Aluminum alloy substrate for magnetic discs and manufacturing method therefor, as well as magnetic disc using said aluminum alloy substrate for magnetic discs
The present invention provides: an aluminum alloy substrate for magnetic discs with excellent plating surface smoothness; a manufacturing method therefor; and a magnetic disc using said aluminum alloy substrate for magnetic discs. The present invention is an aluminum alloy substrate for magnetic discs, a manufacturing method therefor, and a magnetic disc using said aluminum alloy substrate for magnetic discs, the aluminum alloy substrate being characterized in being obtained from an aluminum alloy containing Mg: 2.0-8.0 mass % (“%” below), Be: 0.00001-0.00200%, Cu: 0.003-0.150%, Zn: 0.05-0.60%, Cr: 0.010-0.300%, Si: 0.060% or less, Fe: 0.060% or less, the balance being obtained from Al and unavoidable impurities.
1. An aluminum alloy substrate for magnetic discs comprising an aluminum alloy containing 2.0 to 8.0 mass % Mg, 0.00001 to 0.00200 mass % Be, 0.003 to 0.150 mass % Cu, 0.05 to 0.60 mass % Zn and 0.010 to 0.300 mass % Cr, and restricted to 0.060 mass % or less Si and 0.060 mass % or less Fe, and a content of Cl in the aluminum alloy, as measured by glow discharge mass spectrometry, is restricted to 0.00300 mass % or less, with a balance of Al and unavoidable impurities, wherein
when the aluminum alloy substrate is subjected to a pre-plating treatment and plated with a plating layer, the distribution of plating pits having the longest diameter of 1 μm or more as measured using an optical microscope in an observation viewing field of 1 mm 2 at a magnification of 1,000 times is 1 pit per mm 2 or less, and a distribution of plating pits having a longest diameter of 0.5 μm to less than 1 μm as measured using a scanning electron microscope (SEM) with an observation viewing field of 1 mm 2 at a magnification of 2,000 times is 7 pits/mm 2 or less.
2. The aluminum alloy substrate for magnetic discs according to claim 1 , wherein the aluminum alloy contains 0.00001 to 0.00025 mass % Be.
3. The aluminum alloy substrate for magnetic discs according to claim 1 , wherein, with respect to the substrate before subjected to pre-plating treatment, when the maximum intensity [a.u.] of Be in the surface depth direction, as measured by means of a glow discharge optical emission spectrometry is taken as I Be , the average intensity [a.u.] of Be inside a matrix of the aluminum alloy is taken as I bulk , and the Be content is taken as C Be , the relationship: I Be /I bulk ×C Be ≤0.1000 is satisfied.
4. The aluminum alloy substrate for magnetic discs according to claim 2 , wherein, with respect to the substrate before subjected to pre-plating treatment, when the maximum intensity [a.u.] of Be in the surface depth direction, as measured by means of a glow discharge optical emission spectrometry is taken as I Be , the average intensity [a.u.] of Be inside a matrix of the aluminum alloy is taken as I bulk , and the Be content is taken as C Be , the relationship: I Be /I bulk ×C Be ≤0.1000 is satisfied.
5. A method for manufacturing the aluminum alloy substrate for magnetic discs according to claim 3 or claim 4 , comprising:
a casting step for casting the aluminum alloy, a hot rolling step for subjecting a resultant slab to hot rolling, a cold rolling step for subjecting the hot rolled plate to cold rolling, a processing step for processing the cold rolled plate into an annular disc, a pressure flattening annealing step for subjecting the annular disc to pressure flattening to obtain a disc blank, a lathing/grinding step for the disc blank, and a heating treatment step for subjecting the cut/ground disc blank to heating treatment,
wherein the heating treatment step has a heating temperature increase stage in which the disc blank is heated from 150° C. to a holding temperature in the range of from 200 to 400° C. at a temperature increase rate of 20.0° C./minute or more, a heating and maintaining stage in which the disc blank is heated and maintained at the holding temperature for 5 to 15 minutes, and a cooling temperature decrease stage in which the disc blank is cooled from the holding temperature to 150° C. at a temperature decrease rate of 20.0° C./minute or more.
6. A magnetic disc comprising a plating and a magnetic material formed on the aluminum alloy substrate for magnetic discs according to any one of claims 1 - 2 , 3 and 4 .
7. An aluminum alloy substrate for magnetic discs comprising an aluminum alloy containing 2.0 to 8.0 mass % Mg, 0.00001 to 0.00200 mass % Be, 0.003 to 0.150 mass % Cu, 0.05 to 0.60 mass % Zn and 0.010 to 0.300 mass % Cr, and restricted to 0.060 mass % or less Si and 0.060 mass % or less Fe, and a content of Cl in the aluminum alloy, as measured by glow discharge mass spectrometry, is restricted to 0.00300 mass % or less, with a balance of Al and unavoidable impurities, wherein
when the aluminum alloy substrate is subjected to a pre-plating treatment and plated with an electroless Ni—P plating layer, the distribution of plating pits having the longest diameter of 1 μm or more as measured using an optical microscope in an observation viewing field of 1 mm 2 at a magnification of 1,000 times is 1 pit per mm 2 or less, and a distribution of plating pits having a longest diameter of 0.5 μm to less than 1 μm as measured using a scanning electron microscope (SEM) with an observation viewing field of 1 mm 2 at a magnification of 2,000 times is 7 pits/mm 2 or less.