Water-soluble packets
The disclosure provides a water soluble pouch including at least two sealed compartments, the pouch including outer walls including water soluble film including a water soluble resin, and an inner wall including water soluble film including a water soluble resin, the outer wall films being sealed to the inner wall film, the outer wall films being characterized by: a dissolution time of 300 seconds or less, the water soluble resin of the outer wall films having a viscosity in a range of 14.5 cP to 25 cP, and a pouch strength of at least 200 N, and the inner wall film being characterized by: a dissolution time of 300 seconds or less, the water soluble resin of the inner film having viscosity in a range of 12 cP to 14.5 cP, and a tackiness value of at least 1500 g/s.
1. A water soluble pouch defining an interior pouch volume, the pouch comprising at least two water-soluble films, wherein a first water soluble film of the at least two water-soluble films comprises a polyvinyl alcohol resin comprising a polyvinyl alcohol copolymer comprising an anionic monomer unit, optionally wherein the anionic monomer unit is derived from one or more of maleic acid, monoalkyl maleate, dialkyl maleate monomethyl maleate dimethyl maleate, maleic anhydride, alkali metal salts of the foregoing, and esters of the foregoing, and wherein the first water-soluble film comprising a polyvinyl alcohol copolymer comprising an anionic monomer unit is sealed to a second water-soluble film of the at least two water-soluble films using a sealing solution comprising water, one or more diols and/or glycols, and a surfactant.
2. The water-soluble pouch of claim 1 , wherein the surfactant is one or more selected from polyoxyethylenated polyoxypropylene glycols, alcohol ethoxylates, alkylphenol ethoxylates, tertiary acetylenic glycols and alkanolamides (nonionics), polyoxyethylenated amines, quaternary ammonium salts and quaternized polyoxyethylenated amines (cationics), amine oxides, N-alkylbetaines and sulfobetaines (zwitterionics), dioctyl sodium sulfosuccinate, lactylated fatty acid esters of glycerin and propylene glycol, lactylic esters of fatty acids, sodium alkyl sulfates, polysorbate 20, polysorbate 60, polysorbate 65, polysorbate 80, lecithin, acetylated fatty acid esters of glycerin and propylene glycol, and acetylated esters of fatty acids.
3. The water-soluble pouch of claim 2 , wherein the surfactant is one or more selected from polyoxyethylenated polyoxypropylene glycols, alcohol ethoxylates, alkylphenol ethoxylates, tertiary acetylenic glycols and alkanolamides, polyoxyethylenated amines, quaternary ammonium salts and quaternized polyoxyethylenated amines, amine oxides, N-alkylbetaines, sulfobetaines, and combinations thereof.
4. The water-soluble pouch of claim 1 , wherein the second water soluble film of the at least two water-soluble films comprises a polyvinyl alcohol resin comprising a polyvinyl alcohol copolymer comprising an anionic monomer unit, optionally wherein the anionic monomer unit is derived from one or more of maleic acid, monoalkyl maleate, dialkyl maleate monomethyl maleate dimethyl maleate, maleic anhydride, alkali metal salts of the foregoing, esters of the foregoing.
5. The pouch of claim 4 , wherein one or both copolymer-containing polyvinyl alcohol resins have a 4% solution viscosity at 20° C. in a range of 12 cP to 25 cP.
6. The pouch of claim 5 , wherein both the copolymer-containing polyvinyl alcohol resins have a 4% solution viscosity at 20° C. in a range of 14.5 cP to 25 cP.
7. The pouch of claim 4 , wherein one or both of the films is a blend of the copolymer resin further comprising a polyvinyl alcohol homopolymer resin.
8. The pouch of claim 7 , wherein the blend in one or both films comprises from 30 to 100 weight percent of the polyvinyl alcohol copolymer comprising an anionic monomer unit and from 0 to 70 weight percent of the polyvinyl alcohol homopolymer, based on the total weight of polyvinyl alcohol in the film.
9. The pouch of claim 4 , wherein the anionic monomer unit in one or both films is selected from the group consisting of vinyl acetic acid, alkyl acrylates, maleic acid, monoalkyl maleate, dialkyl maleate, monomethyl maleate, dimethyl maleate, maleic anhydride, fumaric acid, monoalkyl fumarate, dialkyl fumarate, monomethyl fumarate, dimethyl fumarate, fumaric anhydride, itaconic acid, monomethyl itaconate, dimethyl itaconate, itaconic anhydride, citraconic acid, monoalkyl citraconate, dialkyl citraconate, citraconic anhydride, mesaconic acid, monoalkyl mesaconate, dialkyl mesaconate, mesaconic anhydride, glutaconic acid, monoalkyl glutaconate, dialkyl glutaconate, glutaconic anhydride, vinyl sulfonic acid, alkyl sulfonic acid, ethylene sulfonic acid, 2-acrylamido-1-methyl propane sulfonic acid, 2-acrylamide-2-methylpropanesulfonic acid, 2-methylacrylamido-2-methylpropanesulfonic acid, 2-sulfoethyl acrylate, alkali metal salts of the foregoing, esters of the foregoing, and combinations of the foregoing.
10. The pouch of claim 9 , wherein the anionic monomer unit in one or both films is derived from one or more of maleic acid, monoalkyl maleate, dialkyl maleate, monomethyl maleate, dimethyl maleate, maleic anhydride, alkali metal salts of the foregoing.
11. The pouch of claim 7 , wherein the blend in one or both films comprises at least 65 weight percent of the polyvinyl alcohol copolymer comprising an anionic monomer based on the total weight of polyvinyl alcohol in the film.
12. The pouch of claim 4 , wherein the polyvinyl alcohol copolymer in one or both films comprises from 2 to 8 mol % of the anionic monomer unit.
13. The pouch of claim 1 , wherein the polyvinyl alcohol resin of the first water soluble film of the at least two water-soluble films has a degree of hydrolysis in a range of 87 to 93, or if a blend of polyvinyl alcohol resins is used then the arithmetic weight average degree of hydrolysis is in a range of 87 to 93.
14. The pouch of claim 4 , wherein one or both anionic copolymer films is characterized by a pouch strength of less than 2000 N as measured by the film sealed, conditioned, and tested according to the Pouch Strength Test.
15. The pouch of claim 1 , wherein the pouch has a pouch strength of at least 200 N as measured by the Pouch Strength Test.
16. The pouch of claim 4 , wherein one or both copolymer-containing films further comprise a plasticizer.
17. The pouch of claim 16 , wherein the plasticizer is selected from the group consisting of glycerin, trimethylol propane, sorbitol, and combinations thereof.
18. The pouch of claim 4 , wherein one or both copolymer-containing films further comprise a surfactant.
19. The pouch of claim 18 , wherein the surfactant is selected from the group consisting of polyoxyethylenated polyoxypropylene glycols, alcohol ethoxylates, alkylphenol ethoxylates, tertiary acetylenic glycols and alkanolamides, polyoxyethylenated amines, quaternary ammonium salts and quaternized polyoxyethylenated amines, and amine oxides, N-alkylbetaines, sulfobetaines, and combinations thereof.
20. The pouch of claim 1 , wherein at least one film further comprises an aversive agent comprising a bitterant, a pungent, or a combination thereof.
21. The pouch of claim 4 , wherein one or both copolymer-containing films has a tackiness value of at least 1500 g/s for the film tested according to the Tackiness PA Test.
22. A method of making a water-soluble pouch according to claim 1 , comprising solvent sealing the first water-soluble film to the second water soluble film with a sealing solution comprising water, one or more diols and/or glycols, and a surfactant.