Packaging material for power storage device, packaging case for power storage device, and power storage device
A packaging material for a power storage device includes a heat resistant resin layer 2 as an outer layer, a sealant layer 3 as an inner layer, and a metal foil layer 4 arranged between these layers. The sealant layer 3 is composed of one layer or a plurality of layers. The innermost layer 7 of the sealant layer contains a random copolymer containing propylene as a copolymerization component and another copolymerization component other than propylene, a roughening material, and a lubricant. The roughening material is composed of particles containing a thermoplastic resin. The center line average roughness Ra of the surface 7 a of the innermost layer 7 is 0.05 μm to 1 μm. It can provide a packaging material for a power storage device which is excellent in formability and hard to generate white powder on the surface.
1. A packaging material for a power storage device, comprising:
a heat resistant resin layer as an outer layer;
a sealant layer as an inner layer; and
a metal foil layer arranged between the heat resistant resin layer and the sealant layer, wherein
the sealant layer is composed of one layer or a plurality of layers, and an innermost layer of the sealant layer contains a random copolymer containing propylene as a copolymerization component and another copolymerization component other than propylene, a roughening material, and a lubricant,
the roughening material is composed of particles containing a thermoplastic resin, and
a center line average roughness Ra of a surface of the innermost layer is 0.05 μm to 1 μm,
wherein the roughening material in a dispersed state has an average particle diameter of 0.05 μm to 10 μm, and,
wherein the packaging material has formability,
wherein the thermoplastic resin constituting the roughening material is a high-density polyethylene resin, and
wherein a density of the high-density polyethylene resin is 0.935 g/cm 3 to 0.965 g/cm 3 , and a melt flow rate of the high-density polyethylene resin at 190° C. is within a range of 0.01 g/10 min to 2 g/10 min.
2. The packaging material for a power storage device as recited in claim 1 , wherein
the lubricant is one or more lubricants selected from the group consisting of fatty acid amide, wax, silicone, and paraffin.
3. A packaging case for a power storage device, the packaging case being composed of a shaped body of the packaging material for a power storage device as recited in claim 1 .
4. A power storage device comprising:
a power storage device main body; and
a packaging material composed of the packaging material for a power storage device as recited in claim 1 ,
wherein the power storage device main body is packaged by the packaging material.
5. A packaging material for a power storage device, comprising:
a heat resistant resin layer as an outer layer;
a sealant layer as an inner layer; and
a metal foil layer arranged between the heat resistant resin layer and the sealant layer, wherein
the sealant layer is composed of one layer or a plurality of layers, and an innermost layer of the sealant layer contains a random copolymer containing propylene as a copolymerization component and another copolymerization component other than propylene, a roughening material, and a lubricant,
the roughening material is composed of particles containing a thermoplastic resin, and
a center line average roughness Ra of a surface of the innermost layer is 0.05 μm to 1 μm,
wherein the roughening material in a dispersed state has an average particle diameter of 0.05 μm to 10 μm, and,
wherein the packaging material has formability, and
wherein the roughening material in the innermost layer of the sealant layer is present in an amount from 1 mass % to 30 mass %, and the lubricant in the innermost layer in an amount which exceeds 0 ppm and is equal to or less than 1,000 ppm.
6. The packaging material for a power storage device as recited in claim 5 , wherein
the lubricant is one or more lubricants selected from the group consisting of fatty acid amide, wax, silicone, and paraffin.
7. A packaging case for a power storage device, the packaging case being composed of a shaped body of the packaging material for a power storage device as recited in claim 5 .
8. A power storage device comprising:
a power storage device main body; and
a packaging material composed of the packaging material for a power storage device as recited in claim 5 ,
wherein the power storage device main body is packaged by the packaging material.
9. A packaging material for a power storage device, comprising:
a heat resistant resin layer as an outer layer;
a sealant layer as an inner layer; and
a metal foil layer arranged between the heat resistant resin layer and the sealant layer, wherein
the sealant layer is composed of one layer or a plurality of layers, and an innermost layer of the sealant layer contains a random copolymer containing propylene as a copolymerization component and another copolymerization component other than propylene, a roughening material, and a lubricant,
the roughening material is composed of particles containing a thermoplastic resin, and
a center line average roughness Ra of a surface of the innermost layer is 0.05 μm to 1 μm,
wherein the roughening material in a dispersed state has an average particle diameter of 0.05 μm to 10 μm, and,
wherein the packaging material has formability,
wherein the sealant layer is composed of a plurality of layers, and
wherein the sealant layer includes the innermost layer, a first intermediate layer laminated on a surface of the innermost layer on a side of the metal foil layer, and a second intermediate layer laminated on a surface of the first intermediate layer on a side of the metal foil layer,
the first intermediate layer contains an elastomer-modified olefin-based resin,
the elastomer-modified olefin-based resin is composed of elastomer-modified homopolypropylene and/or an elastomer-modified random copolymer,
the elastomer-modified random copolymer is an elastomer modified product of a random copolymer containing propylene as a copolymerization component and another copolymerization component other than propylene, and
the second intermediate layer contains a random copolymer containing propylene as a copolymerization component and another copolymerization component other than propylene.
10. The packaging material for a power storage device as recited in claim 9 , wherein
the lubricant is one or more lubricants selected from the group consisting of fatty acid amide, wax, silicone, and paraffin.
11. The packaging material for a power storage device as recited in claim 9 , wherein
the sealant layer includes the innermost layer and a first intermediate layer laminated on a surface of the innermost layer on a side of the metal foil layer,
the first intermediate layer contains an elastomer-modified olefin-based resin,
the elastomer-modified olefin-based resin is composed of elastomer-modified homopolypropylene and/or an elastomer-modified random copolymer, and
the elastomer-modified random copolymer is an elastomer modified product of a random copolymer containing propylene as a copolymerization component and another copolymerization component other than propylene.
12. The packaging material for a power storage device as recited in claim 9 , wherein
the lubricant is one or more lubricants selected from the group consisting of fatty acid amide, wax, silicone, and paraffin.
13. A power storage device comprising:
a power storage device main body; and
a packaging material composed of the packaging material for a power storage device as recited in claim 9 ,
wherein the power storage device main body is packaged by the packaging material.