfonyl group having 1 to 10 carbon atoms, a haloalkyl group having 1 to 10 carbon atoms, an amino group, an alkylamide group having 2 to 10 carbon atoms, a trialkylsilyl group having 3 to 20 carbon atoms, a trialkylsilylalkyl group having 4 to 20 carbon atoms, an alkenyl group having 2 to 60 carbon atoms, a trialkylsilylalkenyl group having 5 to 20 carbon atoms, an alkynyl group having 2 to 60 carbon atoms, a trialkylsilylalkynyl group having 5 to 20 carbon atoms, a cyano group, a nitro group, an aryl group having 6 to 60 carbon atoms, a heteroaryl group having 3 to 60 carbon atoms, an alkoxy group having 1 to 60 carbon atoms, an aryloxy group having 6 to 60 carbon atoms, an arylalkyl group having 7 to 60 carbon atoms, a heteroarylalkyl group having 3 to 60 carbon atoms, a cycloalkyl group having 3 to 60 carbon atoms, a heterocycloalkyl group having 1 to 60 carbon atoms, an alkylsilyl group having 3 to 60 carbon atoms, an arylsilyl group having 3 to 60 carbon atoms, a heteroarylsilyl group having 1 to 60 carbon atoms, and a substituted or unsubstituted aromatic 6-membered heterocycle having 3 to 30 carbon atoms, wherein at least two of R 1 to R 9 are the same or different, or adjacent two of R 1 to R 9 are coupled to form a ring,

and wherein at least one of A 2 , A 31 and A 41 individually includes a functional-group compound selected from a group consisting of compounds having following structural formulas 3-1, 3-2 and 3-4 respectively:

2. The delayed fluorescence material of claim 1 , wherein each of D 1 , D 2 and D 31 individually includes a functional-group compound derived from one selected from a group consisting of compounds having following structural formulas 2-1 to 2-52 respectively:

3. The delayed fluorescence material of claim 1 , wherein the molecular structure has one of following structural formulas:

4. An organic light-emitting device including a light emission layer, wherein the layer contains the delayed fluorescence material of claim 1 .

5. An organic light-emitting device including a light emission layer, wherein the layer contains the delayed fluorescence material of claim 2 .

6. An organic light-emitting device including a light emission layer, wherein the layer contains the delayed fluorescence material of claim 3 .

7. A delayed fluorescence material having a molecular structure of one of following structural formulas 1-1 to 1-6:

wherein each of D 0 , D 01 , D 1 , D 2 , D 11 , D 21 , D 3 and D 31 individually represents an electron donor unit that includes a functional-group compound derived from one selected from a group consisting of compounds having following structural formulas 2-2 to 2-52 respectively:

wherein each of A 1 , A 11 , A 2 , A 21 , A 3 , A 4 , A 31 and A 41 individually represents an acceptor functional-group that includes a functional-group compound selected from a group consisting of compounds having following structural formulas 3-1, 3-2 and 3-4 respectively:

wherein each of R 1 to R 9 individually represents one selected from a group consisting of hydrogen, deuterium, an alkyl group having 1 to 60 carbon atoms, an alkylthio group having 1 to 10 carbon atoms, an alkyl-substituted amino group having 1 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, a diarylamino group having 12 to 24 carbon atoms, an alkoxycarbonyl group having 2 to 10 carbon atoms, an alkylsulfonyl group having 1 to 10 carbon atoms, a haloalkyl group having 1 to 10 carbon atoms, an amino group, an alkylamide group having 2 to 10 carbon atoms, a trialkylsilyl group having 3 to 20 carbon atoms, a trialkylsilylalkyl group having 4 to 20 carbon atoms, an alkenyl group having 2 to 60 carbon atoms, a trialkylsilylalkenyl group having 5 to 20 carbon atoms, an alkynyl group having 2 to 60 carbon atoms, a trialkylsilylalkynyl group having 5 to 20 carbon atoms, a cyano group, a nitro group, an aryl group having 6 to 60 carbon atoms, a heteroaryl group having 3 to 60 carbon atoms, an alkoxy group having 1 to 60 carbon atoms, an aryloxy group having 6 to 60 carbon atoms, an arylalkyl group having 7 to 60 carbon atoms, a heteroarylalkyl group having 3 to 60 carbon atoms, a cycloalkyl group having 3 to 60 carbon atoms, a heterocycloalkyl group having 1 to 60 carbon atoms, an alkylsilyl group having 3 to 60 carbon atoms, an arylsilyl group having 3 to 60 carbon atoms, a heteroarylsilyl group having 1 to 60 carbon atoms, and a substituted or unsubstituted aromatic 6-membered heterocycle having 3 to 30 carbon atoms, wherein at least two of R 1 to R 9 are the same or different, or adjacent two of R 1 to R 9 are coupled to form a ring.

8. An organic light-emitting device including a light emission layer, wherein the layer contains the delayed fluorescence material of claim 7 .

9. A delayed fluorescence material having a molecular structure, wherein the molecular structure includes an electron donor unit and an electron acceptor unit coupled to the electron donor unit, wherein the electron acceptor unit includes an indolocarbazole group having at least one acceptor functional-group bound to the indolocarbazole group,

wherein the molecular structure has one of following structures 1-5 and 1-6:

where each of D 3 and D 31 individually represents the electron donor unit,

wherein each of A 3 , A 4 , A 31 and A 41 individually represents the acceptor functional-group, and

wherein each of R 1 to R 9 individually represents one selected from a group consisting of hydrogen, deuterium, an alkyl group having 1 to 60 carbon atoms, an alkylthio group having 1 to 10 carbon atoms, an alkyl-substituted amino group having 1 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, a diarylamino group having 12 to 24 carbon atoms, an alkoxycarbonyl group having 2 to 10 carbon atoms, an alkylsulfonyl group having 1 to 10 carbon atoms, a haloalkyl group having 1 to 10 carbon atoms, an amino group, an alkylamide group having 2 to 10 carbon atoms, a trialkylsilyl group having 3 to 20 carbon atoms, a trialkylsilylalkyl group having 4 to 20 carbon atoms, an alkenyl group having 2 to 60 carbon atoms, a trialkylsilylalkenyl group having 5 to 20 carbon atoms, an alkynyl group having 2 to 60 carbon atoms, a trialkylsilylalkynyl group having 5 to 20 carbon atoms, a cyano group, a nitro group, an aryl group having 6 to 60 carbon atoms, a heteroaryl group having 3 to 60 carbon atoms, an alkoxy group having 1 to 60 carbon atoms, an aryloxy group having 6 to 60 carbon atoms, an arylalkyl group having 7 to 60 carbon atoms, a heteroarylalkyl group having 3 to 60 carbon atoms, a cycloalkyl group having 3 to 60 carbon atoms, a heterocycloalkyl group having 1 to 60 carbon atoms, an alkylsilyl group having 3 to 60 carbon atoms, an arylsilyl group having 3 to 60 carbon atoms, a heteroarylsilyl group having 1 to 60 carbon atoms, and a substituted or unsubstituted aromatic 6-membered heterocycle having 3 to 30 carbon atoms, wherein at least two of R 1 to R 9 are the same or different, or adjacent two of R 1 to R 9 are coupled to form a ring.

10. An organic light-emitting device including a light emission layer, wherein the layer contains the delayed fluorescence material of claim 9 .