Nitrogen conservation in polymerization processes

1. A system for recovering nitrogen during regeneration of a treater, the system comprising:

the treater configured for regeneration via a nitrogen purge step, a heating step, a hold step, a cool down step, or a combination thereof, and wherein a treater bed regeneration effluent is a product of the nitrogen purge step, the cool down step, or a combination thereof;

an adsorbent bed downstream of the treater, wherein the adsorbent bed comprises an adsorbent operable to adsorb at least one impurity from the treater bed regeneration effluent stream comprising nitrogen to provide a nitrogen product having a higher nitrogen purity than a nitrogen purity of the treater bed regeneration effluent stream,

wherein the adsorbent bed comprises a pressure swing adsorption unit configured for regeneration of the adsorbent bed by (i) depressurization of the adsorbent bed to a pressure below an adsorption pressure; (ii) introduction of gas comprising nitrogen into the depressurized adsorbent bed; and (iii) repressurization of the adsorbent bed to the adsorption pressure.

2. The system of claim 1 , wherein the adsorbent comprises silica gel.

3. The system of claim 1 , wherein the treater comprises a treater configured to remove at least one component from a feed stream to a polyethylene (PE) polymerization reactor; or wherein the treater contains a desiccant selected from zeolites, molecular sieves, alumina, or combinations thereof; or both.

4. The system of claim 3 , wherein the feed stream comprises primarily isobutane, ethylene, 1-hexene, 1-butene, 1-octene, or a combination thereof; or wherein the nitrogen purity of the nitrogen product is greater than or equal to about 99.8 mole percent; or both.

5. The system of claim 3 , wherein the at least one component is selected from water, carbon dioxide, carbon monoxide, alcohols, acetylene, carbonyls, sulfur compounds, peroxides, ammonia, amines, phosphines, oxygen, or combinations thereof; or wherein the at least one impurity comprises a hydrocarbon, water, carbon dioxide, carbon monoxide, alcohols, acetylene, carbonyls, sulfur compounds, peroxides, ammonia, amines, phosphines, oxygen, or combinations thereof; or both.

6. The system of claim 1 , wherein regeneration of the adsorbent bed is performed during the heating step, the holding step, or both.

7. A method for recovering nitrogen during regeneration of a treater bed, the method comprising:

regenerating the treater bed by purging the treater bed, heating the treater bed to a regeneration temperature, holding the treater bed at the regeneration temperature, cooling down the treater bed, or a combination thereof;

introducing a treater bed regeneration effluent stream comprising nitrogen and at least one impurity into an adsorbent bed, wherein the adsorbent bed comprises an adsorbent operable to adsorb the at least one impurity from the treater bed regeneration effluent stream to provide a nitrogen product having a higher nitrogen purity than a nitrogen purity of the treater bed regeneration effluent stream, wherein the treater bed regeneration effluent stream introduced into the adsorbent bed is produced during the purging of the treater bed, the cooling down of the treater bed, or a combination thereof; and

regenerating the adsorbent bed during the heating of the treater bed to the regeneration temperature, the holding of the treater bed at the regeneration temperature, or both, by depressurizing the adsorbent bed to a pressure below an adsorption pressure; introducing a gas comprising nitrogen into the depressurized adsorbent bed; and repressurizing the adsorbent bed to the adsorption pressure.

8. The method of claim 7 , wherein the adsorbent comprises silica gel, or wherein the adsorbent bed comprises a pressure swing adsorption unit, or both.

9. The method of claim 7 , wherein the gas comprising nitrogen comprises a treater bed regeneration effluent produced during the cooling down of the treater bed, substantially pure nitrogen, or a combination thereof; or wherein regeneration of the adsorbent bed produces a tail gas enriched in hydrocarbons relative to the treater bed regeneration effluent stream introduced into the adsorbent bed; or both.

10. The method of claim 7 , wherein the treater bed is being regenerated after operating to remove at least one component from a feed stream to a polyethylene (PE) polymerization reactor; or wherein the feed stream comprises primarily isobutane, ethylene, 1-hexene, 1-butene, 1-octene, or a combination thereof; or both.

11. The method of claim 10 , wherein the at least one component is selected from water, carbon dioxide, carbon monoxide, alcohols, acetylene, carbonyls, sulfur compounds, peroxides, ammonia, amines, phosphines, oxygen, or combinations thereof, or wherein the at least one impurity comprises a hydrocarbon, water, carbon dioxide, carbon monoxide, alcohols, acetylene, carbonyls, sulfur compounds, peroxides, ammonia, amines, phosphines, oxygen, or combinations thereof; or both.

12. A method for recovering nitrogen during regeneration of a treater bed, the method comprising:

contacting a feed stream to a polyethylene polymerization reactor with a treater bed to remove at least one component from the feed stream;

regenerating the treater bed to yield a treater bed regeneration effluent stream comprising nitrogen and at least one impurity;

contacting the treater bed regeneration effluent with an adsorbent bed to remove at least a portion of impurity from the treater bed regeneration effluent stream and provide a nitrogen product having a higher nitrogen purity than a nitrogen purity of the treater bed regeneration effluent stream; and

regenerating the adsorbent bed by depressurizing the adsorbent bed to a pressure below an adsorption pressure; introducing a gas comprising nitrogen into the depressurized adsorbent bed; and repressurizing the adsorbent bed to the adsorption pressure.

13. The method of claim 12 , wherein regenerating the adsorbent bed is performed during the heating of the treater bed to the regeneration temperature, the holding of the treater bed at the regeneration temperature, or both.

14. The method of claim 12 , wherein regenerating the treater bed further comprises purging the treater bed, heating the treater bed to a regeneration temperature, holding the treater bed at the regeneration temperature, cooling down the treater bed, or a combination thereof.

15. The method of claim 14 , wherein regenerating the adsorbent bed produces a tail gas enriched in hydrocarbons relative to the treater bed regeneration effluent stream introduced into the adsorbent bed.

16. The method of claim 15 , wherein further comprising flaring at least a portion of the tail gas enriched in hydrocarbons, or recycling at least a portion of the nitrogen product to regeneration of the treater bed, or both.

17. The method of claim 16 , wherein the adsorbent comprises silica gel, or wherein the adsorbent bed comprises a pressure swing adsorption unit, or both.

18. The method of claim 17 , wherein the treater bed contains a desiccant selected from zeolites, molecular sieves, alumina, or combinations thereof.

19. The method of claim 18 , wherein the feed stream comprises primarily isobutane, ethylene, 1-hexene, 1-butene, 1-octene, or a combination thereof, or wherein the nitrogen purity of the nitrogen product is greater than or equal to about 99.8 mole percent; or both.

20. The method of claim 19 , wherein the at least one component is selected from water, carbon dioxide, carbon monoxide, alcohols, acetylene, carbonyls, sulfur compounds, peroxides, ammonia, amines, phosphines, oxygen, or combinations thereof, or wherein the at least one impurity comprises a hydrocarbon, water, carbon dioxide, carbon monoxide, alcohols, acetylene, carbonyls, sulfur compounds, peroxides, ammonia, amines, phosphines, oxygen, or combinations thereof; or both.