Tempered vacuum glass
The disclosure describes a tempered vacuum glass, which comprises: at least two glass sheets arranged parallel to each other; surrounding edges of adjacent glass sheets being sealed using an edge sealing structure; and support members placed in an array between the adjacent glass sheets to form a vacuum space. The edge sealing structure is a metallic edge-sealing structure. The structure comprises a first transition layer, a first metallized layer, a first intermetallic compound layer, a solder layer, a second intermetallic compound layer, a second metallized layer, and a second transition layer stacked in that order. The first and second metallized layers are in a spongy skeleton structure formed by sintering a metal paste. The first and second transition layers are formed by sintering the metal paste on the adjacent glass sheets, and contain a glass phase layer including metallic particles and a metal oxide layer with a net structure.
1. A tempered vacuum glass, comprising:
at least two glass sheets arranged parallel to each other, at least one of the at least two glass sheets being tempered glass;
surrounding edges of adjacent glass sheets being sealed by an edge sealing structure; and
support members placed in an array between the adjacent glass sheets to form a vacuum space;
wherein:
the edge sealing structure is a metallic edge-sealing structure formed by sealing the surrounding edges of the adjacent glass sheets with metal;
the edge sealing structure comprises a first transition layer, a first metallized layer, a first intermetallic compound layer, a solder layer, a second intermetallic compound layer, a second metallized layer, and a second transition layer stacked in that order;
the first and second metallized layers are in a spongy skeleton structure formed by sintering of a first metal paste;
the first and second intermetallic compound layers comprise intermetallic compound formed by solder in the solder layer and the first metal paste, wherein the solder is heated and melt to fill pores of the spongy skeleton structure on the first and second metallized layers' surfaces adjacent to the solder layer; and
the first and second transition layers are formed by sintering a second metal paste on the adjacent glass sheets, and contain a glass phase layer including metallic particles and a metal oxide layer,
wherein the metal oxide layer and the glass phase layer form a mutually inclusive integrated structure.
2. A tempered vacuum glass according to claim 1 , wherein the solder layer is formed through melting of a low-temperature solder containing tin, and the low-temperature solder containing tin is a combination of tin and one or more transition metals, rare metals, or precious metals.
3. A tempered vacuum glass according to claim 2 , wherein material of the solder layer is Sn—Ag—Cu, Sn—Au, Sn—Pb, Sn—Ag, Sn—Cu, Sn—Zn, Sn—Bi, Sn—Sb, Sn—Ag—Cu—Bi, Sn—Ag—Bi—In—Ti, Sn—Ag—Bi—In, Sn—Ag—Cu—In—Ti, or Sn—Ag—Bi—Cu—In—Ti alloy.
4. A tempered vacuum glass according to claim 1 , wherein the first metal paste or the second metal paste is a silver paste, a silver-coated copper paste, or a silver-coated nickel paste, which contains one or more rare metals, transition metals, or precious metals.
5. A tempered vacuum glass according to claim 1 ,
wherein each joint surface of the first and second intermetallic compound layers and the solder layer has a rugged tooth structure.
6. A tempered vacuum glass according to claim 5 , wherein the first and second intermetallic compound layer contain one or more Ag3Sn, AgZn, or In3Sn.
7. A tempered vacuum glass according to claim 1 , wherein the first and second intermetallic compound layer contain about 3% to 10% of glass phase.
8. A tempered vacuum glass according to claim 1 , wherein at least one of the at least two glass sheets includes a pump-out hole, and a cap liner that is used to seal the pump-out hole.
9. A tempered vacuum glass according to claim 1 , wherein outer sides of the edge sealing structure are provided with a secondary peripheral sealing structure including sealant, resin, or plastic.