IP Library › Granted Patent US 10,938,062
Granted Patent B2
US 10,938,062 · App. 16/220,980 · Granted Mar 2, 2021

Sulfide solid electrolyte material, lithium solid battery and method of preparing sulfide solid electrolyte material

Inventors: Koichi Sugiura (Susono, JP); Shigenori Hama (Sunto-gun, JP); Miwako Ohashi (Mishima, JP)
Assignee: TOYOTA JIDOSHA KABUSHIKI KAISHA
H01M10/0562C03C3/323C03C4/14H01M10/052H01M10/0585H01M2300/0068
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Quick Facts
Patent No.
US 10,938,062
App. No.
16/220,980
Granted
Mar 2, 2021
Kind
B2
Abstract

A method for preparing a sulfide solid electrolyte material exhibiting Li ion conductivity. The sulfide solid electrolyte material contains an organic compound having a molecular weight within a range of 30 to 300, and the organic compound is present in an amount of 0.8 wt % or less. The method includes: (i) performing mechanical milling to a mixture of a raw material composition and the organic compound to convert the raw material composition to an amorphous state, thereby synthesizing a sulfide glass; and (ii) drying the sulfide glass such that at least some of the organic compound remains in the sulfide solid electrolyte material.

Claims (7)

1. A method of preparing a sulfide solid electrolyte material exhibiting a Li ion conductivity, wherein the sulfide solid electrolyte material comprises: (i) an organic compound having a molecular weight within a range of 30 to 300, (ii) S element, (iii) Li element, and (iv) at least one element selected from the group consisting of P, Si, Ge, Al, and B elements, the method comprising:

performing mechanical milling to a mixture of a raw material composition and the organic compound to convert the raw material composition to an amorphous state, thereby synthesizing a sulfide glass; and

drying the sulfide glass at a temperature in a range of from 110° C. to 140° C. such that an amount of the organic compound remaining in the sulfide solid electrolyte material is 0.40 wt % or more and 0.65 wt % or less, based on an amount of the sulfide solid electrolyte material.

2. The method according to claim 1 , wherein the sulfide solid electrolyte material further comprises a halogen element.

3. The method according to claim 1 , wherein the molecular weight of the organic compound is within a range of from 60 to 200.

4. The method according to claim 1 , wherein the organic compound is liquid at a temperature of 25° C.

5. The method according to claim 1 , wherein the organic compound is an aprotic organic compound.

Priority Claims (1)
JP JP2012-284233 · Dec 27, 2012 · national
Continuity (2)
Division 14654916
Related Publication 20190207247A1 · Jul 4, 2019
Cited By (1)
US 12,731,814