Process for production of base stocks
Base stocks having Group III/III+ characteristics are prepared from certain advantageous crude oils via simplified process configurations and/or under less severe process conditions. Crude oils comprising a vacuum gas oil (VGO) fraction having a ratio of a sum of paraffin content plus 1-Ring species content to multi-ring species content that is greater than or equal to about 1.5 are advantageous in this context. Other parameters such as API gravity and crude compositional ranges may also be considered for identifying advantageous crudes. In some instances, advantageous crudes are processed into Group III base stocks via a process configuration in which the crude oil is directly supplied to a hydroprocessing unit.
1. A method of producing a base stock, comprising:
hydroprocessing a crude oil, said crude oil having an API gravity in a range of 49 to 53, as measured according to ASTM D4052-16 comprising a vacuum gas oil (VGO) fraction having a ratio of (a sum of paraffin content in wt. %+1-ring species content in wt. %) to (multi-ring species content in wt. %) greater than or equal to 1.5 to produce a base stock having a viscosity index greater than 120, as determined according to ASTM D2270-10.
2. The method of claim 1 , wherein the crude oil has a paraffin content in a range of 25 to 76 wt. %, a naphthenes content in a range of 21 to 52 wt. %, and an aromatics content of 3 to 38 wt. %.
3. The method of claim 1 , wherein the crude oil has a paraffin content in a range of 34-53 wt. %, a naphthenes contend in a range of 33-51 wt. %, and an aromatics content of 8-20 wt. %.
4. The method of claim 1 , wherein the viscosity index of the base stock is greater than 130.
5. The method of claim 4 , wherein the base stock has a saturates percentage greater than 90 wt. %.
6. The method of claim 1 , wherein the hydroprocessing provides a 700F+conversion (wt. %) in the range of 5% to 90%.
7. The method of claim 1 , wherein the hydroprocessing provides a 700F+conversion (wt. %) in the range of 10% to 70%.
8. The method of claim 1 , wherein the hydroprocessing provides a 700F+conversion (wt. %) in the range of 15% to 60%.
9. The method of claim 1 , wherein hydroprocessing uses a ratio of hydrotreating catalyst to hydrocracking catalyst that is greater than 1 to 1.
10. The method of claim 1 , wherein hydroprocessing uses a ratio of hydrotreating catalyst to hydrocracking catalyst that is greater than 2 to 1.
11. The method of claim 1 , wherein hydro processing uses a ratio of hydrotreating catalyst to hydrocracking catalyst that is greater than 3 to 1.
12. A method of producing a base stock, comprising:
hydroprocessing a crude oil comprising a vacuum gas oil (VGO) fraction having a ratio of (a sum of paraffin content in wt. %+1-ring species content in wt. %) to (multi-ring species content in wt. %) greater than or equal to 1.5 to produce a hydroprocessed effluent;
fractionating the hydroprocessed effluent to produce an upper fractionate, a lower fractionate, and a middle fractionate;
dewaxing the middle fractionate to produce a dewaxed effluent;
hydrofinishing the dewaxed effluent to produce a hydrofinished effluent; and
fractionating the hydrofinished effluent to produce an overhead fractionate and a residual fractionate, wherein
the residual fractionate is a base stock having a viscosity index greater than 120 as determined according to ASTM D2270-10.
13. The method of claim 12 , wherein the crude oil has an API gravity of 45 to 55, as measured according to ASTM D4052-16.
14. The method claim 12 , wherein the crude oil has an API gravity of 49 to 53, as measured according to ASTM D4052-16.
15. The method of claim 12 , wherein the crude oil is a topped crude oil.
16. The method of claim 12 , wherein the viscosity index (VI) of the base stock is greater than 130, as determined according to ASTM D2270-10.
17. The method of claim 12 , wherein
the base stock has a sulfur weight percent of less than or equal to 0.05, and
a saturates level greater than or equal to 90 wt. percent.
18. The method of claim 12 , wherein the crude oil has a paraffin content in a range of 25 to 76 wt. %, a naphthenes content in a range of 21 to 52 wt. %, and an aromatics content of 3 to 38 wt. %.
19. The method of claim 12 , wherein the crude oil has a paraffin content in a range of 34-53 wt. %, a naphthenes contend in a range of 33-51 wt. %, and an aromatics content of 8-20 wt. %.
20. The method of claim 12 , wherein
the hydroprocessing is a hydrotreatment performed in a hydrotreating unit, and
the crude oil is fed directly to the hydrotreating unit.
21. The method of claim 12 , wherein
the hydroprocessing is a hydrocracking performed in a hydrocracking unit, and
the crude oil is fed directly to the hydrocracking unit.
22. The method of claim 12 , wherein the dewaxing is performed using a noble-metal containing zeolite catalyst.
23. The method of claim 12 , wherein the hydrofinishing is performed using a noble-metal containing catalyst.
24. The method of claim 12 , wherein
the crude oil has an API gravity that is within a range of 45 to 55, inclusive, as measured according to ASTM D4052-16,
the hydroprocessing is performed in a hydroprocessing unit, and
the crude oil is fed directly to the hydroprocessing unit.
25. The method of claim 24 , wherein the viscosity index (VI) of the base stock oil is greater than 130, as determined according to ASTM D2270-10.
26. A method of producing a base stock, comprising:
feeding a crude oil comprising a VGO fraction having a ratio of (a sum paraffin content in wt. %+1-ring species content in wt. %) to (multi-ring species content in wt. %) greater than or equal to 1.5 to a hydroprocessing unit to produce a hydroprocessed effluent;
fractionating the hydroprocessed effluent in a first fractionating unit to produce an upper fractionate and a lower fractionate;
feeding the lower fractionate to a dewaxing unit to produce a dewaxed effluent;
feeding the dewaxed effluent to a hydrofinishing unit to produce a hydrofinished effluent; and
fractionating the hydrofinished effluent in a second fractionating unit to produce an overhead fractionate and a residual fractionate, wherein
the residual fractionate is a base stock oil having a viscosity index (VI) greater than 120, as determined according to ASTM D2270-10.
27. The method of claim 26 , wherein the crude oil has an API gravity that is within a range of 45 to 55, inclusive, as measured according to ASTM D4052-16.
28. The method of claim 26 , wherein
the base stock has a sulfur weight percent of less than or equal to 0.05,
the base stock has a saturates level greater than or equal to 90 wt. percent, and
the viscosity index (VI) of the base stock is greater than 130, as determined according to ASTM D2270-10.
29. The method of claim 26 , wherein the hydroprocessing is a hydrotreatment process.
30. The method of claim 26 , wherein the hydroprocessing is a hydrocracking process.
31. A method of producing a base stock, comprising:
fractionating a crude oil comprising a vacuum gas oil (VGO) fraction having a ratio of (a sum of paraffin content in wt. %+1-ring species content in wt. %) to (multi-ring species content in wt. %) greater than or equal to 1.5 to produce a vacuum gas oil (VGO);
hydroprocessing the VGO to produce a hydroprocessed effluent;
fractionating the hydroprocessed effluent to produce an upper fractionate, a lower fractionate, and a middle fractionate;
dewaxing the middle fractionate to produce a dewaxed effluent;
hydrofinishing the dewaxed effluent to produce a hydrofinished effluent; and
fractionating the hydrofinished effluent to produce an overhead fractionate and a residual fractionate, wherein
the residual fractionate is a base stock having a viscosity index greater than 120 as determined according to ASTM D2270-10.