Binder composition, binder dispersion liquid, electrode mixture, electrode, non-aqueous electrolyte secondary battery, and method for producing binder composition
The present invention provides a binder composition which suppresses a swelling ratio in an electrolyte solution while having sufficient peel strength. The binder composition according to the present invention contains a copolymer including monomer units derived from vinylidene fluoride, a fluorine-containing alkyl vinyl compound, and a crosslinkable monomer; the content of the monomer unit derived from the fluorine-containing alkyl vinyl compound in the copolymer being not less than 2 mass % and less than 10 mass %; and the content of the monomer unit derived from the crosslinkable monomer being less than 5 mass %.
1. A binder composition for binding an electrode active material to a current collector,
the binder composition comprising:
a copolymer including monomer units derived from vinylidene fluoride;
hexafluoropropylene; and
a crosslinkable monomer;
a content of the monomer unit derived from the hexafluoropropylene in the copolymer being not less than 3 mass % and not greater than 9 mass %, and
a content of the monomer unit derived from the crosslinkable monomer being not less than 0.1 mass % to less than 5 mass %;
wherein the crosslinkable monomer is perfluorodivinyl ether or perfluoroalkylene divinyl ether.
2. The binder composition according to claim 1 , wherein the copolymer is a ternary copolymer containing monomer units including vinylidene fluoride, a fluorine-containing alkyl vinyl compound, and a crosslinkable monomer.
3. A binder dispersion liquid comprising the binder composition according to claim 1 and a water-based solvent.
4. An electrode mixture comprising the binder dispersion liquid according to claim 3 and an electrode active material.
5. An electrode comprising a layer formed from the electrode mixture according to claim 4 on a current collector.
6. A non-aqueous electrolyte secondary battery comprising the electrode according to claim 5 .
7. A method for producing a binder composition for binding an electrode active material to a current collector, the binder composition containing a copolymer including monomer units derived from vinylidene fluoride, hexafluoropropylene, and a crosslinkable monomer, the method comprising
producing the copolymer using the hexafluoropropylene in an amount of not less than 3 parts by mass and not greater than 9 parts by mass and the crosslinkable monomer in an amount of not less than 0.1 parts by mass to less than 5 parts by mass when a total amount of the monomers used in the production of the copolymer is defined as 100 parts by mass;
wherein the crosslinkable monomer is perfluorodivinyl ether or perfluoroalkylene divinyl ether.
8. The binder composition according to claim 1 , wherein the content of the monomer unit derived from the crosslinkable monomer is 0.3 mass % to less than 5 mass %.
9. The method according to claim 7 , wherein the crosslinkable monomer is in an amount of 0.3 parts by mass to less than 5 parts by mass.