Interlayer film for laminated glass and laminated glass
A first object of the invention is to provide an interlayer film for laminated glass which has excellent sound insulating properties and heat shielding properties, and a laminated glass using the same. Further, a second object of the invention is to provide an interlayer film for laminated glass capable of maintaining the sound insulating properties, weather resistance, and heat creep resistance at a high level even if the thickness is reduced, and a laminated glass using the same. The invention relates to an interlayer film for laminated glass, including at least one layer A containing a thermoplastic elastomer, wherein a laminated glass in which the interlayer film for laminated glass is disposed between two clear glasses with the total thickness of the clear glasses being 4 mm or less has a visible light transmittance of 70% or more and an average transmittance of infrared light in the wavelength range of 800 to 1,100 nm of 72% or less.
1. An interlayer film for laminated glass, comprising:
at least one layer A comprising a thermoplastic elastomer; and
at least one layer B comprising a thermoplastic resin, which is an ionomer resin, provided on at least one surface of the layer A;
wherein:
when the interlayer film is disposed between two clear glass layers of a laminated glass with a total thickness of the clear glass layers being 4 mm or less, the laminated glass has a visible light transmittance of 70% or more and an average transmittance of infrared light in the wavelength range of 800 to 1,100 nm of 72% or less;
the thermoplastic elastomer comprises a hard segment block and a soft segment block;
the hard segment block is a polystyrene block or a polymethyl methacrylate block;
the soft segment block comprises a conjugated diene monomer unit;
an amount of residual carbon-carbon double bonds derived from the conjugated diene monomer unit in the thermoplastic elastomer is from 2 to 40 mol %;
at least one of the layer A and the layer B comprises a UV absorber;
an area density of the UV absorber in the layer A is 0.1 g/m 2 and 10 g/m 2 or less, or an area density of the UV absorber in the layer B is 0.2 g/m 2 or more and 10 g/m 2 or less; and
wherein the layer B constitutes at least one outermost layer.
2. The interlayer film for laminated glass according to claim 1 , wherein, when the interlayer film is disposed between two clear glass layers of a laminated glass with a total thickness of the clear glass layers being 4 mm or less, the laminated glass has an average transmittance of infrared light in the wavelength range of 800 to 1,100 nm of 70% or less.
3. The interlayer film for laminated glass according to claim 1 wherein a heat shielding material is contained in at least one of the layers constituting the interlayer film for laminated glass.
4. The interlayer film for laminated glass according to claim 3 , wherein the heat shielding material is at least one material selected from tin-doped indium oxide, antimony-doped tin oxide, zinc antimonate, metal-doped tungsten oxide, a phthalocyanine compound, aluminum-doped zinc oxide, and lanthanum hexaboride.
5. The interlayer film for laminated glass according to claim 4 , wherein the metal-doped tungsten oxide is cesium-doped tungsten oxide.
6. The interlayer film for laminated glass according to claim 1 , wherein, when the interlayer film is disposed between two green glass layers of a laminated glass with a total thickness of the green glass layers being 4 mm or less, the laminated glass has a visible light transmittance of 70% or more and an average transmittance of infrared light in the wavelength range of 800 to 1,100 nm of 32% or less.
7. The interlayer film for laminated glass according to claim 1 , wherein
the thermoplastic elastomer is a hydrogenated product of a block copolymer having a polymer block (a) containing 60 mol % or more of an aromatic vinyl monomer unit and a polymer block (b) containing 60 mol % or more of a conjugated diene monomer unit, and
the polymer block (b) contains 50 mol % or more in total of an isoprene unit and a butadiene unit as the conjugated diene monomer unit.
8. The interlayer film for laminated glass according to claim 1 , wherein an antioxidant is contained in the layer A.
9. The interlayer film for laminated glass according to claim 8 , wherein the antioxidant is at least one or more compounds selected from the group consisting of a phenolic antioxidant, a phosphorus-based antioxidant, and a sulfur-based antioxidant.
10. The interlayer film for laminated glass according to claim 1 , wherein the temperature at which the peak maximum in tan δ as measured for the layer A by performing a dynamic viscoelasticity test at a frequency of 1,000 Hz in accordance with ASTM D4065-06 appears in the range of −10 to 30° C.
11. The interlayer film for laminated glass according to claim 1 , wherein the maximum value of tan δ as measured for the layer A by performing a dynamic viscoelasticity test at a frequency of 1,000 Hz in accordance with ASTM D4065-06 is 1.2 or more.
12. The interlayer film for laminated glass according to claim 1 , wherein the layer B containing a thermoplastic resin is provided on both surfaces of the layer A.
13. The interlayer film for laminated glass according to claim 1 , wherein the content of a plasticizer in the layer B is 50 parts by mass or less with respect to 100 parts by mass of the thermoplastic resin.
14. The interlayer film for laminated glass according to claim 1 , wherein the temperature at which the peak maximum in tan δ as measured for the layer B by performing a dynamic viscoelasticity test at a frequency of 1,000 Hz in accordance with ASTM D4065-06 appears at 30° C. or higher.
15. The interlayer film for laminated glass according to claim 1 , wherein a heat shielding material is contained in at least one of the layer A and the layer B.
16. The interlayer film for laminated glass according to claim 1 , wherein the UV absorber is at least one or more compounds selected from the group consisting of a benzotriazole-based compound, a benzophenone-based compound, a triazine-based compound, a hindered amine-based compound, a benzoate-based compound, a malonic ester-based compound, and an oxalic anilide-based compound.
17. The interlayer film for laminated glass according to claim 1 , wherein, when performing a weathering test on a laminated glass comprising the interlayer film disposed between two glass layers, with a total thickness of the glass layers being 4 mm or less, by exposure for 200 hours under conditions of an illuminance of 180 W/m 2 , a black panel temperature of 60° C., and a relative humidity of 50%, a change in color difference ΔE*ab in accordance with JIS Z 8781-4 for the laminated glass between before and after the weathering test is 2 or less.
18. The interlayer film for laminated glass according to claim 1 , wherein, when the interlayer film is disposed between two glass layers of a laminated glass with a total thickness of the glass layers being 4 mm or less, the laminated glass has a haze of 5 or less.
19. The interlayer film for laminated glass according to claim 1 , wherein, when the interlayer film is disposed between two glass layers of a laminated glass with a total thickness of the glass layers being 4 mm or less, the laminated glass has a sound transmission loss at 4,000 Hz as measured under the conditions of ASTM E 90-09 of 37 dB or more.
20. A laminated glass, comprising the interlayer film for laminated glass according to claim 1 , disposed between at least two glass layers.
21. The interlayer film for laminated glass according to claim 1 , wherein
the layer B constitutes the outermost layers.