Gel electrolyte for use in a magnesium battery
View Patent ↗Gel electrolytes and other solid electrolytes for magnesium batteries include a monocarboranyl magnesium salt and an ether solvent having a relatively high boiling point. A polymer forms a gel or other solid matrix throughout which the monocarboranyl magnesium salt and ether solvent are uniformly distributed. Methods for making such electrolytes include combining solutions of monocarboranyl magnesium salt and polymer, followed by selectively removing the solvent in which polymer has high solubility, forcing gel formation.
1. A three-dimensional magnesium battery, comprising:
a magnesium foam anode;
a continuous electrolyte layer coating all surfaces of the magnesium foam anode, the continuous electrolyte layer comprising:
an ether solvent having a boiling point, at standard pressure, greater than 100° C.;
a monocarboranyl magnesium salt; and
a matrix-forming polymer, present at a concentration that exceeds its solubility in the ether solvent; and
a continuous cathode layer coating most or all exposed surfaces of the continuous electrolyte layer.
2. The three-dimensional magnesium battery as recited in claim 1 , wherein the ether solvent has a boiling point, at standard pressure, greater than 150° C.
3. The three-dimensional magnesium battery as recited in claim 1 , wherein the ether solvent has a boiling point, at standard pressure, greater than 200° C.
4. The electrolyte as recited in claim 1 , wherein the monocarboranyl salt comprises a closo-carboranyl anion having a formula [CB (n-1) X n ] − , wherein X is selected from the group consisting of: hydrogen, halogen, alkyl, alkoxy, cycloalkyl, aryl, aryloxy, amino, thioether, phosphine, and combinations thereof.
5. The three-dimensional magnesium battery as recited in claim 1 , wherein the monocarboranyl salt comprises Mg(CB 11 H 12 ) 2 .
6. A method of making a electrolyte for a magnesium battery, the method comprising:
combining:
a first solution having:
an ether solvent having a boiling point, at standard pressure, greater than 100° C.; and
a monocarboranyl magnesium salt dissolved in the ether solvent; and
a second solution having:
a second solvent having a boiling point, at standard pressure, less than 100° C.; and
a polymer dissolved in the second solvent, the polymer having low solubility in the ether solvent;
evaporatively removing the second solvent under conditions at which the ether solvent does not substantially evaporate, so that the polymer at least partially comes out of solution.
7. The method as recited in claim 6 , wherein the ether solvent has a boiling point, at standard pressure, greater than 150° C.
8. The method as recited in claim 6 , wherein the ether solvent has a boiling point, at standard pressure, greater than 200° C.
9. The method as recited in claim 6 , wherein the second solvent has a boiling point, at standard pressure, less than 85° C.
10. The method as recited in claim 6 , wherein the monocarboranyl salt comprises a closo-carboranyl anion having a formula [CB (n-1) X n ] − , wherein X is selected from the group consisting of: hydrogen, halogen, alkyl, alkoxy, cycloalkyl, aryl, aryloxy, amino, thioether, phosphine, and combinations thereof.
11. The method as recited in claim 6 , wherein the monocarboranyl salt comprises Mg(CB 11 H 12 ) 2 .
12. The method as recited in claim 6 , wherein the ether solvent is selected from the group consisting of: diethylene glycol dimethyl ether (diglyme), triethylene glycol dimethyl ether (triglyme), tetraethylene glycol dimethyl ether (tetraglyme), and polyethylene glycol dimethyl ether (PEGDME).
13. The method as recited in claim 6 , wherein the polymer is selected from the group consisting of: polyvinylidene fluoride (PVDF), polytetrafluoroethylene (PTFE), styrene butadiene rubber, and a polyimide.