Use of polymer particles containing insecticide in order to improve the soil mobility of insecticides, insecticide formulas, polymer particles containing insecticide, and method for pest control
Polymer particles, comprising a) at least one sparingly soluble insecticide from the group consisting of fipronil, allethrin, alpha-cypermethrin, beta-cyfluthrin, bifenthrin, bioallethrin, 4-chloro-2-(2-chloro-2-methylpropyl)-5-[(6-iodo-3-pyridinyl)methoxy]-3(2H)-pyridazinone (CAS-RN: 120955-77-3), chlorantraniliprole, chlorfenapyr, cyantraniliprole, cyfluthrin, cyhalothrin, cypermethrin, deltamethrin, etofenprox, fenoxycarb, flufenoxuron, hydramethylnon, imidacloprid, indoxacarb, metaflumizone, permethrin, pyriproxifen, tebufenozide and tralomethrin and b) at least one water-insoluble polymer, are suitable for improving the soil mobility of the sparingly soluble insecticide(s).
1. A polymer particle, consisting essentially of:
i) an insecticide fipronil; and
ii) at least one water-insoluble polymer P1, wherein the at least one water-insoluble polymer P1 is a water-insoluble polymer, obtained by polymerization of
M1.1) 30 to 80% by weight, based on P1, of at least one monomer (M I) selected from the group consisting of the C 1 -C 24 -alkyl esters of acrylic acid, C 1 -C 24 -alkyl esters of methacrylic acid and methacrylonitrile,
M1.2) 20 to 60% by weight, based on P1, of at least one monomer (M II), selected from the group consisting of butanediol diacrylate, trimethylolpropane triacrylate, trimethylolpropane trimethacrylate, pentaerythritol triallyl ether, pentaerythritol triacrylate and pentaerythritol tetraacrylate, and
M1.3) 5 to 40% by weight, based on P1, of at least one further monomer (M III) which is structurally different from monomers (M I) and (M II), wherein M III is either acrylic acid or methacrylic acid.
2. The polymer particle according to claim 1 , wherein the polymerization is carried out by mini-emulsion polymerization.
3. An insecticide formulation consisting essentially of comprising the polymer particle according to claim 1 .
4. The insecticide formulation according to claim 3 , wherein the polymerization is carried out by mini-emulsion polymerization.
5. A method for controlling soil-dwelling invertebrate pests, comprising applying onto or into a soil an insecticide formulation consisting essentially of comprising the polymer particle according to claim 1 .
6. The method according to claim 5 , wherein the polymerization is carried out by mini-emulsion polymerization.
7. A method for improving the soil mobility of sparingly soluble insecticides comprising applying onto or into the soil an insecticide formulation consisting essentially of comprising the polymer particle according to claim 1 .
8. The method according to claim 7 , wherein the polymerization is carried out by mini-emulsion polymerization.