Modified polyolefin resin
The present invention provides a modified polyolefin resin that can form a coating that exhibits excellent adhesion to a low-polarity base material, especially a poorly adherable polyolefin base material with no surface treatment even when being dried at low temperatures and has flexibility (bendability). Provided is a modified polyolefin resin that is a modified product of a polyolefin resin having a melting point (Tm) by a differential scanning calorimeter (DSC) of 60 to 165° C. with a modifier comprising the following (A): (A) a monomer mixture comprising Monomer Group (A-1) and Monomer Group (A-2) with a weight ratio of Monomer Group (A-1) to Monomer Group (A-2) ((A-1)/(A-2)) of 30/70 to 50/50.
1. A modified polyolefin resin, obtained by a process comprising:
modifying a polyolefin resin having a melting point (Tm) measured by a differential scanning calorimeter (DSC) of 60 to 165° C. with a modifier,
wherein the modifier comprises:
(A) a monomer mixture comprising Monomer Group (A-1) and Monomer Group (A-2) with a weight ratio of Monomer Group (A-1) to Monomer Group (A-2) ((A-1)/(A-2)) of 30/70 to 50/50, and (B) chlorine:
Monomer Group (A-1): two or more monomers comprising an ethylenically unsaturated bond and a functional group wherein when a homopolymer is made from each monomer of said two or more monomers said homopolymer has a glass transition temperature (Tg) of 60° C. or more, and
Monomer Group (A-2): two or more monomers comprising an ethylenically unsaturated bond and a functional group wherein when a homopolymer is made from each monomer of said two or more monomers said homopolymer has a glass transition temperature (Tg) of 30° C. or less.
2. The modified polyolefin resin according to claim 1 , wherein the functional group of the Monomer Group (A-1), the functional group of the Monomer Group (A-2), or both, is one or more selected from the group consisting of a carboxy group, a group represented by —(C═O)—O—, a hydroxy group, an ether group, and an optionally substituted amino group.
3. The modified polyolefin resin according to claim 1 , wherein at least one of the one or more monomers included in Monomer Group (A-1) comprises a carboxyl group as the functional group.
4. The modified polyolefin resin according to claim 1 , wherein Monomer Group (A-1) includes one or more selected from the group consisting of a (meth)acrylic acid and an alkyl (meth)acrylate.
5. The modified polyolefin resin according to claim 1 , wherein at least one of the one or more monomers included in Monomer Group (A-2) comprises one or more selected from the group consisting of a hydroxy group and an ether group as the functional group.
6. The modified polyolefin resin according to claim 1 , wherein Monomer Group (A-2) includes one or more selected from the group consisting of an alkyl (meth)acrylate, a hydroxyalkyl (meth)acrylate, and an alkoxy alkyl (meth)acrylate.
7. The modified polyolefin resin according to claim 1 , wherein the modifier further comprises:
(C) one or more selected from the group consisting of an α,β-unsaturated carboxylic acid and a derivative thereof.
8. A resin composition, comprising the modified polyolefin resin according to claim 1 .
9. An organic solvent-containing resin composition, comprising:
the modified polyolefin resin according to claim 1 ; and
an organic solvent.
10. An aqueous resin composition, comprising:
the modified polyolefin resin according to claim 1 ; and
water.
11. A method for manufacturing a modified polyolefin resin, the method comprising:
modifying a polyolefin resin having a melting point (Tm) measured by a differential scanning calorimeter (DSC) of 60 to 165° C. with a modifier comprising:
(A) a monomer mixture comprising Monomer Group (A-1) and Monomer Group (A-2) with a weight ratio of Monomer Group (A-1) to Monomer Group (A-2) ((A-1)/(A-2)) of 30/70 to 50/50, and (B) chlorine:
Monomer Group (A-1): two or more monomers comprising an ethylenically unsaturated bond and a functional group wherein when a homopolymer is made from each monomer of said two or more monomers said homopolymer has a glass transition temperature (Tg) of 60° C. or more, and
Monomer Group (A-2): two or more monomers comprising an ethylenically unsaturated bond and a functional group wherein when a homopolymer is made from each monomer of said two or more monomers said homopolymer has a glass transition temperature (Tg) of 30° C. or less.
12. The method according to claim 11 , wherein the modifier further comprises: (C) one or more selected from the group consisting of an α,β-unsaturated carboxylic acid and a derivative thereof.
13. The method according to claim 12 , comprising modifying the polyolefin resin with the one or more selected from group consisting of (B) and (C) and then with (A).