Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus
Provided is an electrophotographic photosensitive member that can achieve both of abrasion resistance and the suppression of a ghost. The electrophotographic photosensitive member includes: a support; an undercoat layer; a charge-generating layer; and a charge-transporting layer, the undercoat layer, the charge-generating layer, and the charge-transporting layer being arranged in the stated order on the support, wherein the charge-transporting layer includes a charge-transporting substance, and a polymer containing a structure represented by the following general formula (1) and a structure represented by the following general formula (2), wherein the charge-generating layer includes a phthalocyanine crystal and a binder resin, and wherein the undercoat layer includes strontium titanate particles and a binder resin.
1. An electrophotographic photosensitive member comprising, in this order:
a support;
an undercoat layer comprising strontium titanate particles and a binder resin;
a charge-generating layer comprising a phthalocyanine crystal and a binder resin; and
a charge-transporting layer, wherein
the charge-transporting layer includes a charge-transporting substance, and a copolymer containing a structure represented by formula (1) and a structure represented by formula (2)
where R 1 and R 2 independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group or an aryl group, R 3 and R 4 independently represent a halogen atom, an alkyl group, a cycloalkyl group or an aryl group, m and n independently represent an integer of 0 to 4, and X represents a cycloalkylene group, an alkylene group, a phenylene group, a biphenylene group, a naphthylene group, —O—, —S—, —SO— or —SO 2 —.
2. The electrophotographic photosensitive member according to claim 1 , wherein the charge-transporting layer has a thickness of 30 μm or more.
3. The electrophotographic photosensitive member according to claim 1 , wherein a content of the copolymer in the charge-transporting layer is 125 to 250 mass % with respect to a content of the charge-transporting sub stance.
4. The electrophotographic photosensitive member according to claim 1 , wherein the phthalocyanine crystal comprises one of a gallium phthalocyanine crystal and a titanyl phthalocyanine crystal.
5. The electrophotographic photosensitive member according to claim 1 , wherein a content of the strontium titanate particles in the undercoat layer is 100 to 500 mass % with respect to a content of the binder resin.
6. The electrophotographic photosensitive member according to claim 1 , wherein the strontium titanate particles have a specific surface area of 30 m 2 /g or more.
7. The electrophotographic photosensitive member according to claim 6 , wherein primary particles of the strontium titanate particles have a number-average particle diameter of 10 to 100 nm.
8. The electrophotographic photosensitive member according to claim 6 , wherein the strontium titanate particles are subjected to a surface treatment with a silane coupling agent.
9. The electrophotographic photosensitive member according to claim 1 , wherein the copolymer contains the structure represented by formula (1) and the structure represented by formula (2) at a mass ratio of 3:7 to 4:6.
10. A process cartridge comprising:
an electrophotographic photosensitive member; and
at least one unit selected from the group consisting of a charging unit, a developing unit and a cleaning unit,
the process cartridge integrally supporting the electrophotographic photosensitive member and the at least one unit, and being removably mounted onto a main body of an electrophotographic apparatus, the electrophotographic photosensitive member comprising in this order:
a support;
an undercoat layer comprising strontium titanate particles and a binder resin;
a charge-generating layer comprising a phthalocyanine crystal and a binder resin; and
a charge-transporting layer, wherein
the charge-transporting layer includes a charge-transporting substance, and a copolymer containing a structure represented by formula (1) and a structure represented by formula (2)
where R 1 and R 2 independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group or an aryl group, R 3 and R 4 independently represent a halogen atom, an alkyl group, a cycloalkyl group or an aryl group, m and n independently represent an integer of 0 to 4, and X represents a cycloalkylene group, an alkylene group, a phenylene group, a biphenylene group, a naphthylene group, —O—, —S—, —SO— or —SO 2 —.
11. The process cartridge according to claim 10 , wherein the copolymer contains the structure represented by formula (1) and the structure represented by formula (2) at a mass ratio of 3:7 to 4:6.
12. An electrophotographic apparatus comprising:
an electrophotographic photosensitive member; and
at least one unit selected from the group consisting of a charging unit, an exposing unit, a developing unit and a transferring unit, the electrophotographic photosensitive member comprising in this order:
a support;
an undercoat layer comprising strontium titanate particles and a binder resin;
a charge-generating layer comprising a phthalocyanine crystal and a binder resin; and
a charge-transporting layer,
wherein the charge-transporting layer includes a charge-transporting substance, and a polymer copolymer containing a structure represented by formula (1) and a structure represented by formula (2)
where R 1 and R 2 independently represent a hydrogen atom, a halogen atom, a substituted or unsubstituted alkyl group or an aryl group, R 3 and R 4 independently represent a halogen atom, an alkyl group, a cycloalkyl group or an aryl group, m and n independently represent an integer of 0 to 4, and X represents a cycloalkylene group, an alkylene group, a phenylene group, a biphenylene group, a naphthylene group, —O—, —S—, —SO— or —SO 2 —.
13. The electrophotographic apparatus according to claim 12 , wherein the copolymer contains the structure represented by formula (1) and the structure represented by formula (2) at a mass ratio of 3:7 to 4:6.