Method for producing paper, board or the like
The invention relates to a method for producing paper, board or the like. The method comprises obtaining a thick stock comprising cellulose fibres, forming a fibrous web and drying of drying the fibrous web. A strength agent system, which comprises at least one synthetic or natural polymer, or their mixture, and microfibrillated parenchymal cellulose material originating from non-wood sources, is added to the thick stock. The invention relates also to paper or board produced by the method.
1. A method for producing paper or board, comprising:
obtaining a thick stock comprising cellulose fibres;
forming a fibrous web; and
drying the fibrous web,
wherein
a strength agent system, comprising at least one synthetic or natural polymer or their mixture and a microfibrillated parenchymal cellulose material originating from non-wood sources is added to the thick stock, and
wherein a cationic retention polymer, which is a cationic polyacrylamide having an average molecular weight of 4,000,000-18,000 000 Da is added to the stock after the addition of the strength agent system.
2. The method according to claim 1 , wherein the microfibrillated parenchymal cellulose material originates from vegetables; fruits; cellulose pith; and mixtures thereof.
3. The method according to claim 2 , wherein the microfibrillated parenchymal cellulose material originates from vegetables selected from sugar beet pulp, potato pulp, cassava pulp, sweet potato and any mixtures thereof.
4. The method according to claim 1 , wherein the microfibrillated parenchymal cellulose material is obtained by mechanical treatment, without preceding treatment steps, which are selected from oxidation, extraction and/or washing.
5. The method according to claim 4 , wherein the mechanical treatment is homogenization.
6. The method according to claim 1 , wherein the microfibrillated parenchymal cellulose material has:
a Brookfield viscosity of at least 10 Pas, measured at concentration of 1.0 weight-% at 100 rpm shear rate, and/or
a turbidity value less than 1000 NTU, measured at 0.1 weight-% concentration, and/or
a net charge in a range of −0.001-1.99 meq/g, at pH 7.5.
7. The method according to claim 1 , wherein the Brookfield viscosity of the microfibrillated parenchymal cellulose material is in a range of 500 2000 Pas.
8. The method according to claim 1 , wherein the turbidity of the microfibrillated parenchymal cellulose material may be in a range 375-525 NTU.
9. The method according to claim 1 , wherein the strength agent system is added in such amount that the microfibrillated parenchymal cellulose material is added in amount of 1-100 kg, given as dry per ton of dry solids of the fibre stock.
10. The method according to claim 9 , wherein the strength agent system is added in such amount that the microfibrillated parenchymal cellulose material is added in amount of 5-70 kg.
11. The method according to claim 1 , wherein the strength agent system comprises 50-99.9 weight-%, of microfibrillated parenchymal cellulose material, calculated from the dry solids content.
12. The method according to claim 11 , wherein the strength agent system comprises 70-99.9 weight-% of microfibrillated parenchymal cellulose material, calculated from the dry solids content.
13. The method according to claim 1 , wherein that the strength agent system comprises a natural polymer, which is selected from a group consisting of cationic or amphoteric starch, chitin, guargum, carboxymethyl cellulose, and any mixture thereof.
14. The method according to claim 1 , wherein the strength agent is a synthetic polymer selected from cationic polyacrylamide (C-PAM), glyoxalated poly-acrylamide (G-PAM), amphoteric polyacrylamide, polydiallyldimethylammonium chloride (poly-DADMAC), polyacrylic amide (PARE), polyvinyl amine (PVAm), polyethylene oxide (PEO), polyethyleneimine (PEI) or a mixture of two or more of these polymers.
15. The method according to claim 14 , wherein the average molecular weight of the synthetic polymer is in a range 100,000-20,000,000 g/mol.
16. The method according to claim 14 , wherein the synthetic polymer is a cationic synthetic polymer which has a charge density of 0.5-2 meq/g.
17. The method according to claim 14 , wherein the synthetic polymer is a cationic synthetic polymer which is a copolymer of methacrylamide or acrylamide and at least one cationic monomer.
18. The method according to claim 1 , wherein the cationic retention polymer is cationic polyacrylamide having an average molecular weight of 4,000,000 12,000,000 Da and/or having a charge density of 0.2-2.5 meq/g.
19. The method according to claim 1 , wherein the stock comprising cellulose fibres is obtained by using furnish from kraft pulping, chemithermomechanical pulping or by repulping recycled fibres.
20. A paper or board product, having a density in a range of 150-800 kg/m 3 , produced by a method according to claim 1 .