Ethylene/alpha-olefin copolymer having excellent environmental stress crack resistance
Provided is an ethylene/alpha-olefin copolymer having excellent environmental stress crack resistance.
1. An ethylene/alpha-olefin copolymer, wherein
a weight average molecular weight is 50,000 g/mol to 250,000 g/mol,
a molecular weight distribution (Mw/Mn) is 4 to 20,
a density is 0.950 g/cm 3 to 0.965 g/cm 3 ,
a melt flow rate ratio (MFR 5 /MFR 2.16 ) as measured at 190° C. according to ASTM 1238 is 3 to 10, and
environmental stress crack resistance as measured according to ASTM D1693-B is 150 hours to 350 hours.
2. The ethylene/alpha-olefin copolymer of claim 1 , wherein the weight average molecular weight is 180,000 g/mol to 220,000 g/mol.
3. The ethylene/alpha-olefin copolymer of claim 1 , wherein the molecular weight distribution (Mw/Mn) is 10 to 15.
4. The ethylene/alpha-olefin copolymer of claim 1 , wherein the melt flow rate ratio is 5 to 8.
5. The ethylene/alpha-olefin copolymer of claim 1 , wherein the environmental stress crack resistance is 200 hours to 400 hours.
6. The ethylene/alpha-olefin copolymer of claim 1 , wherein
crack resistance is 100 hours or more, the crack resistance is a time at which a water pressure begins to decrease, when the water pressure of 5 bar is applied to the inside of a cap obtained by injection-molding of the ethylene/alpha-olefin copolymer while the cap is immersed in a bath containing a 5% igepal solution, wherein the cap is a 28 mm cap according to PET standard PCO 1881.
7. The ethylene/alpha-olefin copolymer of claim 1 , wherein
the alpha-olefin is one or more selected from the group consisting of 1-propylene, 1-butene, 1-pentene, 1-hexene, 4-methyl-1 -pentene, 1-octene, 1-decene, 1-docene, 1-tetradecene, 1-hexadecene, 1-octadecene, 1-eicosene, and mixtures thereof.