Polyolefin production with chromium-based catalysts
A method including contacting a chromium-based catalyst with a reducing agent in a solvent to lower an oxidation state of at least some chromium in the chromium-based catalyst to give a reduced chromium-based catalyst, drying the reduced chromium-based catalyst at a temperature, and adjusting the temperature to affect the flow index response of the reduced chromium-based catalyst.
1. A method of preparing a chromium-based catalyst for the polymerization of an olefin into a polyolefin, the method comprising:
contacting a chromium-based catalyst with a reducing agent in a solvent to lower an oxidation state of at least some chromium in the chromium-based catalyst to give a mixture of a reduced chromium-based catalyst and the solvent, wherein the chromium-based catalyst comprises a chromium oxide catalyst;
drying the reduced chromium-based catalyst at a drying line-out temperature; and
adjusting the drying line-out temperature to change the flow index response of the reduced chromium-based catalyst.
2. The method of claim 1 , wherein the reducing agent comprises an organoaluminum compound, and wherein the solvent comprises an alkane.
3. The method of claim 1 , wherein the reducing agent comprises diethylaluminum ethoxide (DEAlE).
4. The method of claim 1 , wherein the reducing agent comprises triethyl aluminum (TEAL).
5. The method of claim 1 , wherein the chromium-based catalyst comprises an inorganic oxide support having a pore volume of about 1.1 to about 1.8 cubic centimeters (cm3)/g and a surface area of about 245 to about 375 square meters (m2)/g.
6. The method of claim 1 , wherein the chromium-based catalyst comprises an inorganic oxide support having a pore volume of about 2.4 to about 3.7 cm3/g and a surface area of about 410 to about 620 m2/g.
7. The method of claim 1 , wherein the chromium-based catalyst comprises an inorganic oxide support having a pore volume of about 0.9 to about 1.4 cm3/g and a surface area of about 390 to about 590 m2/g.
8. The method of claim 1 , wherein the chromium-based catalyst comprises an activated and supported chromium-based catalyst, and wherein drying comprises evaporating at least a majority of the solvent.
9. The method of claim 1 , wherein contacting the chromium-based catalyst with the reducing agent allows the chromium-based catalyst to react with the reducing agent to give the reduced chromium-based catalyst.
10. The method of claim 1 , wherein contacting comprises contacting the chromium-based catalyst with the reducing agent in the solvent at a reaction temperature lower than the drying line-out temperature, and wherein the reaction temperature is in the range of 20° C. to 60° C., and the drying line-out temperature is in the range of 40° C. to 90° C.
11. The method of claim 1 , wherein drying comprises reducing a pressure of the mixture of the reduced chromium-based catalyst and the solvent.
12. The method of claim 1 , wherein the drying is initiated after substantially all of the reducing agent contacted with the chromium-based catalyst has been consumed in a reaction of the reducing agent with the chromium-based catalyst.
13. The method of claim 1 , comprising collecting the reduced chromium-based catalyst for supply to a polymerization reactor.
14. The method of claim 1 , comprising feeding the reduced chromium-based catalyst to a polymerization reactor to polymerize an olefin into a polyolefin.
15. The method of claim 1 , wherein drying comprises filtering the reduced chromium-based catalyst to remove solvent at a temperature of less than 30° C.