Embossing lacquer and method for embossing, and substrate surface coated with the embossing lacquer
In the case of an embossing lacquer based on a UV-polymerizable prepolymer composition containing at least one acrylate monomer, the prepolymer composition—in addition to the acrylate monomer—contains at least one thiol selected from the group: 3-Mercaptopropianates, mercaptoacetates, thioglycolates, and alkylthiols as well as potentially a surface-active anti-adhesive additive selected from the group of anionic surfactants, such as polyether siloxanes, fatty alcohol ethoxylates, such as polyoxyethylene (9) lauryl ethers, monofunctional alkyl (meth)acrylates, polysiloxane (meth)acrylates, perfluoroalkyl (meth)acrylates, and perfluoropolyether (meth)acrylates as well as a photoinitiator, as well as a method for imprinting substrate surfaces coated with an embossing lacquer.
1. An embossing lacquer based on a UV-polymerizable prepolymer composition containing at least one acrylate monomer, wherein the prepolymer composition contains a thiol, selected from the group consisting of 3-Mercaptopropionates, mercaptoacetates, thioglycolates, and alkyl thiols, as well as a surface-active anti-adhesive additive selected from the group consisting of mono-functional polydimethylsiloxane (meth) acrylates, perfluoro-n-alkyl (meth) acrylates and perfluoropolyether (meth) acrylates, as well as a photoinitiator,
wherein the surface-active anti-adhesive additive is contained in a quantity of 0.1 wt % to 3 wt % of the UV-polymerizable prepolymer composition, and
wherein the embossing lacquer is water soluble after polymerization.
2. The embossing lacquer according to claim 1 , wherein the acrylate monomer is selected from the group consisting of acryloylmorpholine (ACMO) and isobornyl acrylate (IBOA).
3. The embossing lacquer according to claim 1 , wherein the thiol is contained in the prepolymer composition in a quantity between 0.5 and 20 wt % of the UV-polymerizable prepolymer composition.
4. The embossing lacquer according to claim 1 , wherein the photoinitiator is selected from the group consisting of thioxanthones, ketosulfones, (alkyl) benzoyl phenyl phosphine oxides, 1-Hydroxy alkyl phenyl ketones and 2,2-Dimethoxy-1,2-diphenylethane-1-one.
5. The embossing lacquer according to claim 4 , wherein the photoinitiator is contained in a quantity of 0.1 to 10 wt %, of the UV-polymerizable prepolymer composition.
6. The embossing lacquer according to claim 1 , wherein the thiol is selected from the group consisting of a mono or dithiol of the group: octanethiol, 1,8-Octanedithiol, decanethiol, 1,10-Decanedithiol, dodecanethiol, 1,12-Dodecanedithiol, 2-Ethylhexyl mercaptoacetate, 2-Ethyl-hexyl-3-mercaptopropionate, 2-Ethylhexyl thioglycolate, glycol di-(3-mercaptopropionate), glycol di(mercaptoacetates), glyceryl dimercaptoacetate and glyceryl di-(3-mercaptopropionate).
7. The embossing lacquer according to claim 1 , wherein the prepolymer composition has a viscosity between 10 and 100 mPas.
8. The embossing lacquer according to claim 5 , wherein the photoinitiator is contained in a quantity of 0.5 to 5 wt % of the UV-polymerizable prepolymer composition.