Hard coat layered film
Embodiments provide a hard coat layered film having a first hard coat, a second hard coat, and a transparent resin film layer in order from an outer layer side, the first hard coat including (A) 100 parts by mass of a polyfunctional (meth)acrylate including 20% by mass or more of a tripentaerythritol acrylate, (B) 0.01-7 parts by mass of a water repellent, and (C) 0.01-10 parts by mass of a silane coupling agent, the first hard coat being formed from a coating material not including inorganic particles, and the second hard coat including (A′) 100 parts by mass of a polyfunctional (meth)acrylate and (D) 50-300 parts by mass of inorganic fine particles having an average particle diameter of 1-300 nm. According to at least one embodiment, component (A) may be a mixture of tripentaerythritol acrylate and one or more species selected from the group consisting of dipentaerythritol acrylate, monopentaerythritol acrylate, and polypentaerythritol acrylate.
1. A hard coat laminated film, comprising:
a first hard coat,
a second hard coat, and
a transparent resin film layer in order from a surface layer side,
wherein the first hard coat comprises
(A) 100 parts by mass of a polyfunctional (meth)acrylate comprising 20% by mass or more of a tripentaerythritol acrylate;
(B) 0.01 to 7 parts by mass of a water repellent; and
(C) 0.01 to 10 parts by mass of a silane coupling agent,
wherein the first hard coat being formed from a coating material not containing inorganic particles; and
wherein the second hard coat comprising (A′) 100 parts by mass of a polyfunctional (meth)acrylate; and
wherein (D) 50 to 300 parts by mass of inorganic fine particles having an average particle diameter of 1 to 300 nm.
2. The hard coat laminated film according to claim 1 , wherein the polyfunctional (meth)acrylate comprising 20% by mass or more of a tripentaerythritol acrylate of component (A) is a mixture of a tripentaerythritol acrylate; and
one or more species selected from the group consisting of a dipentaerythritol acrylate, a monopentaerythritol acrylate, and a polypentaerythritol acrylate.
3. The hard coat laminated film according to claim 1 , wherein the (C) silane coupling agent comprises one or more species selected from the group consisting of a silane coupling agent having an amino group and a silane coupling agent having a mercapto group.
4. The hard coat laminated film according to claim 1 , wherein the (B) water repellent comprises a (meth)acryloyl group-containing fluoropolyether water repellent.
5. The hard coat laminated film according to claim 1 , wherein the coating material for forming the second hard coat further comprises (E) 0.01 to 1 part by mass of a leveling agent.
6. The hard coat laminated film according to claim 1 , wherein a thickness of the first hard coat is 0.5 to 5 μm.
7. The hard coat laminated film according to claim 1 , wherein a thickness of the second hard coat is 10 to 30 μm.
8. The hard coat laminated film according to claim 1 , wherein the transparent resin film is a transparent multilayer film with a first poly(meth)acrylimide resin layer (α1); an aromatic polycarbonate resin layer (β); and a second poly(meth)acrylimide resin layer (α2) directly laminated in this order.
9. Use of the hard coat laminated film according to claim 1 for a member in an image display device.
10. An image display device comprising the hard coat laminated film according to claim 1 .
11. The hard coat laminated film according to claim 1 , wherein the polyfunctional (meth)acrylate comprising 20% by mass or more of a tripentaerythritol acrylate of component (A) is a polyfunctional (meth)acrylate comprising 40% by mass or more of a tripentaerythritol acrylate.
12. The hard coat laminated film according to claim 1 , wherein the polyfunctional (meth)acrylate comprising 20% by mass or more of a tripentaerythritol acrylate of component (A) is a mixture of a tripentaerythritol acrylate, a dipentaerythritol acrylate, a monopentaerythritol acrylate, and a polypentaerythritol acrylate.
13. The hard coat laminated film according to claim 1 , wherein the (D) inorganic fine particles having an average particle diameter of 1 to 300 nm are silica fine particles.
14. A method for producing the hard coat laminated film according to claim 1 , comprising the steps of:
(1) coating the transparent resin film with the coating material for forming the second hard coat to form a first wet coat;
(2) irradiating the first wet coat formed from a coating material for forming the second hard coat with an active energy ray so that the integrated amount of light is 1 to 230 mJ/cm 2 to convert the first wet coat formed from the coating material for forming the second hard coat into a coat in a set-to-touch state;
(3) coating the coat in a set-to-touch state formed from the coating material for forming the second hard coat with a coating material for forming the first hard coat to form a second wet coat; and
(4) preheating the second wet coat formed from the coating material for forming the first hard coat to a temperature of 30 to 100° C. followed by irradiating with an active energy ray so that the integrated amount of light is 240 to 10000 mJ/cm 2 to obtain a hard coat laminated film comprising the second hard coat formed from the coating material for forming the second hard coat and the first hard coat formed from the coating material for forming the first hard coat.