IP Library › Granted Patent US 10,767,068
Granted Patent B2
US 10,767,068 · App. 16/079,043 · Granted Sep 8, 2020

Photocurable inkjet printing ink composition

Inventors: Okinori Nakashima (Osaka, JP); Takuya Myose (Osaka, JP); Takuya Okamoto (Osaka, JP); Kazuhiro Fuke (Osaka, JP)
Assignee: SAKATA INX CORPORATION
C09D11/38C09D11/037C09D11/101C09D11/106C09D11/107C09D11/30C09D11/32
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Quick Facts
Patent No.
US 10,767,068
App. No.
16/079,043
Granted
Sep 8, 2020
Kind
B2
Abstract

A photocurable inkjet printing ink composition contains a photopolymerizable compound and a photopolymerization initiator, wherein in 100 percent by mass of the photocurable inkjet printing ink composition, included are: an acrylamide-based monomer by 5.0 to 50 percent by mass; a monofunctional monomer other than acrylamide-based monomer by 15 to 70 percent by mass; a polymerizable compound having two or more functionalities by 5.0 to 30.0 percent by mass; vinyl caprolactam by 0.1 to 15 percent by mass and/or an acrylated amine compound having two photopolymerizable functional groups and two amino groups in the molecule by 0 to 10 percent by mass; and the percentage of monofunctional monomers in the photopolymerizable compound is 60 to 99.5 percent by mass.

Claims (21)

1. A photocurable inkjet printing ink composition containing a photopolymerizable compound and a photopolymerization initiator, wherein in 100 percent by mass of the photocurable inkjet printing ink composition, included are:

a. an acrylamide-based monomer by 22.0 to 50 percent by mass, which is expressed by General Formula (I) below:

CH 2 ═CR4-CON(R5)R6

wherein R4 represents a hydrogen atom or a methyl group; R5 and R6 may be the same or different, and although they are each a hydrogen atom or a substituted or an unsubstituted alkyl group with the carbon number from 1 to 8, they are not a hydrogen atom at the same time; and alternatively, R5 and R6 may be bonded to form a ring together with an adjacent nitrogen atom;

b. a monofunctional monomer other than acrylamide-based monomer by 15 to 70 percent by mass;

c. a polymerizable compound having two or more functionalities by 5.0 to 20.0 percent by mass;

d. an acrylated amine compound having two photopolymerizable functional groups and two amino groups in the molecule by more than 0 percent by mass but no more than 10 percent by mass; and

e. the percentage of monofunctional monomers in the photopolymerizable compound is 60 to 99.5 percent by mass.

2. The photocurable inkjet printing ink composition according to claim 1 , wherein the acrylamide-based monomer is an acryloyl morpholine.

3. The photocurable inkjet printing ink composition according to claim 1 , wherein the photopolymerization initiator contains an acylphosphine oxide photopolymerization initiator and the acylphosphine oxide photopolymerization initiator accounts for 2 to 15 percent by mass relative to 100 percent by mass of the photopolymerizable compound.

4. The photocurable inkjet printing ink composition according to claim 1 , wherein the photopolymerization initiator contains a thioxanthone photopolymerization initiator and the thioxanthone photopolymerization initiator accounts for 5 percent by mass or less relative to 100 percent by mass of the photopolymerizable compound.

5. The photocurable inkjet printing ink composition according to claim 1 , which contains a coloring agent.

6. The photocurable inkjet printing ink composition according to claim 1 , of which viscosity at 25° C. is 5.0 to 30 m·Pas.

7. The photocurable inkjet printing ink composition according to claim 2 , wherein the photopolymerization initiator contains an acylphosphine oxide photopolymerization initiator and the acylphosphine oxide photopolymerization initiator accounts for 2 to 15 percent by mass relative to 100 percent by mass of the photopolymerizable compound.

8. The photocurable inkjet printing ink composition according to claim 2 , wherein the photopolymerization initiator contains a thioxanthone photopolymerization initiator and the thioxanthone photopolymerization initiator accounts for 5 percent by mass or less relative to 100 percent by mass of the photopolymerizable compound.

9. The photocurable inkjet printing ink composition according to claim 2 , which contains a coloring agent.

10. The photocurable inkjet printing ink composition according to claim 2 , of which viscosity at 25° C. is 5.0 to 30 mPa·s.

11. The photocurable inkjet printing ink composition according to claim 3 , wherein the photopolymerization initiator contains a thioxanthone photopolymerization initiator and the thioxanthone photopolymerization initiator accounts for 5 percent by mass or less relative to 100 percent by mass of the photopolymerizable compound.

12. The photocurable inkjet printing ink composition according to claim 3 , which contains a coloring agent.

13. The photocurable inkjet printing ink composition according to claim 3 , of which viscosity at 25° C. is 5.0 to 30 mPa·s.

14. The photocurable inkjet printing ink composition according to claim 4 , which contains a coloring agent.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 26, 2019
From: NAKASHIMA, OKINORI; MYOSE, TAKUYA; OKAMOTO, TAKUYA; FUKE, KAZUHIRO
To: SAKATA INX CORPORATION
Reel/Frame 048705/0948 →
Priority Claims (1)
JP 2016-032395 · Feb 23, 2016 · national
Continuity (1)
Related Publication 20190062580A1 · Feb 28, 2019
Cited By (1)
US 12,480,011