Composition for removing silicone resins and method of thinning substrate by using the same
Compositions for removing silicone resins and methods of thinning a substrate by using the same, as well as related methods, apparatus and systems for facilitating the removal of silicone resins are provided. The compositions for removing silicone resins, may include a heterocyclic solvent and an alkyl ammonium fluoride salt represented by a formula, (R) 4 N + F − , wherein R is a C1 to C4 linear alkyl group. Silicone resins may be effectively removed by using the compositions since the compositions exhibit an excellent decomposition rate with respect to the silicone resins that remain on a semiconductor substrate in a process of backside grinding of the semiconductor substrate, backside electrode formation, or the like.
1. A composition for removing silicone resins, the composition comprising:
a heterocyclic solvent; and
an alkyl ammonium fluoride salt represented by Formula (1):
(R) 4 N + F − Formula (1)
wherein R is a C3 or C4 linear alkyl group,
wherein the heterocyclic solvent comprises at least one selected from the group consisting of a pyridine solvent, a morpholine solvent, a piperazine solvent, a urea solvent, and an oxazolidinone solvent, and
wherein the composition comprises a protic solvent in an amount less than 10% based on a total weight of the compositions, wherein the heterocyclic solvent is present in an amount of about 90 wt % to about 99 wt % based on a total weight of the composition, and wherein the alkyl ammonium fluoride salt represented by Formula (1) is present in an amount of about 0.1 wt % to about 10 wt % based on a total weight of the composition.
2. The composition according to claim 1 , wherein the amount of the protic solvent is 3 wt % or less of the composition.
3. The composition according to claim 2 , wherein the protic solvent comprises at least one of water and an alcohol.
4. The composition according to claim 1 , further comprising:
a surfactant; and
a corrosion inhibitor.
5. A composition for removing silicone resins, the composition comprising:
a heterocyclic solvent; and
an alkyl ammonium fluoride salt represented by Formula (1):
(R) 4 N + F − Formula (1)
wherein R is a C3 or C4 linear alkyl group;
wherein the alkyl ammonium fluoride salt is present in an amount of about 0.1 wt % to about 10 wt % based on a total weight of the composition,
wherein the heterocyclic solvent has a 4- to 8-membered ring;
wherein the heterocyclic solvent is at least one selected from the group consisting of a nitrogen-containing and oxygen-containing heterocyclic solvent; and
wherein the heterocyclic solvent is present in an amount of about 70 wt % to about 99.9 wt % based on a total weight of the composition.
6. The composition according to claim 5 , wherein the heterocyclic solvent comprises at least one selected from the group consisting of a pyridine solvent, a morpholine solvent, a piperazine solvent, a urea solvent, and an oxazolidinone solvent.
7. The composition according to claim 5 , wherein the composition comprises a protic solvent in an amount of 3 wt % or less of the composition.
8. The composition according to claim 5 , wherein the composition comprises any one of water and alcohol in an amount of 3 wt % or less of the composition.
9. A system for temporarily bonding a target substrate to a carrier substrate to facilitate processing of the target substrate, the system comprising:
a carrier substrate;
a silicone binder configured to bond the carrier substrate to the target substrate;
a separation apparatus configured to separate the carrier substrate and the target substrate from one another such that a residue of the silicone binder remains on the target substrate; and
a composition configured to remove the residue, wherein the composition comprises a heterocyclic solvent and an alkyl ammonium fluoride salt represented by Formula (1):
(R) 4 N + F − Formula (1)
wherein R is a C3 or C4 linear alkyl group,
wherein the heterocyclic solvent comprises at least one selected from the group consisting of a pyridine solvent, a morpholine solvent, a piperazine solvent, a urea solvent, and an oxazolidinone solvent, and
wherein the composition comprises a protic solvent in an amount of 3 wt % of less based on a total weight of the composition, wherein the heterocyclic solvent is present in an amount of about 90 wt % to about 99 wt % based on a total weight of the composition, and wherein the alkyl ammonium fluoride salt represented by Formula (1) is present in an amount of about 0.1 wt % to about 10 wt % based on a total weight of the composition.
10. The system of claim 9 , wherein the silicone binder comprises:
a silicone release layer configured to contact the target substrate; and
a silicone adhesive layer disposed on the silicone release layer and contacting the carrier substrate.
11. The composition according to claim 1 , wherein the heterocyclic solvent comprises a pyridine solvent represented by Formula (2):
wherein each of R 1 , R 2 , and R 3 are independently a hydrogen, a halogen element, a C1 to C22 branched or non-branched alkyl group, a C1 to C10 alkoxy group, a C2 to C22 branched or non-branched alkenyl group, a C1 to C20 alkylamino group, a C6 to C20 aryl or alkylaryl group, a C7 to C20 arylalkyl group, a C5 to C12 cycloalkyl group, an aldehyde group, an acetaldehyde group, a cyanide group, or a methyl sulfide group.
12. The composition according to claim 1 , wherein the heterocyclic solvent comprises at least one selected from the group consisting of 2-methylpyridine, 3-methylpyridine, 4-methylpyridine, 4-ethylpyridine, 4-propylpyridine, 4-isopropylpyridine, 4-amylpyridine, 2,3-lutidine, 2,4-lutidine, 2,5-lutidine, 3,4-lutidine, 3,5-lutidine, and 2,4,6-trimethylpyridine.
13. The composition according to claim 1 , wherein the heterocyclic solvent comprises a morpholine solvent represented by Formula (3):
wherein R 4 is a hydrogen, a halogen element, a C1 to C6 branched or non-branched alkyl group, a C1 to C6 alkoxy group, a C2 to C6 branched or non-branched alkenyl group, a C1 to C6 alkylamino group, a C6 to C15 aryl or alkylaryl group, a C7 to C15 arylalkyl group, a C5 to C10 cycloalkyl group, an aldehyde group, an acetaldehyde group, a cyanide group, or a methyl sulfide group.
14. The composition according to claim 13 , wherein R 4 is a phenyl group substituted with a C1 to C4 aliphatic hydrocarbon, a halogen element, a cyanide group, or an aldehyde group; or R 4 is a pyridine group substituted with a C1 to C4 aliphatic hydrocarbon, a halogen element, a cyanide group, or an aldehyde group.
15. The composition according to claim 1 , wherein the heterocyclic solvent comprises a piperazine solvent represented by Formula (4):
wherein each of R 5 and R 6 is a hydrogen, a halogen element, a C1 to C6 branched or non-branched alkyl group, a C1 to C6 alkoxy group, a C2 to C6 branched or non-branched alkenyl group, a C1 to C6 alkylamino group, a C6 to C15 aryl or alkylaryl group, a C7 to C15 arylalkyl group, a C5 to C10 cycloalkyl group, an aldehyde group, an acetaldehyde group, a cyanide group, or a methyl sulfide group.
16. The composition according to claim 15 , wherein R 5 or R 6 is a phenyl group substituted with a C1 to C4 aliphatic hydrocarbon, a halogen element, a cyanide group, or an aldehyde group; or R 5 or R 6 is a pyridine group substituted with a C1 to C4 aliphatic hydrocarbon, a halogen element, a cyanide group, or an aldehyde group.
17. The composition according to claim 1 , wherein the heterocyclic solvent comprises a pyrrolidone solvent represented by Formula (5):
wherein R 7 is a hydrogen, a halogen element, a C1 to C6 branched or non-branched alkyl group, a C1 to C6 alkoxy group, a C2 to C6 branched or non-branched alkenyl group, a C1 to C6 alkylamino group, a C6 to C15 aryl or alkylaryl group, a C7 to C15 arylalkyl group, a C5 to C10 cycloalkyl group, an aldehyde group, an acetaldehyde group, a cyanide group, or a methyl sulfide group.
18. The composition according to claim 1 , wherein the heterocyclic solvent comprises a urea solvent represented by Formula (6):
wherein each of R 8 and R 9 is a hydrogen, a halogen element, a C1 to C6 branched or non-branched alkyl group, a C1 to C6 alkoxy group, a C2 to C6 branched or non-branched alkenyl group, a C1 to C6 alkylamino group, a C6 to C15 aryl or alkylaryl group, a C7 to C15 arylalkyl group, a C5 to C10 cycloalkyl group, an aldehyde group, an acetaldehyde group, a cyanide group, or a methyl sulfide group.
19. The composition according to claim 1 , wherein the heterocyclic solvent comprises a oxazolidinone solvent represented by Formula (7):
wherein R 10 is a hydrogen, a halogen element, a C1 to C6 branched or non-branched alkyl group, a C1 to C6 alkoxy group, a C2 to C6 branched or non-branched alkenyl group, a C1 to C6 alkylamino group, a C6 to C15 aryl or alkylaryl group, a C7 to C15 arylalkyl group, a C5 to C10 cycloalkyl group, an aldehyde group, an acetaldehyde group, a cyanide group, or a methyl sulfide group.
20. The composition according to claim 5 , wherein the composition comprises alcohol in an amount of 3 wt% or less of the composition.