Encapsulation
An improved process of making a benefit agent delivery particle and consumer products incorporating such particles are disclosed. The process comprises the steps of providing a first composition of water phase 1, water phase 2 and water phase 3. Water phase 1 comprises water and an initiator; water phase 2 comprises water, a water-soluble or dispersible amine(meth)acrylate or hydroxyl(meth)acrylate and a multifunctional (meth)acrylate. Water phase 3 comprises water, and carboxyalkyl(meth)acrylate and a base or quaternary ammonium acrylate. The first two water phases are combined to prereact the hydroxy- or amine(meth)acrylate and the multifunctional (meth)acrylate to form a multifunctional hydroxyl-amine(meth)acrylate pre-polymer. The pre-polymer is combined with water phase 3; then an emulsion is formed by emulsifying under high shear agitation a second composition into said first composition; said second composition comprising an oil phase comprising an isocyanate and a benefit agent core material thereby forming a wall surrounding the benefit agent core material.
1. A consumer product comprising the combination of a consumer product ingredient and microcapsules, the microcapsules having a shell with surface charge functional groups, the microcapsules made by a process comprising:
dispersing in one or more water phases an initiator, and a cross-linking functional monomer having one or more —OH, —NH 2 , or —NH − groups, and a charge functional monomer having one or more anionic or cationic groups which are selected from carboxy, sulfonic acid, quaternary ammonium groups, or other charged groups;
prereacting the cross-linking functional monomer and the charge-functional monomer in the one or more water phases and combining with a water dispersible multifunctional (meth)acrylate monomer;
further prereacting the cross-linking functional monomers and the charge-functional monomers, forming prereacted monomers;
forming an emulsion by emulsifying into the water phase or phases, using high shear agitation, an oil phase comprising an isocyanate and a benefit agent core material;
optionally adding in addition, an amine cross-linker;
further reacting the combined emulsion of prereacted monomers, water dispersible multifunctional (meth)acrylate monomer, and emulsified oil phase by heating for a time and temperature, or actinic irradiation for a time, sufficient to form a microcapsule shell surrounding the benefit agent core material,
wherein the shell comprises a reaction product of the isocyanate, the prereacted monomers, and the water dispersible multifunctional (meth)acrylate monomer.
2. The consumer product according to claim 1 wherein the cross-linking functional monomer is an amine.
3. The consumer product according to claim 2 wherein the amine is an alkylaminoalkyl(meth)acrylate.
4. The consumer product according to claim 1 wherein the cross-linking functional monomer is hydroxyl functional.
5. The consumer product according to claim 4 wherein the cross-linking functional monomer is a hydroxyl(meth)acrylate.
6. A consumer product comprising the combination of a consumer product ingredient and microcapsules comprising an oil soluble or dispersible benefit agent core material and a shell surrounding the benefit agent core material, the shell comprising a polyurea formed from a first component of an isocyanate and a second component of an amine, the amine comprising the reaction product of an alkylaminoalkyl(meth)acrylate and a multifunctional (meth)acrylate, together with a carboxyalkyl(meth)acrylate or quaternary ammonium acrylate.
7. The consumer product according to claim 6 wherein the amine is tertiary-butylaminoethylmethacrylate.
8. A consumer product according to claim 6 wherein the shell of the microcapsules comprises a reaction product of an isocyanate; and a multifunctional amine (meth)acrylate.
9. The consumer product according to claim 6 wherein the isocyanate is selected from isophorone diisocyanate, 4,4′-methylene diphenyl diisocyanate, 2,2′-methylene diphenyl diisocyanate, and 2,4′-methylene diphenyl diisocyanate.
10. The consumer product according to claim 6 wherein the alkylaminoalkyl (meth)acrylate is selected wherein each alkyl moiety is independently from C 1 to C 8 .
11. The consumer product according to claim 6 wherein the alkylamino (meth)acrylate is selected from tertiary-butylaminoethyl methacrylate, tertiary-butylaminopropyl methacrylate, n-butylaminoethyl methacrylate, diethylaminoethyl methacrylate, dimethylaminoethyl methacrylate, diisopropyaminoethyl methacrylate, dibutylaminoethyl methacrylate, dipropylaminoethyl methacrylate, tertiary pentylaminoethyl methacrylate, tertiary hexylaminoethyl methacrylate, tertiary-butylaminopropyl methacrylate, diethylaminopropyl methacrylate, and dimethylaminopropyl methacrylate.
12. The consumer product according to claim 6 wherein the microcapsule has a zeta potential, measured at a pH of 7, of from +70 to −70.
13. The consumer product according to claim 6 wherein the benefit agent core material of the microcapsule is selected from one or more of a fragrance, perfume, phase change material, biological active, antimicrobial, self-healing composition, lubricant or cooling agent.
14. A consumer product comprising the combination of a consumer product ingredient and microcapsules comprising an oil soluble or dispersible benefit agent core material and a shell surrounding the benefit agent core material, the shell comprising a reaction product of an isocyanate; and a multifunctional amine (meth)acrylate, together with a carboxyalkyl(meth)acrylate, wherein the multifunctional amine(meth)acrylate is selected to be polar.