Adhesive resin laminate, laminate, and method of producing same
Provided are an adhesive resin laminate having an excellent adhesive force to two adherends, a laminate in which this adhesive resin laminate is laminated with two adherends, and a method of producing them. An adhesive resin laminate having at least a first adhesive layer and a second adhesive layer, in which the first adhesive layer includes a base resin and a crosslinking agent, the base resin is a modified polyolefin resin, the crosslinking agent is an epoxy-based compound, the second adhesive layer includes a polyolefin-based resin, and the first adhesive layer has a viscoelastic modulus measurement value E (150) at 150° C. of 1.0×10 4 Pa or more and 1.0×10 8 Pa or less.
1. A method of producing an adhesive resin laminate having at least a first adhesive layer and a second adhesive layer,
wherein said first adhesive layer comprises a base resin and a crosslinking agent, said base resin is a modified polyolefin resin and said crosslinking agent is an epoxy-based compound, said second adhesive layer comprises a polyolefin-based resin, and said first adhesive layer has a viscoelastic modulus measurement value E (150) at 150° C. of 1.0×10 4 Pa or more and 1.0×10 8 Pa or less,
the method comprising:
(1) a step of dissolving said modified polyolefin resin and said epoxy-based compound in a solvent to produce a coating liquid;
(2) a step of coating said coating liquid on a substrate film and drying the coating liquid to produce said first adhesive layer;
(3) a step of obtaining said second adhesive layer having a film shape by extrusion molding;
(4) a step of laminating said first adhesive layer on said substrate film and said second adhesive layer; and
(5) a step of peeling said substrate film to obtain said adhesive resin laminate, in this order.
2. A method of producing a laminate comprising an adhesive resin laminate having at least a first adhesive layer and a second adhesive layer; and first and second adherends, said adhesive resin laminate and said first and second adherends being laminated in an order of the first adherend, said first adhesive layer of said adhesive resin laminate, said second adhesive layer of said adhesive resin laminate, and the second adherend,
wherein said first adhesive layer comprises a base resin and a crosslinking agent, said base resin is a modified polyolefin resin and said crosslinking agent is an epoxy-based compound, said second adhesive layer comprises a polyolefin-based resin, and said first adhesive layer has a viscoelastic modulus measurement value E (150) at 150° C. of 1.0×10 4 Pa or more and 1.0×10 8 Pa or less,
the method comprising:
(1) a first step of laminating said first adherend and said first adhesive layer and heat-pressing said first adherend and said first adhesive layer to laminate said first adherend and said adhesive resin laminate; and
(2) a step of laminating said second adherend and said second adhesive layer and heat-pressing said second adherend and said second adhesive layer at a temperature higher than a temperature in said first step by 30° C. or more to laminate said second adherend and said adhesive resin laminate, in this order.