Silver powder, method for producing same, and hydrophilic conductive paste
A silver powder, wherein the silver powder satisfies D 50 -IPA>D 50 -W, where in measurement of a volume-based particle size distribution of the silver powder by a laser diffraction particle size distribution analysis, D 50 -IPA (μm) is a cumulative 50% point of particle diameter of the silver powder when isopropyl alcohol (IPA) is used as a measurement solvent for dispersing the silver powder, and D 50 -W (μm) is a cumulative 50% point of particle diameter of the silver powder when water is used as a measurement solvent for dispersing the silver powder, and wherein a phosphorus content in the silver powder is 0.01% by mass or more but 0.3% by mass or less.
1. A method for producing a silver powder, the method comprising:
adding a reducing agent to an aqueous reaction system containing silver ions to reduce and deposit silver particles, and
adding a phosphorus-containing compound at least one timing selected from the group consisting of: before reduction and deposition of the silver particles; during reduction and deposition of the silver particles; and after reduction and deposition of the silver particles, a phosphorus content in the phosphorus-containing compound being 20% by mass or more but 30% by mass or less.
2. The method for producing a silver powder according to claim 1 , wherein the phosphorus-containing compound is a phosphate ester of inositol.
3. The method for producing a silver powder according to claim 2 , wherein the phosphate ester of inositol is phytic acid.
4. The method for producing a silver powder according to claim 1 , wherein the reducing agent is at least one selected from the group consisting of ascorbic acid, alkanolamine, sodium borohydride, hydroquinone, hydrazine, and formalin.