Polyisocyanurate polymer and process for the production of polyisocyanurate polymers
The present invention relates to novel polyisocyanurate plastics which are obtainable by catalytic trimerization of a polyisocyanate composition A) which contains oligomeric polyisocyanates and is low in monomeric diisocyanates. “Low in monomeric diisocyanates” means that the polyisocyanate composition A) has a content of monomeric diisocyanates of at most 20% by weight. The invention further relates to the use of these polyisocyanurate plastics for production of coatings, films, semi-finished products and mouldings, and to a process for producing polyisocyanurate plastics comprising the following steps: (a) providing a polyisocyanate composition A) which contains oligomeric polyisocyanates and is low in monomeric diisocyanates, “low in monomeric diisocyanates” meaning that the polyisocyanate composition A) has a content of monomeric diisocyanates of at most 20% by weight; (b) catalytically trimerizing the polyisocyanate composition A).
1. A process for producing polyisocyanurate plastics, comprising the following steps:
a) providing a polyisocyanate composition A) which contains oligomeric polyisocyanates and is low in monomeric diisocyanates, “low in monomeric diisocyanates” meaning that the polyisocyanate composition A) has a content of monomeric diisocyanates of at most 20% by weight;
b) catalytically trimerizing the polyisocyanate composition A) until at least 95% of free isocyanate groups present in the polyisocyanate composition prior to step b) have reacted.
2. The process according to claim 1 , wherein in the oligomeric polyisocyanate a proportion of isocyanurate groups makes up at least 50 mol-% of the sum total of oligomeric polyisocyanates consisting of uretdione, isocyanurate, allophanate, biuret, iminooxadiazinedione and oxadiazinetrione structures.
3. The process according to claim 1 , wherein the polyisocyanate composition A) consists to an extent of at least 70% by weight of polyisocyanates having exclusively aliphatically and/or cycloaliphatically bound isocyanate groups.
4. The process according to claim 1 , wherein trimerization means cyclotrimerization of at least 50% of the isocyanate groups present in the polyisocyanate composition A) to isocyanurate structural units.