Dielectric ceramic composition and multilayer ceramic capacitor
The object of the present invention is to provide a dielectric ceramic composition having good properties, particularly good IR property and high temperature accelerated lifetime. The dielectric ceramic composition of the present invention has a main component made of a perovskite type compound expressed by a compositional formula of (Ba 1-x-y Sr x Ca y ) m (Ti 1-z Zr z )O 3 (note that, m, x, y, and z of the above compositional formula all represent molar ratios, and each satisfies 0.9≤m≤1.1, 0≤x≤0.5, 0≤y≤0.3, 0≤(x+y)≤0.6, and 0.03≤z≤0.3), and a first sub component made of an oxide of a rare earth element R (note that, R is at least one selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu), wherein the dielectric ceramic composition includes a dielectric particle and a particle boundary, and the dielectric particle include a complete solid solution particle in which Zr is solid dissolved to the entire dielectric particle, when Za represents a concentration of Zr in the dielectric ceramic composition in case a concentration of Ti atom in the dielectric ceramic composition is deemed to be 100 atom % and when Zb represents an average concentration of Zr in the complete solid solution particle in case a concentration of Ti atom in the complete solid solution particle is deemed to be 100 atom %, 0.7<(Zb/Za) is satisfied, and a standard deviation and an average value of the Zb measured satisfies (the standard deviation/the average value)≤0.15.
1. A dielectric ceramic composition comprising
a main component made of a perovskite type compound expressed by a compositional formula of (Ba 1-x-y Sr x Ca y ) m (Ti 1-z Zr z )O 3 , where m, x, y, and z all represent molar ratios, and the following is satisfied:
0.9≤ m≤ 1.1,
0≤ x≤ 0.5,
0≤ y≤ 0.3,
0≤( x+y )≤0.6, and
0.03≤ z≤ 0.3, and
a first sub component made of an oxide of a rare earth element R, where R is at least one selected from the group consisting of Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, and Lu, wherein:
the dielectric ceramic composition includes a dielectric particle and a particle boundary, and the dielectric particle includes a complete solid solution particle in which Zr is solid dissolved into an entirety of the dielectric particle,
when Za represents a concentration of Zr in the dielectric ceramic composition based on a concentration of Ti atom in the dielectric ceramic composition of 100 atom %, and when Zb represents an average concentration of Zr in the complete solid solution particle based on a concentration of Ti atom in the complete solid solution particle of 100 atom %,
0.7<(Zb/Za) is satisfied, and
a standard deviation and an average value of the Zb measured satisfies
(the standard deviation/the average value)≤0.15.
2. The dielectric ceramic composition according to claim 1 , wherein (the standard deviation/the average value)<0.10 is satisfied.
3. The dielectric ceramic composition according to claim 1 , wherein 0.8<(Zb/Za) is satisfied.
4. The dielectric ceramic composition according to claim 2 , wherein 0.8<(Zb/Za) is satisfied.
5. An electronic component including the dielectric ceramic composition according to claim 1 .
6. An electronic component including the dielectric ceramic composition according to claim 2 .
7. An electronic component including the dielectric ceramic composition according to claim 3 .
8. An electronic component including the dielectric ceramic composition according to claim 4 .
9. A multilayer ceramic capacitor comprising a dielectric layer including the dielectric ceramic composition according to claim 1 and an internal electrode layer.
10. A multilayer ceramic capacitor comprising a dielectric layer including the dielectric ceramic composition according to claim 2 and an internal electrode layer.
11. A multilayer ceramic capacitor comprising a dielectric layer including the dielectric ceramic composition according to claim 3 and an internal electrode layer.
12. A multilayer ceramic capacitor comprising a dielectric layer including the dielectric ceramic composition according to claim 4 and an internal electrode layer.