Hard coating composition and flexible display device including the hard coating composition
A coating composition includes a siloxane oligomer including an epoxy group and acryl group, a cross-linker, a polymerization initiator and a solvent.
1. A display device comprising:
a display panel; and
a window member positioned on at least one surface of the display panel, wherein the window member includes a coating layer, the coating layer including a cross-linked structure of a silsesquioxane compound that includes an epoxy group and an acryl group and having an indentation hardness of about 50 MPa or more and a tensile modulus of about 4.0 GPa or less,
wherein the coating layer includes a cross-linked structure formed from a curing reaction of a silsesquioxane compound including repeating units represented by Chemical Formulas 1, wherein an oxygen atom connected to * is connected to an adjacent Si atom in the siloxane oligomer, R1 represents an epoxy group or an alkyl group including an epoxy group, R2 represents a (meth)acryl group or an alkyl group including a (meth)acryl group, n and m independently represent a natural number, and a summation of n and m is from 6 to 100
2. The display device of claim 1 , wherein the window member further includes a base film disposed between the coating layer and the display panel.
3. The display device of claim 1 , wherein a mole ratio of a first repeating unit, which is connected to R1, to a second repeating group, which is connected to R2, is 80:20 to 60:40.
4. A display device comprising:
a display panel; and
a window member positioned on at least one surface of the display panel, wherein the window member includes a coating layer, the coating layer including a cross-linked structure of a silsesquioxane compound that includes an epoxy group and an acryl group and having an indentation hardness of about 50 MPa or more and a tensile modulus of about 4.0 GPa or less, wherein the coating layer includes a cross-linked structure formed from a curing reaction of a silsesquioxane compound including repeating units represented by Chemical Formula 5, wherein an oxygen atom connected to * is connected to an adjacent Si atom in the siloxane oligomer, R1 represents an epoxy group or an alkyl group including an epoxy group, R2 represents a (meth)acryl group or an alkyl group including a (meth)acryl group, R3 represents a fluoroalkyl group, in which at least one hydrogen atom is substituted with a fluorine atom, or a perfluoro polyether group, n, m and r independently represent a natural number, and a summation of n, m and r is from 6 to 100
5. The display device of claim 4 , wherein a content of a repeating unit including fluorine combined with R3 in the siloxane oligomer is from about 5% to about 10% by weight based on a total weight of the siloxane oligomer.
6. A display device comprising:
a display panel; and
a window member positioned on at least one surface of the display panel, wherein the window member includes a coating layer, the coating layer including a cross-linked structure of a silsesquioxane compound that includes an epoxy group and an acryl group and having an indentation hardness of about 50 MPa or more and a tensile modulus of about 4.0 GPa or less, wherein the coating layer includes a first coating layer and a second coating layer disposed on the first coating layer,
wherein the first coating layer includes a cross-linked structure formed from a curing reaction of a silsesquioxane compound including a repeating unit represented by Chemical Formula 8,
wherein the second coating layer includes a cross-linked structure formed from a curing reaction of a silsesquioxane compound including a repeating unit represented by Chemical Formula 9,
wherein an oxygen atom connected to * is connected to an adjacent Si atom in the siloxane oligomer, R1 represents an epoxy group or an alkyl group including an epoxy group, R2 represents a (meth)acryl group or an alkyl group including a (meth)acryl group, and n and m independently represent a natural number
7. The display device of claim 6 , wherein a thickness ratio of the first coating layer and the second coaling layer is from 7:3 to 3:7.
8. A display device comprising:
a display panel; and
a window member positioned on at least one surface of the display panel, wherein the window member includes a coating layer, the coating layer including a cross-linked structure of a silsesquioxane compound that includes an epoxy group and an acryl group and having an indentation hardness of about 50 MPa or more and a tensile modulus of about 4.0 GPa or less, wherein the window member further includes a base film, wherein the coating layer includes an upper coating layer disposed on a first surface of the base film, and a lower coating layer disposed on a second surface of the base film, wherein the upper coating layer includes a first upper coating layer combined with the base film and a second upper coating layer combined with the first upper coating layer, wherein the lower coating layer includes a first lower coating layer combined with the base film and a second lower coating layer combined with the first lower coating layer, and
wherein the first upper coating layer and the first lower coating layer include a cross-linked structure formed from a curing reaction of a silsesquioxane compound including a repeating unit represented by Chemical Formula 8,
wherein the second upper coating layer and the second lower coating layer include a cross-linked structure formed from a curing reaction of a silsesquioxane compound including a repeating unit represented by Chemical Formula 9, p 1 wherein an oxygen atom connected to * is connected to another Si atom in the siloxane oligomer, R1 represents an epoxy group or an alkyl group including an epoxy group, R2 represents a (meth)acryl group or an alkyl group containing a (meth)acryl group, and n and m independently represent a natural number
9. The display device of claim 1 , wherein the display device is foldable.
10. The display device of claim 1 , wherein the silsesquioxane compound has a tensile modulus of about 2.7-4.0 GPa.
11. The display device of claim 1 , wherein the silsesquioxane compound comprises at least about 40% by weight of the coating layer.
12. A display device comprising;
a display panel; and
a window member positioned on at least one surface of the display panel, wherein the window member includes a coating layer, the coating layer including a cross-linked structure of a silsesquioxane compound including repeating units having substituents, wherein each of the substituents independently includes an epoxy group or an acryl group.
13. The display device of claim 12 , wherein the coating layer includes a cross-linked structure formed from a curing reaction of a silsesquioxane compound including repeating units represented by Chemical Formula 1, wherein an oxygen atom connected to * is connected to an adjacent Si atom in the siloxane oligomer, R1 represents an epoxy group or an alkyl group including an epoxy group, R2 represents a (meth)acryl group or an alkyl group including a (meth)acryl group, n and m independently represent a natural number, and a summation of n and m is from 6 to 100
14. The display device of claim 12 , wherein the coating layer includes a cross-linked structure formed from a curing reaction of a silsesquioxane compound including repeating units represented by Chemical Formula 5, wherein an oxygen atom connected to * is connected to an adjacent Si atom in the siloxane oligomer, R1 represents an epoxy group or an alkyl group including an epoxy group, R2 represents a (meth)acryl group or an alkyl group including a (meth)acryl group, R3 represents a fluoroalkyl group, in which at least one hydrogen atom is substituted with a fluorine atom, or a perfluoro polyether group, n, m and r independently represent a natural number, and a summation of n, m and r is from 6 to 100
15. The display device of claim 12 , wherein the coating layer includes a first coating layer and a second coating layer disposed on the first coating layer,
wherein the first coating layer includes a cross-linked structure formed from a curing reaction of a silsesquioxane compound including a repeating unit represented by Chemical Formula 8,
wherein the second coating layer includes a cross-linked structure formed from a curing reaction of a silsesquioxane compound including a repeating unit represented by Chemical Formula 9,
wherein an oxygen atom connected to * is connected to an adjacent Si atom in the siloxane oligomer, R1 represents an epoxy group or an alkyl group including an epoxy group, R2 represents a (meth)acryl group or an alkyl group including a (meth)acryl group, and n and m independently represent a natural number
16. The display device of claim 12 , wherein the window member further includes a base film, wherein the coating layer includes an upper coating layer disposed on a first surface of the base film, and a lower coating layer disposed on a second surface of the base film, wherein the upper coating layer includes a first upper coating layer combined with the base film and a second upper coating layer combined with the first upper coating layer, wherein the lower coating layer includes a first lower coating layer combined with the base film and a second lower coating layer combined with the first lower coating layer, and
wherein the first upper coating layer and the first lower coating layer include a cross-linked structure formed from a curing reaction of a silsesquioxane compound including a repeating unit represented by Chemical Formula 8,
wherein the second upper coating layer and the second lower coating layer include a cross-linked structure formed from a curing reaction of a silsesquioxane compound including a repeating unit represented by Chemical Formula 9,
wherein an oxygen atom connected to * is connected to another Si atom in the siloxane oligomer, R1 represents an epoxy group or an alkyl group including an epoxy group, R2 represents a (meth)acryl group or an alkyl group containing a (meth)acryl group, and n and m independently represent a natural number