IP Library › Granted Patent US 10,813,870
Granted Patent B2
US 10,813,870 · App. 16/146,215 · Granted Oct 27, 2020

Mineral sunscreen compositions with improved efficacy

Inventors: Anil Shah (East Windsor, NJ); Brian Scott Bodnar (Manasquan, NJ)
Assignee: L'OREAL
A61K8/602A61K8/06A61K8/37A61K8/40A61Q17/04A61K2800/30
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Quick Facts
Patent No.
US 10,813,870
App. No.
16/146,215
Granted
Oct 27, 2020
Kind
B2
Abstract

Mineral sunscreen compositions having improved efficacy are described. The mineral sunscreen compositions include: (a) one or more mineral UV filtering agents; (b) one or more stilbenoids; (c) ethylhexylmethoxycrylene. (d) diethylhexyl syringylidenemalonate; and (e) a cosmetically acceptable carrier. The mineral sunscreen compositions provide a high sun protection factor (SPF) without requiring high amounts of mineral UV filtering agents. Also, the mineral sunscreen compositions are less opaque and white than traditional mineral sunscreen compositions making them aesthetically appealing to consumers.

Claims (48)

1. A sunscreen composition comprising:

(a) one or more mineral UV filtering agents;

(b) piceid;

(c) ethylhexylmethoxycrylene;

(d) diethylhexyl syringylidenemalonate; and

wherein weight ratios for the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate relative to the total weight of the combination of the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate is as follows:

0.1 to 0.4 for the piceid,

0.3 to 0.53 for the ethylhexylmethoxycrylene; and

0.1 to 0.4 for the diethylhexyl syringylidenemalonate

(e) a cosmetically acceptable carrier.

2. The sunscreen composition of claim 1 , wherein the one or more mineral UV filtering agents are selected from titanium dioxide, zinc oxide, iron oxides, cerium oxides, zirconium oxides, and a mixture thereof.

3. The sunscreen composition of claim 1 , wherein the total amount of the piceid, the diethylhexyl syringylidenemalonate, and the ethylhexylmethoxycrylene in the sunscreen composition is about 0.5 wt. % to about 6 wt. %, based on the total weight of the sunscreen composition.

4. The sunscreen composition of claim 1 , wherein the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate are in amounts sufficient to boost the in vitro SPF of the sunscreen composition by at least 5% in comparison to an otherwise identical sunscreen composition in which the total amount of the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate is replaced with only ethylhexylmethoxycrylene.

5. The sunscreen composition of claim 1 , wherein the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate are in amounts sufficient to boost the in vitro SPF of the sunscreen composition by at least 5% in comparison to an otherwise identical sunscreen composition in which the total amount of the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate is replaced with only diethylhexyl syringylidenemalonate.

6. The sunscreen composition of claim 1 , wherein the sunscreen composition is free of butyl methoxydibenzoylmethane (avobenzone) and ethylhexyl methoxycinnamate (octinoxate).

7. The sunscreen composition of claim 1 , wherein the sunscreen composition is free of organic UV filtering agents.

8. The sunscreen composition of claim 1 , wherein the total amount of the one or more inorganic UV filtering agents is from about 1 to about 25 wt. %, based on the total weight of the sunscreen composition.

9. A sunscreen composition of claim 1 comprising:

(a) one or more mineral UV filtering agents:

(b) at least 0.2 wt. % of piceid:

(c) at least 0.5 wt. % of ethylhexylmethoxycrylene: and

(d) at least 0.2 wt. % of diethylhexyl syringylidenemalonate,

wherein the weight percentages are based on the total weight of the sunscreen composition: and wherein the total amount of the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate does not exceed 6 wt. %, based on the total weight of the sunscreen composition.

10. A sunscreen composition of claim 1 comprising:

(a) one or more mineral UV filtering agents;

(b) about 0.2 to about 3 wt % of piceid;

(c) about 0.5 to about 5 wt. % of ethylhexylmethoxycrylene; and

(d) about 0.2 to about 2 wt. % of diethylhexyl syringylidenemalonate,

wherein the weight percentages are based on the total weight of the sunscreen composition.

11. The sunscreen composition of claim 1 , wherein the piceid, the ethylhexylmethoxycrylene and the diethylhexyl syringylidenemalonate are in amounts sufficient to:

boost the in vitro SPF of the sunscreen composition by at least 5% in comparison to an otherwise identical sunscreen composition in which the total amount of the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate is replaced with only ethylhexylmethoxycrylene; and

boost the in vitro SPF of the sunscreen composition by at least 5% in comparison to an otherwise identical sunscreen composition in which the total amount of the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate is replaced with only diethylhexyl syringylidenemalonate.

12. The sunscreen composition of claim 1 , further comprising:

(f) one or more silicone oils.

13. The sunscreen composition of claim 1 in the form of a lotion, cream, gel, or spray.

14. The sunscreen composition of claim 1 , wherein the cosmetically acceptable carrier comprises water.

15. The sunscreen composition of claim 1 in the form of an emulsion.

16. A sunscreen composition comprising:

(a) about 1 to about 25 wt. %, based on the total weight of the sunscreen composition, of one or more mineral UV filtering agents selected from titanium dioxide, iron oxide, and a mixture thereof;

(b) piceid;

(c) ethylhexylmethoxycrylene; and

(d) diethylhexyl syringylidenemalonate;

wherein the total amount of the combination of the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate is from about 1 wt % to about 6 wt %, based on the total weight of the sunscreen composition; and

weight ratios for the piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate relative to the total weight of the combination of piceid, the ethylhexylmethoxycrylene, and the diethylhexyl syringylidenemalonate is as follows:

0.1 to about 0.4 for the piceid;

0.3 to 0.53 for the ethylhexylmethoxycrylene; and

about 0.1 to 0.4 for the diethylhexyl syringylidenemalonate.

17. A method for protecting skin from UV radiation comprising applying an effective amount of the sunscreen composition of claim 1 to the skin.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 10, 2018
From: SHAH, ANIL; BODNAR, BRIAN SCOTT
To: L'OREAL
Reel/Frame 047722/0114 →
Continuity (1)
Related Publication 20200101002A1 · Apr 2, 2020
Cited By (2)
US 12,453,681 US 12,605,314