Porous graphene network electrodes and an all-carbon lithium ion battery containing the same
Systems for the production of graphene oxide sheets are provided. The systems include electro-deposition and spray deposition techniques. The graphene oxide sheets may be used as pre-cursors for the formation of porous graphene network (PGN) anodes and lithiated porous graphene (Li-PGN) cathodes. The method of making PGN electrodes includes thermally reducing a pre-cursor sheet of graphene oxide to provide a PGN anode and exposing the sheet to lithium or a lithium-containing compound to produce a Li-PGN cathode. The Li-PGN cathode and PGN anode may be combined with an electrolyte to provide an “all-carbon” battery that is useful in various applications, such as automotive applications.
1. A system for the production of graphene sheets comprising:
a counter electrode and a working electrode immersed in a bath, the bath containing a dispersion of graphene oxide,
a membrane applied to a surface of the counter electrode,
a source of electricity configured to apply a current between the counter electrode and the working electrode capable of electrolytically depositing the graphene oxide in the bath onto the membrane; and
a reduction zone downstream of the bath configured to reduce the graphene oxide to graphene, the reduction zone comprising a light source configured to emit flashes having an energy intensity of about 150 Ws to about 400 Ws.
2. The system of claim 1 , wherein the membrane comprises a hydrophilic porous polymer.
3. The system of claim 1 , wherein the membrane is configured to be removable from the bath following deposition of the graphene oxide.
4. The system of claim 1 , further comprising a plurality of rollers configured to advance the membrane through the bath and wherein the membrane is in the form of a web provided on at least one of the plurality of rollers.
5. The system of claim 4 further comprising a drying zone downstream of the bath and configured to dry the graphene oxide deposited on the membrane.
6. The system of claim 4 wherein the membrane is configured to be separated from the graphene oxide and wound on one of the plurality of rollers between the drying zone and the reduction zone.