High-strength heavy-walled stainless steel seamless tube or pipe and method of manufacturing the same
A high-strength heavy-walled stainless steel seamless tube or pipe exhibiting excellent low-temperature toughness is characterized by having a chemical composition containing Cr: 15.5% to 18.0% and a steel microstructure containing a ferritic phase and a martensitic phase, wherein the maximum value of the areas of the ferrite grains in the steel microstructures in a circumferential direction cross section and an L direction (rolling direction) cross section of the steel tube or pipe is 3,000 μm 2 or less and the content of ferrite grains having areas of 800 μm 2 or less is 50% or more on an area fraction basis, where, when adjacent ferrite grains are present in the steel microstructure and the crystal misorientation between one ferrite grain and the other ferrite grain is 15° or more, the adjacent grains are assumed to be grains different from each other.
1. A high-strength heavy-walled stainless steel seamless tube or pipe with excellent low-temperature toughness,
comprising a steel microstructure containing a ferritic phase and a martensitic phase, and a chemical composition consisting of, on a percent by mass basis,
Cr: 15.5% to 18.0%, C: 0.050% or less, Si: 1.00% or less, Mn: 0.20% to 1.80%, Ni: 1.5% to 5.0%, Mo: 1.0% to 3.5%, V: 0.02% to 0.20%, N: 0.02% to 0.15%, O: 0.006% or less, W: 0.5% to 3.5%,
optionally, at least one group selected from Group A to Group D:
Group A: Al: 0.002% to 0.050%,
Group B: at least one selected from Cu: 3.5% or less, W: 3.5% or less, and REM: 0.3% or less,
Group C: at least one selected from Nb: 0.2% or less, Ti: 0.3% or less, and Zr: 0.2% or less,
Group D: at least one selected from Ca: 0.01% or less and B: 0.01% or less, and
the remainder composed of Fe and incidental impurities,
wherein ferrite grains have maximum areas of 3,000 μm 2 or less in the steel microstructures in a circumferential direction cross section and an L direction (rolling direction) cross section of the steel tube or pipe and content of ferrite grains having areas of 800 μm 2 or less is 50% or more on an area fraction basis, where, adjacent grains are grains different from each other when crystal mis-orientation between one ferrite grain and another ferrite grain is 15° or more.
2. A method of manufacturing a high-strength heavy-walled stainless steel seamless tube or pipe according to claim 1 , comprising: heating a steel, performing piercing the steel to produce a hollow base steel, and subjecting the hollow base steel to elongating rolling, wherein the elongating rolling includes adjusting a hot working temperature of 700° C. to 1,200° C. and obtaining a steel microstructure of the hollow base steel at the hot working temperature that contains 35% or more of austenite on an area fraction basis.
3. The high-strength heavy-walled stainless steel seamless tube or pipe according to claim 1 , wherein the chemical composition contains C: 0.030% to 0.050%.
4. A method of manufacturing a high-strength heavy-walled stainless steel seamless tube or pipe according to claim 3 , comprising: heating a steel, performing piercing the steel to produce a hollow base steel, and subjecting the hollow base steel to elongating rolling, wherein the elongating rolling includes adjusting a hot working temperature of 700° C. to 1,200° C. and obtaining a steel microstructure of the hollow base steel at the hot working temperature that contains 35% or more of austenite on an area fraction basis.