Method for producing (meth)acrylic acid
A method for producing (meth)acrylic acid comprising: a step of obtaining a (meth)acrylic acid-containing gas by subjecting a (meth)acrylic acid production raw material to a catalytic gas phase oxidation reaction; a step of obtaining a (meth)acrylic acid-containing liquid by bringing the (meth)acrylic acid-containing gas into contact with a collection solvent and/or condensing the (meth)acrylic acid-containing gas by cooling; a step of obtaining crude (meth)acrylic acid by introducing the (meth)acrylic acid-containing liquid into a low-boiling separation column; a step of obtaining purified (meth)acrylic acid and a refining residue containing a glyoxal compound by purifying the crude (meth)acrylic acid; and a step of returning at least a part of the refining residue to the low-boiling separation column; wherein a returning position of the refining residue to the low-boiling separation column is located closer to a bottom side of the low-boiling separation column than a supply port of the (meth)acrylic acid-containing liquid.
1. A method for producing (meth)acrylic acid, the method comprising:
a step of obtaining a (meth)acrylic acid-containing gas by subjecting a (meth)acrylic acid production raw material to a catalytic gas phase oxidation reaction;
a step of obtaining a (meth)acrylic acid-containing liquid by bringing the (meth)acrylic acid-containing gas into contact with a collection solvent and/or condensing the (meth)acrylic acid-containing gas by cooling;
a step of obtaining crude (meth)acrylic acid by introducing the (meth)acrylic acid-containing liquid into a low-boiling separation column;
a step of obtaining purified (meth)acrylic acid and a refining residue containing a glyoxal compound by purifying the crude (meth)acrylic acid; and
a step of returning at least a part of the refining residue to the low-boiling separation column;
wherein the returning position of the refining residue to the low-boiling separation column is located closer to the bottom side of the low-boiling separation column than the supply port of the (meth)acrylic acid-containing liquid.
2. The method for producing (meth)acrylic acid according to claim 1 , wherein
the crude (meth)acrylic acid is introduced into a crystallizer and purified, and the refining residue is obtained as a crystallizing residue.
3. The method for producing (meth)acrylic acid according to claim 1 , wherein
the crude (meth)acrylic acid is withdrawn from an outlet port at a position that is intermediate of the top side and the bottom side of the low-boiling separation column, and
the returning position of the refining residue to the low-boiling separation column is located closer to the bottom side of the low-boiling separation column than the outlet port.
4. The method for producing (meth)acrylic acid according to claim 1 , wherein
the returning position of the refining residue to the low-boiling separation column is located at a bottom part of the low-boiling separation column.
5. The method for producing (meth)acrylic acid according to claim 1 , wherein
the crude (meth)acrylic acid is withdrawn from an outlet port at a position that is intermediate of the top side and the bottom side of the low-boiling separation column, and
a bottom liquid is withdrawn from the bottom part of the low-boiling separation column and introduced into a high-boiling separation column.
6. The method for producing (meth)acrylic acid according to claim 5 , wherein
a bottom liquid is withdrawn from a bottom part of the high-boiling separation column and introduced into a (meth)acrylic acid dimmer decomposition apparatus.