Polyolefin film with improved toughness
A film formed from a polyethylene copolymer using a reduced chromium oxide catalyst, ethylene monomers and a co-monomer selected from butene monomers or 1-hexene, where the polyethylene copolymer has a density in the range of from about 0.935 to about 0.950 g/cm 3 and an I 21 /I 5 in a range of about 18.0 to about 30.0. The film formed from the polyethylene copolymer has a dart drop impact (g/μm) that significantly greater as compared to a film of the polyethylene copolymer formed using a silyl chromate catalyst in place of the reduced chromium oxide catalyst. A method of making such films is also provided.
1. A film comprising: a polyethylene copolymer formed using a reduced chromium oxide catalyst, ethylene monomers and a co-monomer selected from the group consisting of 1-butene and 1-hexene, the polyethylene copolymer formed with the co-monomer to ethylene monomer mole ratio in a range of about 0.012 to about 0.04 to form the polyethylene copolymer having a density in the range of from about 0.9350 to about 0.950 g/cm 3 and an I 21 /I 5 in a range of about 18.0 to about 30.0, wherein the polyethylene copolymer formed using the reduced chromium oxide catalyst provides an improvement in a dart drop impact (g/μm) of the film of 17 percent to 56 percent as compared to a film of the polyethylene copolymer formed using a silyl chromate catalyst in place of the reduced chromium oxide catalyst.
2. The film of claim 1 , where the reduced chromium oxide catalyst is reduced with diethylaluminum ethoxide (DEAlE).
3. The film of claim 1 , wherein the polyethylene copolymer has a melt index (I 5 ) of about 0.4 to about 1.0 g/10 min.
4. The film of claim 1 , wherein the polyethylene copolymer has a flow index (I 21 ) of about 5.0 to about 25.0 g/10 min.
5. The film of claim 1 , wherein the polyethylene copolymer has an I 21 /I 5 of about 18.0 to about 28.0.
6. The film of claim 1 , wherein the film has a dart drop impact of about 10.0 to about 20.0 g/μm.
7. The film of claim 1 , wherein the polyethylene copolymer has a Mw ≥about 100,000 g/mol.
8. The film of claim 1 , wherein the film has a TD Elmendorf Tear of about 2.4 g/μm to about 15.0 g/μm.
9. The film of claim 1 , wherein the film has an MD Elmendorf Tear of about 0.6 g/μm to about 5.0 g/μm.
10. The film of claim 1 , wherein the film has a 2% secant modulus from about 600 MPa to about 1400 MPa.
11. The film of claim 1 , wherein the polyethylene copolymer has a Mw/Mn of about 6.0 to about 50.0.
12. A method of making a film having improved dart impact, comprising
providing a polyethylene copolymer formed using a reduced chromium oxide catalyst, ethylene monomers and a co-monomer selected from the group consisting of 1-butene and 1-hexene, where the co-monomer to ethylene monomer mole ratio is in a range of about 0.012 to about 0.04 to form the polyethylene copolymer having a density in the range of from about 0.935 to about 0.950 g/cm 3 and an I 21 /I 5 in a range of about 18 to about 30; and
forming the polyethylene into a film; wherein the polyethylene copolymer formed using the reduced chromium oxide catalyst provides an improvement in a dart drop impact (g/μm) of the film of 17 percent to 56 percent as compared to a film of the polyethylene copolymer formed using a silyl chromate catalyst in place of the reduced chromium oxide catalyst.
13. The method of claim 12 , wherein the polyethylene copolymer has a melt index (I 5 ) of about 0.4 to about 1.0 g/10 min.
14. The method of claim 12 , wherein the polyethylene copolymer has a flow index (I 21 ) of about 5.0 to about 25.0 g/10 min.
15. The method of claim 12 , wherein the film has a dart drop impact of about 10.0 to about 20.0 g/μm.
16. The method of claim 12 , wherein the polyethylene copolymer has a Mw ≥about 100,000 g/mol.
17. The method of claim 12 , wherein the film has a TD Elmendorf Tear of about 2.4 g/μm to about 15.0 g/μm.
18. The method of claim 12 , wherein the film has an MD Elmendorf Tear of about 0.6 g/μm to about 5.0 g/μm.
19. The method of claim 12 , wherein the film has a 2% secant modulus from about 600 MPa to about 1400 MPa.
20. The method of claim 12 , wherein the polyethylene copolymer has a Mw/Mn of about 6.0 to about 50.0.