Solvent for use in aromatic extraction process
Oxidized disulfide oil (ODSO) compounds, derived from by-product disulfide oil (DSO) compounds produced as by-products from the generalized mercaptan oxidation (MEROX) in the practice of the process, are effective as aromatic extraction solvents. This use of ODSO compounds as an extraction solvent converts an otherwise DSO waste oil product into a valuable commodity that has utility in improving the extraction of aromatics from hydrocarbons derived from fossil fuels.
1. A process for the separation of aromatic hydrocarbon compounds from a mixture of hydrocarbons, the process comprising:
a. contacting the mixture containing both aromatic and non-aromatic hydrocarbon compounds with an ODSO aromatic extraction solvent one or more of the following compounds:
1,2 alkyl-alkyl-disulfane 1,1,2 trioxide (R-SOO-SO-R),
1 ,2 alkyl-alkyl-disulfane 1,1,2,2 tetraoxide (R-SOO-SOO-R),
alkyl-sulfoxidesulfonate (R-SO-SOO-OH),
alkyl-sulfonesulfonate (R-SOO-SOO-OH),
alkyl-sulfoxidesulfinate (R-SO-SO-OH), and
alkyl-sulfonesulfiante (R-SOO-SO-OH) to form an extract containing the solvent and dissolved aromatics, and a raffinate comprising non-aromatic hydrocarbon compounds;
b. separating the extract from the raffinate; and
c. recovering a hydrocarbon stream of reduced aromatic content and an extract stream.
2. A process for the separation of one or more targeted aromatic hydrocarbon compounds from a hydrocarbon mixture containing targeted and non-targeted aromatic compounds, and non-aromatic hydrocarbons, the process comprising:
a. contacting the mixture containing both aromatic and non-aromatic hydrocarbon compounds with an ODSO aromatic extraction solvent comprising a mixture of one or more. of the following ODSO compounds:
1,2 alkyl-alkyl-disulfane 1,1,2 trioxide (R-SOO-SO-R),
1,2 alkyl-alkyl-disulfane 1,1,2,2 tetraoxide (R-SOO-SOO-R),
alkyl-sulfoxidesulfonate (R-SO-SOO-OH),
alkyl-sulfonesulfonate (R-SOO-SOO-OH),
alkyl-sulfoxidesulfinate (R-SO-SO-OH), and
alkyl-sulfonesulfiante (R-SOO-SO-OH) to firm an extract comprising the solvent: and dissolved targeted aromatic compounds, and a raffinate comprising non-aromatic hydrocarbon compounds and non-targeted aromatics;
b. separating the extract from the, raffinate; and
c. recovering a hydrocarbon stream of reduced targeted aromatic content and the extract stream.
3. The process of claim 1 , wherein the oxidized disulfide oil compounds are derived from a MEROX process.
4. The process of claim 1 , wherein the one or more oxidized disulfide oil compounds comprising the solvent are selected to remove mono- and multi-aromatic compounds from the hydrocarbon stream.
5. The process of claim 1 , wherein the hydrocarbon stream of reduced aromatic content is contacted with a non-oxidized disulfide oil aromatic extraction solvent to further reduce the aromatic content.
6. The process of claim 2 , wherein the one or more ODSO compounds comprising the solvent are selected to remove the one or more targeted aromatic compounds from the hydrocarbon stream.
7. The process of claim 6 , wherein benzene is a targeted aromatic compound.
8. The process of claim 2 , wherein the hydrocarbon stream of reduced targeted aromatic content is contacted with a second ODSO aromatic extraction solvent to reduce the non-targeted aromatic content of the hydrocarbon stream and produce a hydrocarbon stream of reduced aromatic content.