All-solid-state lithium rechargeable cells
Provided is an all-solid-state lithium rechargeable cell, comprising: a) a cathode, wherein the cathode comprises: a1) a composite of VS4 and graphene; and a2) a solid catholyte; and b) a lithium-based anode. In particular, the all-solid-state lithium rechargeable cell of the present disclosure may exhibit high initial discharge capacities, high initial Coulombic efficiencies, good reversible capacities, excellent cycling stabilities, high energy densities as well as outstanding safeties.
1. An all-solid-state lithium rechargeable cell, comprising:
a) a cathode, wherein the cathode comprises:
a1) a composite of VS 4 and graphene; and
a2) a solid catholyte; and
b) a lithium-based anode.
2. The all-solid-state lithium rechargeable cell according to claim 1 , wherein the composite of VS 4 and graphene has a structure that VS 4 particles chemically bond with or physically embed in graphene sheets.
3. The all-solid-state lithium rechargeable cell according to claim 1 , wherein the graphene is a reduction product of graphene oxide.
4. The all-solid-state lithium rechargeable cell according to claim 1 , wherein the catholyte is selected from polyethylene oxide, a lithium ion-conducting sulfide, a lithium ion-conducting chloride and their combinations.
5. The all-solid-state lithium rechargeable cell according to claim 1 , wherein the lithium-based anode is selected from the group consisting of lithium metal, lithium alloys, pre-lithiated graphite, pre-lithiated silicon, stacks consisting of a layer of lithium metal and one or more layers of other metals, and their combinations.
6. The all-solid-state lithium rechargeable cell according to claim 1 , wherein the cathode further comprises: a3) a conductive additive.
7. The all-solid-state lithium rechargeable cell according to claim 1 , wherein the cathode further comprises: a4) a binder.
8. The all-solid-state lithium rechargeable cell according to claim 1 , further comprising: c) a solid electrolyte located between the cathode and the anode, wherein the solid electrolyte and the solid catholyte are formed from identical or different materials.
9. The all-solid-state lithium rechargeable cell according to claim 1 , wherein the cathode comprises:
a1) 20 to 95 weight parts of the composite of VS 4 and graphene;
a2) 5 to 80 weight parts of the solid catholyte;
a3) 0 to 40 weight parts of the conductive additive; and
a4) 0 to 20 weight parts of the binder.
10. The all-solid-state lithium rechargeable cell according to claim 1 , wherein the content of the graphene is more than 0% by weight but no more than 20% by weight, based on the total weight of the composite of VS 4 and graphene.