Electrochemical corrosion of catalyst material from PCD elements

1. A method of treating a cutter element comprising:

contacting a volume of polycrystalline diamond with an electrolyte solution, wherein the volume of the polycrystalline diamond comprises interbonded diamond grains and a catalyst material disposed in at least some interstitial spaces between adjacent diamond grains;

applying an electrical current between the volume of the polycrystalline diamond and a counter electrode, wherein the counter electrode is in contact with the electrolyte solution, wherein the electrolyte solution is acidic, wherein the electrolyte solution comprises iodide ions, and wherein the iodide ions have a concentration of less than 1.0 N;

maintaining a constant electrochemical potential on the volume of the polycrystalline diamond during the applying of the electrical current;

varying the electrical current between the volume of the polycrystalline diamond and the counter electrode to maintain the constant electrochemical potential; and

corroding at least a portion of the catalyst material from the interstitial spaces between the diamond grains.

2. The method of claim 1 , wherein maintaining the constant electrochemical potential comprises maintaining the constant electrochemical potential on the volume of the polycrystalline diamond with respect to a reference electrode.

3. The method of claim 1 , wherein the catalyst material comprises cobalt.

4. The method of claim 1 , wherein the electrolyte solution comprises a mineral acid having a normality of less than 1.0.

5. The method of claim 1 , wherein the iodide ions have a concentration of less than 0.3 N.

6. The method of claim 1 , wherein the electrolyte solution comprises a buffer.

7. The method of claim 1 , further comprising: circulating the electrolyte solution while applying the electrical current.

8. The method of claim 1 , wherein corroding at least the portion of the catalyst material comprises oxidizing the catalyst material to form a corrosion product that is soluble in the electrolyte solution.

9. The method of claim 1 , wherein maintaining the constant electrochemical potential and the corroding at least the portion of the catalyst material comprise:

potentiostatically corroding at least the portion of the catalyst material from the interstitial spaces between the material grains in the volume of polycrystalline diamond.

10. The method of claim 9 , wherein potentiostatically corroding at least the portion of the catalyst material from the interstitial spaces comprises maintaining an electrode potential between the volume of the polycrystalline diamond and a reference electrode constant while applying a current between the volume of the polycrystalline diamond and the counter electrode.

11. A method of treating a cutter element comprising:

contacting a volume of polycrystalline diamond with an electrolyte solution, wherein the electrolyte solution comprises iodide ions and wherein the iodide ions have a concentration of less than 1.0 N, and wherein the volume of the polycrystalline diamond comprises interbonded diamond grains and a catalyst material disposed in at least some interstitial spaces between adjacent diamond grains;

applying an electrical current between the volume of the polycrystalline diamond and a counter electrode, wherein the counter electrode is in contact with the electrolyte solution;

maintaining a constant electrochemical potential on the volume of the polycrystalline diamond during the applying of the electrical current;

varying the electrical current between the volume of the polycrystalline diamond and the counter electrode to maintain the constant electrochemical potential;

corroding at least a portion of the catalyst material from the interstitial spaces between the diamond grains; and

circulating the electrolyte solution during the applying of the electrical current, wherein circulating the electrolyte solution comprises: pumping the electrolyte solution through a housing containing the electrolyte solution, the volume of the polycrystalline diamond, and the counter electrode while applying the electrical current,

wherein the constant electrode potential is maintained between a reference electrode and the volume of polycrystalline diamond, wherein the reference electrode is in the circulating electrolyte solution and is disposed upstream of the volume of polycrystalline diamond.

12. The method of claim 11 , wherein circulating the electrolyte solution comprises using a stirring device within a housing containing the electrolyte solution, the volume of the polycrystalline diamond, and the counter electrode.

13. The method of claim 11 , wherein the catalyst material comprises cobalt.

14. The method of claim 11 , wherein the electrolyte solution comprises a mineral acid having a normality of less than 1.0.

15. The method of claim 11 , wherein the constant electrochemical potential is between about −0.2 V (SCE) and about 2.5 V (SCE).

16. The method of claim 1 , wherein the constant electrochemical potential is between about −0.2 V (SCE) and about 2.5 V (SCE).