Large energy density batteries
Embodiments of the claimed invention are directed to a device, comprising: an anode that includes a lithiated silicon-based material and a sulfur-based cathode, wherein the anode and the cathode are designed to have mesoporous structures. In certain embodiments, the sulfur-based cathode is a mesoporous carbon structure comprising sulfur within the mesopores. A further embodiment of the invention is directed to a device comprising a semi-liquid lithium-sulfur battery comprising a lithium anode and a sulfur cathode. In certain embodiments, the sulfur cathode comprises a liquid catholyte, which is housed within a reservoir that is a carbon nanotube sponge. An additional embodiment of the invention is directed to a method for producing a lithiated silicon anode and a sulfur-based cathode.
1. A device, comprising:
an anode that includes a lithiated silicon-based material;
a current collector-free electrode comprising a sulfur-based cathode; and
a reservoir that houses the sulfur-based cathode, wherein the reservoir comprises a flexible, porous carbon structure, wherein the porous carbon structure comprises liquid sulfur catholyte within its pores, and wherein the porous carbon structure comprises carbon nanotubes that are physically bonded together and intertwined.
2. The device of claim 1 , further comprising a separator between the sulfur-based cathode and the anode, wherein the separator is configured to facilitate transport of lithium ions between the anode and the sulfur-based cathode and to inhibit flow of other materials therebetween.
3. The device of claim 1 , wherein the porous carbon structure is a carbon nanotube sponge.
4. The device of claim 1 , wherein the porous carbon structure is an electrically conducting reservoir.
5. The device of claim 3 , wherein the carbon nanotube sponge is a reservoir for a liquid polysulfide.
6. The device of claim 1 , wherein the anode comprises mesoporous silicon.
7. The device of claim 3 , wherein the carbon nanotube sponge comprises any of single-walled, double-walled, and multi-walled carbon nanotubes.
8. A semi-liquid lithium-sulfur battery comprising:
a lithium anode;
a current collector-free electrode comprising a sulfur cathode; and
a liquid catholyte containing a LiNO 3 additive, wherein the liquid catholyte is housed within pores of a flexible, porous carbon nanotube sponge reservoir, wherein the reservoir comprises carbon nanotubes that are physically bonded together and intertwined.
9. The semi-liquid lithium-sulfur battery of claim 8 , wherein the liquid catholyte comprises polysulfide.
10. The semi-liquid lithium-sulfur battery of claim 8 , wherein the carbon nanotube sponge is elastic.
11. The semi-liquid lithium-sulfur battery of claim 9 , wherein the liquid catholyte is Li 2 S 6 .
12. A semi-liquid lithium-sulfur battery comprising:
a carbon nanotube sponge anode comprising lithium;
a current collector-free electrode comprising a sulfur cathode; and
a liquid catholyte containing a LiNO 3 additive, wherein the liquid catholyte is housed within pores of a flexible, porous carbon nanotube sponge reservoir, wherein the reservoir comprises carbon nanotubes that are physically bonded together and intertwined.
13. A method to produce a lithiated silicon-sulfur battery, the method comprising:
synthesizing a current collector-free sulfur cathode;
synthesizing a silicon anode, wherein the silicon anode is lithiated; and
placing the cathode in a reservoir, wherein the reservoir is a flexible, porous carbon nanotube sponge and the reservoir contains a liquid catholyte and wherein the reservoir comprises carbon nanotubes that are physically bonded together and intertwined.
14. The method of claim 13 , wherein synthesizing the sulfur cathode comprises infusing sulfur into a porous material, wherein the porous material serves as a charge transfer path and a polysulfide reservoir.
15. The method of claim 14 , wherein the porous material comprises carbon nanotubes that are synthesized by chemical vapor deposition and are physically bonded to each other.
16. The method of claim 13 , wherein synthesizing the silicon anode comprises:
reducing mesoporous silica magnesiothermically; and
lithiating the mesoporous silica.