IP Library › Granted Patent US 10,766,988
Granted Patent B2
US 10,766,988 · App. 16/094,722 · Granted Sep 8, 2020

Ethylene/alpha-olefin copolymer having excellent processibility

Inventors: Soon Ho Sun (Daejeon, KR); Yi Young Choi (Daejeon, KR); Ki Soo Lee (Daejeon, KR); Bog Ki Hong (Daejeon, KR); Sung Hyun Park (Daejeon, KR); Myung Han Lee (Daejeon, KR); Sung Min Lee (Daejeon, KR); Sun Mi Kim (Daejeon, KR); Jin Young Park (Daejeon, KR)
Assignee: LG Chem, Ltd.
C08F210/16C08F4/65908C08F4/65912C08F4/65916
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Quick Facts
Patent No.
US 10,766,988
App. No.
16/094,722
Granted
Sep 8, 2020
Kind
B2
Abstract

The present disclosure relates to an ethylene/alpha-olefin copolymer having excellent processibility. The ethylene/alpha-olefin copolymer according to the present disclosure is excellent in both mechanical properties and processibility.

Claims (23)

1. An ethylene/alpha-olefin copolymer having:

a weight average molecular weight of 180,000 to 250,000 g/mol,

a molecular weight distribution (Mw/Mn) of 5 to 20,

a density of 0.950 to 0.965 g/cm 3 ,

a melt flow rate ratio MFR 5 /MFR 2.16 , measured at 190° C. according to ASTM 1238 of 5 to 10, and

a spiral flow length of 15 to 25 cm, wherein the spiral flow length is evaluated by using a mold having a thickness of 1.5 mm, an injection temperature of 190° C., a mold temperature of 50° C., and an injection pressure of 90 bar,

wherein the ethylene/alpha-olefin copolymer is prepared by polymerizing ethylene and alpha-olefin in the presence of a supported single metallocene catalyst including a metallocene compound of the following Chemical Formula 1; an aluminum-containing first cocatalyst; a borate-based second cocatalyst; and a support:

(Cp 1 R 1 ) n (Cp 2 R 2 )MX 3-n   [Chemical Formula 1]

in Chemical Formula 1,

M is a Group 4 transition metal;

Cp 1 and Cp 2 are same as or different from each other, and are each independently any one selected from the group consisting of cyclopentadienyl, indenyl, 4,5,6,7-tetrahydro-1-indenyl, and fluorenyl radical, provided that both Cp 1 and Cp 2 are not cyclopentadienyl, and they are optionally substituted with a C1 to C20 hydrocarbon;

R 1 and R 2 are same as or different from each other, and are each independently hydrogen, a C1 to C20 alkyl, a C1 to C10 alkoxy, a C2 to C20 alkoxyalkyl, a C6 to C20 aryl, a C6 to C10 aryloxy, a C2 to C20 alkenyl, a C7 to C40 alkylaryl, a C7 to C40 arylalkyl, a C8 to C40 arylalkenyl, or a C2 to C10 alkynyl;

X is a halogen atom, a C1 to C20 alkyl, a C2 to C10 alkenyl, a C7 to C40 alkylaryl, a C7 to C40 arylalkyl, a C6 to C20 aryl, a substituted or unsubstituted C1 to C20 alkylidene, a substituted or unsubstituted amino, a C2 to C20 alkylalkoxy, or a C7 to C40 arylalkoxy; and

n is 1 or 0.

2. The ethylene/alpha-olefin copolymer of claim 1 , wherein the weight average molecular weight is 180,000 to 220,000 g/mol.

3. The ethylene/alpha-olefin copolymer of claim 1 , wherein the molecular weight distribution (Mw/Mn) is 10 to 15.

4. The ethylene/alpha-olefin copolymer of claim 1 , wherein the melt flow rate ratio is 5 to 8.

5. The ethylene/alpha-olefin copolymer of claim 1 , wherein a C 2 value of Equation 1 is −1.0 to −0.4, when a graph of complex viscosity (η*[Pa·s]) versus frequency (ω[rad/s]) of the ethylene/alpha-olefin copolymer is fitted to Power Law of the following Equation 1:

y=c 1 x c 2   [Equation 1]

wherein x means frequency, y means complex viscosity, and c1 refers to a consistency index.

6. The ethylene/alpha-olefin copolymer of claim 1 , wherein a plateau delta value in a Van Gurp Palmen plot of the ethylene/alpha-olefin copolymer is 0.1 to 1.0 rad,

wherein in the Van Gurp-Palmen plot, the x-axis represents complex modulus (G, dyne/cm 2 ) and the y-axis represents phase angle (d(delta)).

7. The ethylene/alpha-olefin copolymer of claim 1 , wherein the alpha-olefin is at least one selected from the group consisting of 1-propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1-pentene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene, 1-hexadecene, 1-octadecene, and 1-eicosene.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Oct 19, 2018
From: SUN, SOON HO; CHOI, YI YOUNG; LEE, KI SOO; HONG, BOG KI; PARK, SUNG HYUN; LEE, MYUNG HAN; LEE, SUNG MIN; KIM, SUN MI; PARK, JIN YOUNG
To: LG CHEM, LTD.
Reel/Frame 047236/0115 →
Priority Claims (1)
KR 10-2016-0152220 · Nov 15, 2016 · national
Continuity (1)
Related Publication 20190119421A1 · Apr 25, 2019
Cited By (1)
US 12,612,475