IP Library Granted Patent US 10,796,849
Granted Patent B2
US 10,796,849 · App. 15/569,912 · Granted Oct 6, 2020

Magnetically tunable photonic crystals based on anisotropic nanostructures

Inventors: Yadong Yin (Riverside, CA); Mingsheng Wang (Riverside, CA)
Assignee: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
H01F41/02C01G49/02H01F1/0036B22F1/0025B22F2001/0033B22F2998/10B22F2999/00B82Y20/00B82Y25/00B82Y40/00C01P2004/04C01P2004/16C01P2004/84Y10S977/762Y10S977/81Y10S977/892Y10S977/896Y10S977/952
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Quick Facts
Patent No.
US 10,796,849
App. No.
15/569,912
Granted
Oct 6, 2020
Kind
B2
Abstract

A method is disclosed of forming magnetically tunable photonic crystals comprising: synthesizing one or more precursory nanoparticles with anisotropic shapes; coating the one or more anisotropic precursory nanoparticles with silica to form composite structures; converting the one or more anisotropic precursory nanoparticles into magnetic nanomaterials through chemical reactions; and assembling the anisotropic magnetic nanoparticles into photonic crystals in a solvent.

Claims (28)

1. A method of forming magnetically tunable photonic crystals comprising:

synthesizing precursory nanoparticles with anisotropic shapes, the anisotropic precursory nanoparticles being iron oxyhydroxide (FeOOH) nanorods;

coating the anisotropic precursory nanoparticles with silica to form composite structures;

converting the anisotropic precursory nanoparticles into magnetic nanomaterials through chemical reactions, the chemical reactions including reducing the coated composite structure with reducing agents to render the coated composite structures magnetic; and

assembling the anisotropic magnetic nanoparticles into photonic crystals in a solvent.

2. The method of claim 1 , comprising:

adding tetraethyl orthosilicate into a mixture of distilled water, ethanol, ammonia and anisotropic precursory nanoparticles; and

isolating the coated composite structures by centrifugation.

3. The method of claim 1 , wherein the reducing of the coated composite structure with reducing agents to render the coated composite structures magnetic comprises:

heating the coated composite structures; and

reducing the coated composite structures with the reducing agents to render the coated composite structures magnetic.

4. The method of claim 1 , further comprising:

redispersing the as-reduced magnetic nanoparticles by sonication;

applying a size selection to the magnetic nanoparticles; and

discarding non-dispersible aggregates by centrifugation.

5. The method of claim 1 , comprising:

a solvent for assembling nanoparticles into photonic structures, the solvent being water, ethanol, glycol, and other polar or nonpolar solvents.

6. The method of claim 1 , wherein the synthesizing of the iron oxyhydroxide nanorods comprises:

solution-based synthesis of anisotropic precursory nanoparticles.

7. The method of claim 6 , further comprising:

dissolving iron trichloride in deionized water;

adjusting a concentration of iron cations in the iron trichloride dissolved in the deionized water;

discarding undissolved precipitates after centrifugation from the iron trichloride dissolved in the deionized water to form a supernatant; and

heating the supernatant to form the iron oxyhydroxide nanorods.

8. The method of claim 7 , comprising:

isolating the iron oxyhydroxide nanorods by centrifugation.

9. The method of claim 7 , comprising:

functionalizing a surface of the iron oxyhydroxide nanorods with polyacrylic acid.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 26, 2017
From: YIN, YADONG; WANG, MINGSHENG
To: THE REGENTS OF THE UNIVERSITY OF CALIFORNIA
Reel/Frame 044486/0371 →
Continuity (2)
Provisional Application 62153228 · Apr 27, 2015
Related Publication 20180114637A1 · Apr 26, 2018