IP Library › Granted Patent US 10,759,753
Granted Patent B2
US 10,759,753 · App. 16/011,077 · Granted Sep 1, 2020

Bismaleimide modified product and method for producing the same

Inventors: Yuki Yamada (Uji, JP); Tatsuya Morikita (Uji, JP); Takeshi Yoshida (Uji, JP); Akira Shigeta (Uji, JP); Yoshiaki Echigo (Uji, JP)
Assignee: UNITIKA LTD.
C07D207/448
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Quick Facts
Patent No.
US 10,759,753
App. No.
16/011,077
Granted
Sep 1, 2020
Kind
B2
Abstract

An object of the present invention is to provide a bismaleimide (D-BMI) modified product in which an amino group of dimer diamine (DDA) is maleimidized, which has the good heat resistance, and has the sufficiently enhanced processability, and a method for producing the same. There are provided: <1> A bismaleimide (D-BMI) modified product in which an amino group of dimer diamine is maleimidized, the bismaleimide modified product having the following characteristics: 1) An acid value of the D-BMI modified product is 2 mg-KOH/g or less. 2) In 1 H-NMR, when quantitative comparison is performed using an integrated value (A) of a peak corresponding to a proton of a methylene group directly bound to a nitrogen atom of a maleimide group and an integrated value (B) of a peak corresponding to a vinyl proton of a maleimide group, A/B is 1.25 or more and 2.00 or less. <2> A method for producing D-BMI, the method including the following steps: 1) A step of preparing a crude D-BMI solution having an acid value of more than 2 mg-KOH/g. 2) A step of lowering an acid value of D-BMI to 2 mg-KOH/g or less by reacting an acid component in the solution with a carbodiimide compound. 3) A step of reacting the solution without a catalyst at 110 to 200° C. in a solvent.

Claims (4)

1. A bismaleimide (D-BMI) modified product in which an amino group of dimer diamine is maleimidized, the bismaleimide modified product having the following characteristics:

1) An acid value of the D-BMI modified product is 2 mg-KOH/g or less; and

2) In 1 H-NMR, when quantitative comparison is performed using an integrated value (A) of a peak corresponding to two protons of a methylene group directly bound to a nitrogen atom of a maleimide group and an integrated value (B) of a peak corresponding to two vinyl protons of a maleimide group, A/B is 1.25 or more and 2.00 or less.

2. The D-BMI modified product of claim 1 , wherein the A/B is 1.30 or more and1.80 or less.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Aug 10, 2018
From: YAMADA, YUKI; MORIKITA, TATSUYA; YOSHIDA, TAKESHI; SHIGETA, AKIRA; ECHIGO, YOSHIAKI
To: UNITIKA LTD.
Reel/Frame 046616/0700 →
Priority Claims (1)
JP 2017-119655 · Jun 19, 2017 · national
Continuity (1)
Related Publication 20180362463A1 · Dec 20, 2018