IP Library › Granted Patent US 10,835,887
Granted Patent B2
US 10,835,887 · App. 16/080,998 · Granted Nov 17, 2020

Process for producing water-absorbing resin particles

Inventors: Maoki Hama (Himeji, JP); Koji Takagi (Himeji, JP); Kenta Kumazawa (Himeji, JP); Sho Isokawa (Himeji, JP)
Assignee: SUMITOMO SEIKA CHEMICALS CO., LTD
B01J20/261B01J20/28004B01J20/28016B01J20/3085C08F2/32C08F20/06
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Quick Facts
Patent No.
US 10,835,887
App. No.
16/080,998
Granted
Nov 17, 2020
Kind
B2
Abstract

The present invention provides a method for producing water-absorbent resin particles that has a low stirring load, and can produce water-absorbent resin particles having a particle diameter within a specific range, with high productivity. The method for producing water-absorbent resin particles comprises adding an ethylenically unsaturated monomer all at once to a hydrocarbon dispersion medium mixed with a surfactant to perform reversed phase suspension polymerization, wherein the reversed phase suspension polymerization is performed in one step, or two or more steps, the surfactant is at least one selected from the group consisting of polyoxyethylene alkyl ether phosphates, alkali metal salts of polyoxyethylene alkyl ether phosphates, and alkaline earth metal salts of polyoxyethylene alkyl ether phosphates, and the surfactant has an HLB of 9 to 15.

Claims (8)

1. A method for producing water-absorbent resin particles comprising:

adding an ethylenically unsaturated monomer all at once to a hydrocarbon dispersion medium mixed with a surfactant to perform reversed phase suspension polymerization, wherein

the reversed phase suspension polymerization is performed in one step, or two or more steps,

the surfactant is at least one selected from the group consisting of polyoxyethylene alkyl ether phosphates, alkali metal salts of polyoxyethylene alkyl ether phosphates, and alkaline earth metal salts of polyoxyethylene alkyl ether phosphates, and the surfactant has an HLB of 9.0 to 15.0.

2. The method for producing water-absorbent resin particles according to claim 1 , wherein the surfactant is a polyoxyethylene alkyl ether phosphate sodium salt.

3. The method for producing water-absorbent resin particles according to claim 1 , wherein the surfactant is used in an amount of 0.1 to 3.0 parts by mass per 100 parts by mass of the ethylenically unsaturated monomer.

4. The method for producing water-absorbent resin particles according to claim 1 , wherein the ethylenically unsaturated monomer is at least one selected from the group consisting of (meth)acrylic acid and salts thereof.

5. The method according to claim 1 , wherein the surfactant is at least one selected from the group consisting of sodium oleth-7-phosphate, Laureth-2 phosphate, laureth-4 phosphate and (C12-15) pareth-6 phosphate.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Nov 16, 2018
From: HAMA, MAOKI; TAKAGI, KOJI; KUMAZAWA, KENTA; ISOKAWA, SHO
To: SUMITOMO SEIKA CHEMICALS CO., LTD.
Reel/Frame 047527/0262 →
Priority Claims (1)
JP 2016-039799 · Mar 2, 2016 · national
Continuity (1)
Related Publication 20190030512A1 · Jan 31, 2019