Polyarylene sulfide resin, method for producing same, poly(arylene sulfonium salt), and method for producing poly(arylene sulfonium salt)
Disclosed is a production method comprising a step of obtaining a poly(arylene sulfonium salt) comprising a terminal group including at least one functional group selected from the group consisting of a carboxy group, a hydroxy group and an amino group, and a step of dealkylating or dearylating the poly(arylene sulfonium salt) to obtain a polyarylene sulfide resin, and a polyarylene sulfide resin comprising a terminal group including a functional group obtainable by the production method.
1. A method for producing a polyarylene sulfide resin comprising a main chain including a constitutional unit represented by the following formula (1-1) or the following formula (2-1) and a terminal group bonding to a terminal of the main chain and including at least one functional group selected from the group consisting of a carboxy group, a hydroxy group and an amino group, the method comprising:
a step of dealkylating or dearylating a poly(arylene sulfonium salt) comprising a main chain including a constitutional unit represented by the following formula (1-2) or a constitutional unit represented by the following formula (2-2) and a terminal group bonding to a terminal of the main chain and including at least one functional group selected from the group consisting of a carboxy group, a hydroxy group and an amino group:
wherein, in formulas (1-1), (1-2), (2-1) and (2-2), R 1 represents an alkyl group having 1 to 10 carbon atoms or an aryl group optionally having an alkyl group having 1 to 10 carbon atoms; R 2b represents a direct bond, —Ar 4b —, —S—Ar 4b —, —O—Ar 4b —, —CO—Ar 4b —, —SO 2 —Ar 4b — or —C(CF 3 ) 2 —Ar 4b —; Ar 1 , Ar 2 , Ar 3b and Ar 4b each independently represent an arylene group optionally having a substituent; Z represents a direct bond, —S—, —O—, —CO—, —SO 2 — or —C(CF 3 ) 2 —; and X − represents an anion.
2. The method for producing a polyarylene sulfide resin according to claim 1 , wherein the terminal group included in the polyarylene sulfide resin and the poly(arylene sulfonium salt) is a group represented by the following formula (3-1b), (3-2b), (3-3b), (3-4b), (3-5b) or (3-6b):
wherein R 3 represents a direct bond or an alkylene group having 1 to 10 carbon atoms; and Ar 5b represents an aryl group.
3. The method for producing a polyarylene sulfide resin according to claim 1 , wherein the terminal group included in the polyarylene sulfide resin and the poly(arylene sulfonium salt) is a group represented by the following formula (4-1b), (4-2b), (4-3b) or (4-4b):
wherein R 4 represents a direct bond or an alkylene group having 1 to 10 carbon atoms; and Ar 6b represents an aryl group.