IP Library › Granted Patent US 10,808,074
Granted Patent B2
US 10,808,074 · App. 16/005,798 · Granted Oct 20, 2020

Glycidyl ether alkoxylate block copolymers

Inventors: Edward D. Daugs (Midland, MI); John J. Rabasco (Allentown, PA); Antony K. Van Dyk (Blue Bell, PA); Tianlan Zhang (Garnet Valley, PA)
Assignees: Rohm and Haas Company; Dow Global Technologies LLC
C08G65/2612C08G65/22C09D5/00C09D5/024C09D7/63C09D7/65C09D171/02C08G2650/58
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Quick Facts
Patent No.
US 10,808,074
App. No.
16/005,798
Granted
Oct 20, 2020
Kind
B2
Abstract

The present invention relates to a compound having the following structure I: where Ar 1 , Ar 2 ; R 1 , m, and n are defined herein. The compound of the present invention is useful as an open time additive in waterborne coatings compositions, particularly waterborne paint compositions.

Claims (11)

1. A compound having the following structure I:

where Ar 1 is unsubstituted phenyl or naphthyl, or phenyl or naphthyl substituted with from 1 to 3 C 1 -C 6 alkyl groups; and Ar 2 is phenyl, phenyl-OCH 2 CH 2 —, naphthyl, naphthyl-CH 2 —, or naphthyl-OCH 2 CH 2 —, wherein the phenyl or naphthyl portion of Ar 2 are unsubstituted or substituted with from 1 to 3 C 1 -C 6 alkyl groups; each R 1 is independently H or C 1 -C 6 -alkyl; m is from 1 to 20; and n is from 2 to 100.

2. The compound of claim 1 wherein Ar 1 is phenyl or o-methylphenyl; Ar 2 is phenyl, phenyl-OCH 2 CH 2 —, or o-methylphenyl; and each R 1 is independently H or CH 3 .

3. The compound of claim 2 which has a number average molecular weight in the range of from 300 to 20,000 g/mol.

4. The compound of claim 3 which has a number average molecular weight in the range of from 500 to 10,000 g/mol is selected from the group consisting of:

5. A coating composition comprising the compound of claim 1 , a binder, a rheology modifier and at least one material selected from the group consisting of dispersants, pigments, defoamers, surfactants, solvents, extenders, coalescents, biocides, opaque polymers, and colorants.

6. A compound having the following structure:

where Ar 1 is phenyl or phenyl substituted with from 1 to 3 C 1 -C 6 alkyl groups; and with Ar 2 is phenyl-OCH 2 CH 2 — and where the phenyl portion of Ar 2 is unsubstituted or substituted with from 1 to 3 C 1 -C 6 alkyl groups, where m is from 1 to 20; and n is from 1 to 100.

7. The compound of claim 6 which is represented by the following formula Ib:

8. The compound of claim 6 which is represented by the following formula Ib:

wherein the compound has a number average molecular weight in the range of from 500 to 10,000 g/mol.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Sep 30, 2020
From: DAUGS, EDWARD D.; RABASCO, JOHN J.; VAN DYK, ANTONY K.; ZHANG, TIANLAN
To: DOW GLOBAL TECHNOLIGIES LLC; ROHM AND HAAS COMPANY
Reel/Frame 053934/0349 →
Continuity (2)
Provisional Application 62518861 · Jun 13, 2017
Related Publication 20180355107A1 · Dec 13, 2018
Cited By (2)
US 12,201,048 US 12,439,840