Compound for organic electric device, organic electric device using same, and electronic device comprising same

1. An organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode,

wherein the organic material layer forms a hole transport layer between the first electrode and the emitting layer, and includes an electron blocking layer between the hole transport layer and the emitting layer,

wherein the electron blocking layer comprises a compound represented by Formula (1), and wherein the hole transport layer comprises a compound represented by Formula (2):

in Formula (1) to (2),

1) n is an integer of 0 to 4, and m is an integer of 0 to 3,

2) R 1 and R 2 are each independently selected from the group consisting of a deuterium; a halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one hetero atom of O, N, S, Si and P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group; and -L′-N(R a )(R b )(where, L′ may be selected from the group consisting of a single bond; a C 6 -C 60 arylene group; a fluorenylene group; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; and a C 2 -C 60 heterocyclic, and the R a and R b may be independently selected from the group consisting of a C 6 -C 60 aryl group; a fluorenyl group; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; and a C 2 -C 60 heterocyclic group containing at least one hetero atom of O, N, S, Si, or P), or in case m and n are each 2 or more a plurality of R 1 or a plurality of R 2 , each same or different, may be bonded to each other to form a ring,

3) Ar 1 and Ar 2 are each independently a C 12 -C 20 aryl group unsubstituted or substituted with deuterium,

4) a, b, and c are each independently integer of 0 to 4, and d is an integer of 0 to 3,

5) R 5 , R 6 , R 7 and R 8 are each independently selected from the group consisting of a deuterium; a halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one hetero atom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group; and -L′-N(R a )(R b ); or in case a, b, c, d, e and f are each 2 or more, a plurality of R 5 or a plurality of R 6 or a plurality of R 7 or a plurality of R 8 , each same or different, may be bonded to each other to form a ring,

6) Ar 3 and Ar 4 are each independently selected from the group consisting of a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one hetero atom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring;

in Formula (2), the aryl group, the fluorenyl group, the heterocyclic group, the fused ring group, the alkyl group, the alkenyl group, the alkynyl group, the alkoxyl group and the aryloxy group may be each independently substituted with one or more substituents selected from a group consisting of a deuterium; halogen; a silane group; a siloxane group; a boron group; a germanium group; a cyano; a nitro group; -L′-N(R a )(R b ); a C 1 -C 20 alkylthio group; C 1 -C 20 alkoxyl group; C 1 -C 20 alkyl group; C 2 -C 20 alkenyl group; C 2 -C 20 alkynyl group; C 6 -C 20 aryl group; C 6 -C 20 aryl group substituted with deuterium; a fluorenyl group; C 2 -C 20 heterocyclic group; C 3 -C 20 cycloalkyl group; C 7 -C 20 arylalkyl group and C 8 -C 20 arylalkenyl group, and also, these substituents may combine each other and form a ring, wherein the term ‘ring’ means C 3 -C 60 aliphatic ring or C 6 -C 60 aromatic ring or a C 2 -C 60 heterocyclic ring or a fused ring formed by the combination of them, and includes a saturated or unsaturated ring.

2. The organic electric element of claim 1 , wherein the compound represented by Formula (1) of the electron blocking layer is represented by any one of the following Formulas (3) to (5):

in Formula (3) to (5), R 1 , R 2 , m and n are the same as defined in the claim 1 .

3. The organic electric element of claim 1 , wherein a compound represented by Formula (2) of the hole transport layer is represented by any one of the following Formulas (6) to (8):

wherein

1) R 5 , R 6 , R 7 , R 8 , a, b, c, d and Ar 3 are the same as defined in the claim 1 ,

2) f is an integer of 0 to 4, and e is an integer of 0 to 3,

3) R 9 and R 10 are each independently selected from the group consisting of a deuterium; halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one hetero atom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group; and -L′-N(R a )(R b ), or in case e and f are 2 or more, a plurality of R 9 or a plurality of R 10 , each same or different, may be bonded to each other to form a ring.

4. The organic electric element of claim 1 , wherein the compound represented by Formula (1) in the electron blocking layer comprises any one of the following compounds 1-1 to 3-12;

5. The organic electric element of claim 1 , wherein the compound represented by Formula (2) in the hole transport layer comprises any one of the following compounds 4-1 to 4-36:

6. The organic electric element of claim 2 , wherein the hole transport layer comprises a compound represented by any one of Formulas (6) to (8):

in Formulas (6) to (8),

R 5 , R 6 , R 7 , R 8 , a, b, c, d and Ar 3 are the same as defined in claim 2 .

7. The organic electric element of claim 4 , wherein the hole transport layer comprises any one of compounds represented by Formulas (6) to (8):

wherein:

1) Ar 3 is selected from the group consisting of a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one hetero atom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring;

2) R 5 , R 6 , R 7 and R 8 are each independently selected from the group consisting of a deuterium; a halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one hetero atom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group; and -L′-N(R a )(R b ); or in case a, b, c, d, e and f are each 2 or more, a plurality of R 5 or a plurality of R 6 or a plurality of R 7 or a plurality of R 8 , each same or different, may be bonded to each other to form a ring,

3) a, b, and c are each independently integer of 0 to 4, and d is an integer of 0 to 3,

4) R 9 and R 10 are each independently selected from the group consisting of a deuterium; halogen; a C 6 -C 60 aryl group; a fluorenyl group; a C 2 -C 60 heterocyclic group including at least one hetero atom of O, N, S, Si or P; a fused ring group of a C 3 -C 60 aliphatic ring and a C 6 -C 60 aromatic ring; a C 1 -C 50 alkyl group; a C 2 -C 20 alkenyl group; a C 2 -C 20 alkynyl group; a C 1 -C 30 alkoxyl group; a C 6 -C 30 aryloxy group; and -L′-N(R a )(R b ), or in case e and f are 2 or more, a plurality of R 9 or a plurality of R 10 , each same or different, may be bonded to each other to form a ring

5) f is an integer of 0 to 4, and e is an integer of 0 to 3.

8. The organic electric element of claim 4 , wherein the hole transport layer comprises any one of compounds represented by Formulas 4-1 to 4-36:

9. The organic electric element of claim 1 , wherein the electron blocking layer comprises a composition in which two or more compounds having different structures among the compounds represented by the formula (1) are mixed.

10. The organic electric element of claim 1 , wherein the hole transport layer comprises a composition in which two or more compounds having different structures among the compounds represented by the formula (2) are mixed.

11. The organic electric element of claim 1 , further comprising a light efficiency enhancing layer formed on at least one side opposite to the organic material layer among one side of the first electrode and the second electrode.

12. The organic electric element of claim 1 , wherein the organic material layer is formed by a spin coating process, a nozzle printing process, an inkjet printing process, a slot coating process, a dip coating process or a roll-to-roll process.

13. An electronic device comprising a display device comprising the organic electric element of claim 1 ; and a control part driving the display device.

14. The electronic device of claim 11 , wherein the organic electric element is one of an OLED, an organic solar cell, an organic photo conductor(OPC), Organic transistor(organic TFT) and an element for monochromic or white illumination.